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Isodecylacrylat
ISODA · sCD163 · M 130 · MM130 · SCARI · GHI/61 · SCARI1 · L-61053
Identifikatoren & physikalische Daten
| CAS No. | 1330-61-6 |
|---|---|
| Summenformel | C13H24O2 |
| Durchschnittliche Molmasse | 212,33 g/mol |
| Monoisotopische Masse | 212,17763001 g/mol |
| SMILES | C=CC(=O)OCCCCCCCC(C)C |
| InChIKey | LVGFPWDANALGOY-UHFFFAOYSA-N |
| PubChem CID | 14899 |
| ChEMBL | CHEMBL3186945 |
| EC No. | 215-542-5 |
| DTXSID | DTXSID10859622 |
| Lokaler Name | Isodecylacrylat |
Chemische & physikalische Eigenschaften
| XLogP | 5,3 |
|---|---|
| Polarare Oberfläche (TPSA) | 26,3 |
| H-Brücken-Donoren | 0 |
| H-Brücken-Akzeptoren | 2 |
| Frei drehbare Bindungen | 10 |
| Schwere Atome | 15 |
| Formalladung | 0 |
| Komplexität | 173 |
| Polymers | Plastics & Rubber -> (Meth)acrylates |
| SpringerMaterials Properties | Density |
| LogP (Verteilungskoeffizient) | log Kow = 5.07 /Estimated/ |
| Geruch | Weak acrylatePungent, characteristic, very slightly nauseating |
| Dichte | 0.885 at 68 °F (USCG, 1999) - Less dense than waterwill float0.885 @ 20 °C0.875 g/mL at 25 °C(lit.) |
| Viscosity | Liquid viscosity: 2.300 cP @ 70 °C |
| Color/Form | ColorlessWater-white liquid |
| Löslichkeit | Negligible in water, <0.01% @ 20 °CSolubility in water: 0.010 lb/100 lb at 68 °Csoluble in Methanol1.34mg/L at 20℃ |
| Flammpunkt | 240 °F (USCG, 1999)240 °F (open cup)223 °F |
| Siedepunkt | 158 °C @ 50 mm HgPolymerizes at boiling pointvapor pressure <0.01 mm Hg at 20 °C121 °C10 mm Hg(lit.) |
| Decomposition | When heated to decomposition it emits acrid smoke and fumes. |
| Schmelzpunkt | -148 °F (USCG, 1999)-100 °C-100℃ |
| Dampfdruck | 3.61Pa at 20℃ |
| Brechungsindex | n20/D 1.442(lit.) |
| Lagerbedingungen | -20°C |
| Aggregatzustand | buffered aqueous solution |
| Farbe | Colorless to Light yellow |
| Biologische Quelle | rabbit |
| InChI | 1S/C13H24O2/c1-4-13(14)15-11-9-7-5-6-8-10-12(2)3/h4,12H,1,5-11H2,2-3H3 |
| InChIKey | LVGFPWDANALGOY-UHFFFAOYSA-N |
| SMILES | CC(C)CCCCCCCOC(=O)C=C |
| LogP (Verteilungskoeffizient) | 5.55 |
| CAS Datenbank | 1330-61-6 |
| EPA chemische Informationen | Isodecyl acrylate (1330-61-6) |
Sicherheit & Vorschriften
| GHS-Einstufung | This chemical does not meet GHS hazard criteria for 4.2% (32 of 769) of reports.WarningH315 (37.1%): Causes skin irritation [Warning Skin corrosion/irritation]P261, P264, P264+P265, P271, P272, P273, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P333+P317, P337+P317, P362+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 769 reports by companies from 29 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies. |
|---|---|
| Regulatorische Informationen | Chemical: 2-Propenoic acid, isodecyl ester2-Propenoic acid, isodecyl ester is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 2-Propenoic acid, isodecyl ester are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)Status: Active Update: 05-05-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/11766Isodecyl acrylate: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right. |
| DOT-Kennzeichnung | Class 9 |
| Brandgefahren | Behavior in Fire: May polymerize to gummy solid. Reaction is not violent. (USCG, 1999) |
| Gesundheitsgefahren | Inhalation causes mild irritation of nose and throat. Eyes are mildly irritated by vapor, more severely by liquid. Prolonged contact of liquid with skin may cause irritation. (USCG, 1999) |
| Gefahrenübersicht | May polymerizeA mild eye, nose, and throat irritant[CAMEO] Repeated dose feeding studies of rats produced no significant adverse effects[eChemPortal: HPVIS] Hazardous polymerization may occurA skin irritant[MSDSonline] See ACRYLIC RESINS (MONOMERS). |
| Reaktive Gruppe | Acrylates and Acrylic Acids |
| TSCA-Anforderungen | Section 8(a) of TSCA requires manufacturers of this chemical substance to report preliminary assessment information concerned with production, use, and exposure to EPA as cited in the preamble of the 51 FR 41329. |
| Reactivity Alerts | Polymerizable |
| Reactivity Profile | ISODECYL ACRYLATE is an acrylate ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Polymerizes readily in the presence of heat and light generating much heatreacts with strong oxidants. REF [Handling Chemicals Safely, 1980. p. 235]. Reaction is not violent (USCG, 1999). |
| DOT Hazard Classification | Isodecyl acrylateMarine pollutant |
| Air and Water Reactions | No rapid reaction with air. No rapid reaction with water. |
| Hazard Classes and Categories | Skin Irrit. 2 (37.1%) |
| Brandbekämpfung | Fire Extinguishing Agents Not to Be Used: Water may be ineffective. |
| Erste Hilfe | INHALATION: move to fresh air. |
| Brandbekämpfungsverfahren | Extinguish with dry chemical, foam or carbon dioxide. Water may be ineffective on fire. Cool exposed containers with water. |
| Lagerbedingungen | The effectiveness of phenolic inhibitors is dependent on the presence of oxygen and the monomers must be stored under air rather than an inert atmosphere. Temp must be kept low to minimize formation of peroxides and other products. Moisture may cause rust-initiated polymerization. /Acrylic acid & derivatives/ |
| Freisetung ohne Brand | Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: |
| Entsorgungsverfahren | SRP: The most favorable course of action is to use an alternative chemical product with less inherent propensity for occupational exposure or environmental contamination. Recycle any unused portion of the material for its approved use or return it to the manufacturer or supplier. Ultimate disposal of the chemical must consider: the material's impact on air qualitypotential migration in soil or watereffects on animal, aquatic, and plant lifeand conformance with environmental and public health regulations. |
| Preventive Measures | Awareness of the dangers and of good engineering design are essential to safety. Employees should be instructed about the necessity of cleansing the skin if it is contaminated by materials which are irritants or skin-absorbed. With careful design, however, and complete enclosure of those processes where toxic chemicals or intermediates occur, dangerous exposures can be avoided. /Acrylic acid & derivatives/ |
| Isolation and Evacuation | Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: |
| Personal Protective Equipment (PPE) | Goggles or face shieldrubber gloves. (USCG, 1999)Suitable protective clothing and self-contained respiratory protective apparatus should be available for use of those who may have to rescue persons overcome by fumes. /acrylic acid and derivatives/Protection required for safe handling of acrylic acid and esters commonly includes use of impervious gloves, shoe soles, and clothingsplash-proof goggles ... . /Acrylic acid & derivatives/ |
| Unerwünschte Wirkungen | Skin Sensitizer - An agent that can induce an allergic reaction in the skin. |
| Human Toxicity Excerpts | /SIGNS AND SYMPTOMS/ Human signs and symptoms following ingestion of acrylic monomers include collapse, severe respiratory difficulties, and CNS stimulation. /Acrylates//SIGNS AND SYMPTOMS/ Allergic reactions have been reported for some acrylates. /Acrylates/ |
| Non-Human Toxicity Excerpts | /LABORATORY ANIMALS: Acute Exposure/ Contact sensitivity was produced in guinea pigs with mono-, di-, and tri- acrylate compounds. /Mono-, di-, and tri- acrylate compounds//LABORATORY ANIMALS: Acute Exposure/ The acute toxicity of the acrylates decreases with increasing molecular weight. ...Acute inhalation of higher concentrations may cause /CNS depression/, salivation, and pronounced nasal, ocular, and pulmonary irritation or edema. Prolonged skin or eye contact may result in severe tissue damage. /Acrylates//LABORATORY ANIMALS: Subchronic or Prechronic Exposure/ The pathology from single exposure is not particularly characteristic, contrary to repeated exposure effects, which include pulmonary congestion or hemorrhage and cloudy swelling and organ weight changes of the liver and kidney, reported following subchronic exposures to excessive concentrations. /Acrylates//LABORATORY ANIMALS: Developmental or Reproductive Toxicity/ Animal studies using rats revealed that some acrylates and methacrylates are embryotoxic. The doses of monomers used in the animal studies, however, were much higher than concentrations likely encountered by workers. /Acrylates and Methacrylates//LABORATORY ANIMALS: Developmental or Reproductive Toxicity/ Monomers of 5 methacrylate esters and acrylic acid /including isodecyl acrylate,/ were administered at 3 dose levels to female rats on days, 5, 10, and 15 of gestation. The incidences of resorptions, dead fetuses, gross abnormalities and skeletal malformations were presented for each of these groups /and/ were smaller (P</=0.01) than those of the untreated controls. |
| Antidote and Emergency Treatment | Basic treatment: Establish a patent airway. Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if needed. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for pulmonary edema and treat if necessary ... . Monitor for shock and treat if necessary ... . Anticipate seizures and treat if necessary ... . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with normal saline during transport ... . Do not use emetics. For ingestion, rinse mouth and administer 5 ml/kg up to 200 ml of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool ... . Cover skin burns with dry sterile dressings after decontamination ... . /Poison A and B/Advanced treatment: Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious, has severe pulmonary edema, or is in respiratory arrest. Positive pressure ventilation techniques with a bag valve mask device may be beneficial. Monitor cardiac rhythm and treat arrhythmias as necessary ... . Start an IV with D5W /SRP: "To keep open", minimal flow rate/. Use lactated Ringer's if signs of hypovolemia are present. Watch for signs of fluid overload. Consider drug therapy for pulmonary edema ... . For hypotension with signs of hypovolemia, administer fluid cautiously. Watch for signs of fluid overload ... . Treat seizures with diazepam (Valium) ... . Use proparacaine hydrochloride to assist eye irrigation ... . /Poison A and B/ |
| Non-Human Toxicity Values | LD50 Rabbit dermal 3540 mg/kgLD50 Rat oral 12 g/kg |
| Wassergefährdungsklasse (WGK) | 2 |
| TSCA-Inventar-Status | TSCA listed |
| UN-Transportnummer | UN 3082 9/PG 3 |
| Zollcode | 2916.12.5050 |
| RTECS-Nr. | AT2190000 |
| R-Sätze (R) | 38-50/53 |
| Gefahrensymbole | Xi,N |
| Sicherheitshinweise (S) | 26-36-61-60 |
| Gefahrenklasse | 9Aquatic Chronic 2Eye Irrit. 2Skin Irrit. 2STOT SE 3 |
| Verpackungsgruppe | III |
| Lagerklasse | 10 - Combustible liquids |
| Gefahrstoffdaten | 1330-61-6(Hazardous Substances Data) |
Anwendungen & Verwendung
Verwenden
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