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Trifluor(trifluormethoxy)ethylen

Perfluoro(methyl vinyl ether)

HCID 14474
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Grundinformationen

CAS
1187-93-5
Standard-SMILES
FC(F)=C(F)OC(F)(F)F
InChIKey
BLTXWCKMNMYXEA-UHFFFAOYSA-N
Summenformel
C3F6O
Durchschnittliche Molmasse
166,02 g/mol
Monoisotopische Masse
165,98533359

Überblick

Perfluoro(methylvinyl ether) appears as a colorless gas. Heavier than air. Easily liquefied. Contact with the liquid may cause frost bite by evaporative cooling. May asphyxiate by displacing air. A flame may flash back from the source of ignition to the source of a leak. Under prolonged exposure to fire or heat containers may rupture violently and rocket.

Namen und Bezeichner

Bevorzugter Name
Perfluoro(methyl vinyl ether)
IUPAC
1,1,2-trifluoro-2-(trifluoromethoxy)ethene
Lokaler Name
Trifluor(trifluormethoxy)ethylen
Englischer Name
Trifluoromethyl trifluorovinyl ether
Summenformel
C3F6O
Molmasse
166.02

Namen und Synonyme

Trifluoromethyl trifluorovinyl ether1187-93-5Perfluoro(methyl vinyl ether)Trifluoro(trifluoromethoxy)ethyleneEthene, 1,1,2-trifluoro-2-(trifluoromethoxy)-Ethene, trifluoro(trifluoromethoxy)-3-OXAPERFLUOROBUTENEETHER, TRIFLUOROMETHYL TRIFLUOROVINYLEINECS 214-703-7UNII-6II375V3XGBRN 19074576II375V3XG
Weitere Namen anzeigen
PMVEPerfluoro(methylvinylether)Perfluoromethylvinyl Ether (PMVE)uorovinyLtrifluoromethoxyetheneHexafluoro-3-oxa-1-buteneHexafluoro-2-oxa-3-buteneperfluorinatedmethylvinylether(Trifluoromethoxy)trifluoroethene
trifluoromethoxytrifluoroethyleneTRIFLUOROMETHYL TRIFLUORVINYL ETHERPERFLUOROVINYL PERFLUOROMETHYL ETHERDTXSID3051599EC 214-703-7RefChem:171634DTXCID10301511,1,2-trifluoro-2-(trifluoromethoxy)ethene

Eigenschaften

Berechnete Struktureigenschaften

XLogP
2,4
Polarare Oberfläche (TPSA)
9,2 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
7
Frei drehbare Bindungen
1
Schwere Atome
10
Formalladung
0
Komplexität
142

Experimentelle und physikochemische Eigenschaften

PFAS · 6 Einträge

PFAS -> Other/unspecified

PFAS -> Other/unspecified

PFAS -> PFAS identified in REACH Regulation EC No. 1272/2008

PFAS -> Other/unspecified

PFAS -> Suspected persistent, mobile, toxic (PMT) PFAS or PFAS-like compounds

PFAS -> OECD Category

SpringerMaterials PropertiesSchoenflies notation
Food Contact SubstancesFCS -> FDA Inventory of Food Contact Substances Listed in 21 CFR
Physical Description · 2 Einträge

Perfluoro(methylvinyl ether) appears as a colorless gas. Heavier than air. Easily liquefied. Contact with the liquid may cause frost bite by evaporative cooling. May asphyxiate by displacing air. A flame may flash back from the source of ignition to the source of a leak. Under prolonged exposure to fire or heat containers may rupture violently and rocket.

Gas Vapor

Physikochemische Eigenschaften

Siedepunkt
-22 °C · -22 °C
Dichte
1.321 · 1.3210 (estimate)

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

GHS-Klassifizierung

GHS Classification · 6 Einträge

Danger

H220 (18.2%): Extremely flammable gas [Danger Flammable gases]

P203, P210, P222, P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P317, P319, P321, P332+P317, P337+P317, P362+P364, P377, P381, P403, P403+P233, P405, P410+P403, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 11 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

H220: Extremely flammable gas [Danger Flammable gases]

Gefahrenhinweise

Regulatory Information · 3 Einträge

Regulation (EC) No 1935/2004 (amended)

Ethene, 1,1,2-trifluoro-2-(trifluoromethoxy)- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Ethene, 1,1,2-trifluoro-2-(trifluoromethoxy)- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

REACH registered substance: Trifluoro(trifluoromethoxy)ethylene (EC: 214-703-7)

DOT LabelFlammable Gas
Fire Hazards · 2 Einträge

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

· EXTREMELY FLAMMABLE.

Health Hazards · 2 Einträge

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

· Vapors may cause dizziness or asphyxiation without warning, especially when in closed or confined areas.

DOT ID and Guide3153 115

Chemie und Industrie

Verwendung und Herstellung

U.S. Production2023: 250,000 - <550,000 lb
Industry UsesMonomers
Use ClassificationPFAS (per- and polyfluoroalkyl substances) -> OECD Category
General Manufacturing Information · 2 Einträge

Plastics Material and Resin Manufacturing

Ethene, 1,1,2-trifluoro-2-(trifluoromethoxy)-: ACTIVE

Vor- und nachgelagerte Produkte

Vorgelagerte Rohstoffe

Hypofluorous acid, methyl ester (9CI)Heptafluoro-1-methoxypropaneHexafluorpropen

Nachgelagerte Produkte

2-Iodotetrafluoroethyl trifluoromethyl ether1,2-Dibromotrifluoroethyl trifluoromethyl ether

Zugehörige Reaktionen

13
Reaktionsaufzeichnung erstellen
Reaktionsgleichung von HRID 252015
HRID 252015als Eduktuspto-grants-2011_01
Reaktionsgleichung von HRID 553375
HRID 553375als Eduktuspto-grants-2011_11
Reaktionsgleichung von HRID 638682
HRID 638682als Eduktuspto-grants-2010_04
Reaktionsgleichung von HRID 1160490
HRID 1160490als Eduktuspto-grants-2010_10
Reaktionsgleichung von HRID 1174052
HRID 1174052als Eduktuspto-grants-2010_11
Reaktionsgleichung von HRID 1710298
HRID 1710298als Eduktuspto-grants-2010_09
Reaktionsgleichung von HRID 1956043
HRID 1956043als Produktuspto-grants-1998_07
Reaktionsgleichung von HRID 1956044
HRID 1956044als Produktuspto-grants-1998_07
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Datenbank-Bezeichner

CAS
1187-93-5
PubChem CID
14474
DTXSID
DTXSID3051599
UNII
6II375V3XG
EC Number
214-703-7
Nikkaji
J203.449B
Dampfdruck
101.325 kPa · 101.325kPa at 20℃
Wasserlöslichkeit
31.5 mg/L · 31.5mg/L at 28℃
InChI
InChI=1S/C3F6O/c4-1(5)2(6)10-3(7,8)9
InChIKey
BLTXWCKMNMYXEA-UHFFFAOYSA-N
SMILES
C(/F)(\F)=C(/F)\OC(F)(F)F
LogP
1.42 · 1.42
EPA chemische Informationen
1 · Ethene, 1,1,2-trifluoro-2-(trifluoromethoxy)- (1187-93-5)
Reactive Group
Ethers
Reactivity AlertsHighly Flammable
Reactivity ProfilePERFLUORO(METHYLVINYL ETHER) oxidizes readily in air to form unstable peroxides that may explode spontaneously [Bretherick 1979. p.151-154, 164].
DOT Hazard Classification · 3 Einträge

Perfluoro(methyl vinyl ether)

UN3153

Div 2.1 Flammable gas (49 eCFR § 173.115)

Air and Water ReactionsHighly flammable.
Hazard Classes and Categories · 2 Einträge

Flam. Gas 1 (18.2%)

Flammable gases (including chemically unstable gases) - Category 1, Chemically unstable gas Category B

Sicherheit und Schutzausrüstung

Fire FightingExcerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:
Accidental Release Measures · 2 Einträge

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

First Aid · 2 Einträge

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

General First Aid:

Exposure Control and Personal Protection· Wear positive pressure self-contained breathing apparatus (SCBA).
Nonfire Spill ResponseExcerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:
Isolation and Evacuation · 2 Einträge

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

Immediate precautionary measure

Personal Protective Equipment (PPE)Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:
Emergency Response Planning Guidelines· DO NOT EXTINGUISH A LEAKING GAS FIRE UNLESS LEAK CAN BE STOPPED.

Sicherheitsdaten

tsca
TSCA listed
ridadr
UN 3153
hs_code
2909199090
RTECS-Nr.
KO4350000
risk_code
20
hazard_code
F
hazard_note
Flammable gas
safety_code
23-38
hazard_class
2.1