Grundinformationen
- Standard-SMILES
FC(F)=C(F)OC(F)(F)F- InChIKey
BLTXWCKMNMYXEA-UHFFFAOYSA-N- Summenformel
- C3F6O
- Durchschnittliche Molmasse
- 166,02 g/mol
- Monoisotopische Masse
- 165,98533394
Überblick
Perfluoro(methylvinyl ether) appears as a colorless gas. Heavier than air. Easily liquefied. Contact with the liquid may cause frost bite by evaporative cooling. May asphyxiate by displacing air. A flame may flash back from the source of ignition to the source of a leak. Under prolonged exposure to fire or heat containers may rupture violently and rocket.
Namen und Bezeichner
- Bevorzugter Name
- Perfluoro(methyl vinyl ether)
- IUPAC
- 1,1,2-trifluoro-2-(trifluoromethoxy)ethene
- Lokaler Name
- Trifluor(trifluormethoxy)ethylen
- Englischer Name
- Trifluoromethyl trifluorovinyl ether
- Summenformel
- C3F6O
- Molmasse
- 166.02
Namen und Synonyme
Trifluoromethyl trifluorovinyl ether1187-93-5Perfluoro(methyl vinyl ether)Trifluoro(trifluoromethoxy)ethyleneEthene, 1,1,2-trifluoro-2-(trifluoromethoxy)-Ethene, trifluoro(trifluoromethoxy)-3-OXAPERFLUOROBUTENEEINECS 214-703-7UNII-6II375V3XGBRN 19074576II375V3XGETHER, TRIFLUOROMETHYL TRIFLUOROVINYL
Weitere Namen anzeigen
PMVEPerfluoro(methylvinylether)Perfluoromethylvinyl Ether (PMVE)uorovinyLtrifluoromethoxyetheneHexafluoro-3-oxa-1-buteneHexafluoro-2-oxa-3-buteneperfluorinatedmethylvinylether(Trifluoromethoxy)trifluoroethene
trifluoromethoxytrifluoroethyleneDTXSID3051599EC 214-703-7TRIFLUOROMETHYL TRIFLUORVINYL ETHERPERFLUOROVINYL PERFLUOROMETHYL ETHERRefChem:171634DTXCID10301511,1,2-trifluoro-2-(trifluoromethoxy)ethene
Datenbank-Bezeichner
- CAS
1187-93-5- PubChem CID
- 14474
- DTXSID
DTXSID3051599- UNII
- 6II375V3XG
- EC Number
- 214-703-7
- Nikkaji
- J203.449B
Eigenschaften
Berechnete Struktureigenschaften
- XLogP
- 2,4
- Polarare Oberfläche (TPSA)
- 9,2 Ų
- H-Brücken-Donoren
- 0
- H-Brücken-Akzeptoren
- 7
- Frei drehbare Bindungen
- 1
- Schwere Atome
- 10
- Formalladung
- 0
- Komplexität
- 142
Experimentelle und physikochemische Eigenschaften
PFAS
PFAS -> Suspected persistent, mobile, toxic (PMT) PFAS or PFAS-like compounds
PFAS -> OECD Category
PFAS -> Other/unspecified
PFAS -> Other/unspecified
PFAS -> Other/unspecified
PFAS -> PFAS identified in REACH Regulation EC No. 1272/2008
SpringerMaterials PropertiesSchoenflies notation
Food Contact SubstancesFCS -> FDA Inventory of Food Contact Substances Listed in 21 CFR
Physical Description
Perfluoro(methylvinyl ether) appears as a colorless gas. Heavier than air. Easily liquefied. Contact with the liquid may cause frost bite by evaporative cooling. May asphyxiate by displacing air. A flame may flash back from the source of ignition to the source of a leak. Under prolonged exposure to fire or heat containers may rupture violently and rocket.
Gas Vapor
Physikochemische Eigenschaften
- Siedepunkt
- -22 °C · -22 °C
- Dichte
- 1.321 · 1.3210 (estimate)
- Dampfdruck
- 101.325 kPa · 101.325kPa at 20℃
- Wasserlöslichkeit
- 31.5 mg/L · 31.5mg/L at 28℃
- InChI
- InChI=1S/C3F6O/c4-1(5)2(6)10-3(7,8)9
- InChIKey
- BLTXWCKMNMYXEA-UHFFFAOYSA-N
- SMILES
- C(/F)(\F)=C(/F)\OC(F)(F)F
- LogP
- 1.42 · 1.42
- EPA chemische Informationen
- 1 · Ethene, 1,1,2-trifluoro-2-(trifluoromethoxy)- (1187-93-5)
Sicherheit und Regulatorisches
GHS-Klassifizierung
GHS Classification
Danger
H220 (18.2%): Extremely flammable gas [Danger Flammable gases]
P203, P210, P222, P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P317, P319, P321, P332+P317, P337+P317, P362+P364, P377, P381, P403, P403+P233, P405, P410+P403, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 11 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Danger
H220: Extremely flammable gas [Danger Flammable gases]
Gefahrenhinweise
Regulatory Information
Regulation (EC) No 1935/2004 (amended)
Ethene, 1,1,2-trifluoro-2-(trifluoromethoxy)- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Ethene, 1,1,2-trifluoro-2-(trifluoromethoxy)- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
Status: Active Update: 25-11-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/13408
DOT LabelFlammable Gas
Fire Hazards
Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:
· EXTREMELY FLAMMABLE.
Health Hazards
Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:
· Vapors may cause dizziness or asphyxiation without warning, especially when in closed or confined areas.
DOT ID and Guide3153 115
Reactive GroupEthers
Reactivity AlertsHighly Flammable
Reactivity ProfilePERFLUORO(METHYLVINYL ETHER) oxidizes readily in air to form unstable peroxides that may explode spontaneously [Bretherick 1979. p.151-154, 164].
DOT Hazard Classification
Perfluoro(methyl vinyl ether)
UN3153
Div 2.1 Flammable gas (49 eCFR § 173.115)
Air and Water ReactionsHighly flammable.
Hazard Classes and Categories
Flam. Gas 1 (18.2%)
Flammable gases (including chemically unstable gases) - Category 1, Chemically unstable gas Category B
Sicherheit und Schutzausrüstung
Fire FightingExcerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:
Accidental Release Measures
· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.
· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.
First Aid
Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:
General First Aid:
Exposure Control and Personal Protection· Wear positive pressure self-contained breathing apparatus (SCBA).
Nonfire Spill ResponseExcerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:
Isolation and Evacuation
Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:
Immediate precautionary measure
Personal Protective Equipment (PPE)Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:
Emergency Response Planning Guidelines· DO NOT EXTINGUISH A LEAKING GAS FIRE UNLESS LEAK CAN BE STOPPED.
Sicherheitsdaten
- tsca
- TSCA listed
- ridadr
- UN 3153
- hs_code
- 2909199090
- RTECS-Nr.
- KO4350000
- risk_code
- 20
- hazard_code
- F
- hazard_note
- Flammable gas
- safety_code
- 23-38
- hazard_class
- 2.1
Chemie und Industrie
Verwendung und Herstellung
U.S. Production2023: 250,000 - <550,000 lb
Industry UsesMonomers
Use ClassificationPFAS (per- and polyfluoroalkyl substances) -> OECD Category
General Manufacturing Information
Plastics Material and Resin Manufacturing
Ethene, 1,1,2-trifluoro-2-(trifluoromethoxy)-: ACTIVE
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