Dimethylcyanamid

Dimethylcyanamide

HCID 15112CAS 1467-79-4

Grundinformationen

Standard-SMILES
CN(C)C#N
InChIKey
OAGOUCJGXNLJNL-UHFFFAOYSA-N
Summenformel
C3H6N2
Durchschnittliche Molmasse
70,09 g/mol
Monoisotopische Masse
70,05309819

Überblick

Dimethyl cyanamide is a clear liquid. (NTP, 1992)

Namen und Bezeichner

Bevorzugter Name
Dimethylcyanamide
IUPAC
dimethylcyanamide
Lokaler Name
Dimethylcyanamid
Englischer Name
Dimethylcyanamide
Summenformel
C3H6N2
Molmasse
70.09

Namen und Synonyme

Dimethylcyanamide1467-79-4DIMETHYL CYANAMIDEN-Cyano-N-methylmethanamineCyanamide, dimethyl-DimethylkyanamidN-Cyanodimethylamine6P25IPQ8GNNSC-7765DTXSID9025116RefChem:134326DTXCID405116
Weitere Namen anzeigen
(CH3)2NCequivNdimethyl-cyanamidDimethylcyanamineDimethylcyanoamineN-Cyanodimethylamide
215-991-7Cyanamide, N,N-dimethyl-MFCD00001767cyanodimethylamineDimethylkyanamid [Czech]CCRIS 5909N,N-dimethylcyanamideHSDB 4274

Datenbank-Bezeichner

CAS
1467-79-4
PubChem CID
15112
DTXSID
DTXSID9025116
ChEBI
CHEBI:229338
UNII
6P25IPQ8GN
EC Number
215-991-7
Nikkaji
J33.545B

Eigenschaften

Berechnete Struktureigenschaften

XLogP
-0,2
Polarare Oberfläche (TPSA)
27 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
2
Frei drehbare Bindungen
0
Schwere Atome
5

Experimentelle und physikochemische Eigenschaften

Chemical ClassesNitrogen Compounds -> Cyanamides
SpringerMaterials PropertiesSchoenflies notation
LogP-0.15
Density · 2 Einträge

0.88 (NTP, 1992) - Less dense than water; will float

0.876

Color/FormCOLORLESS, MOBILE LIQUID
Solubility · 3 Einträge

Decomposes (NTP, 1992)

VERY SOL IN WATER

SOL IN ALCOHOL, ETHER & ACETONE

Physikochemische Eigenschaften

Schmelzpunkt
-41 °C · -41 °C
Siedepunkt
161 · 161-163 °C(lit.)
Dichte
0.867 g/mL · 0.867 g/mL at 25 °C(lit.)
Brechungsindex
20 · n20/D 1.41(lit.)
Flammpunkt
137 °F · 137 °F
storage temp.
2 · Inert atmosphere,2-8°C

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 6 Einträge

Danger

H301 (100%): Toxic if swallowed [Danger Acute toxicity, oral]

P261, P264, P270, P271, P301+P316, P304+P340, P316, P321, P330, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 41 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

H227: Combustible liquid [Warning Flammable liquids]

Gefahrenhinweise

Regulatory InformationDimethylcyanamide: Does not have an individual approval but may be used under an appropriate group standard
DOT LabelPoison
Fire HazardsThis chemical is combustible. (NTP, 1992)
Health HazardsACUTE/CHRONIC HAZARDS: This compound is an irritant. It reacts with water to produce toxic and flammable vapors. (NTP, 1992)
Hazards SummaryReacts with water producing cyanide gas; An irritant; [CAMEO] An irritant; Can be absorbed through skin; Effects in high-dose animal studies include convulsions; [MSDSonline] See Hydrogen cyanide.
Reactive GroupAmines, Phosphines, and Pyridines

Sicherheit und Schutzausrüstung

Fire FightingFires involving this compound should be controlled using a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)
First Aid · 1 Eintrag

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Exposure Control and Personal Protection2.0 [mg/m3], inhalable fraction, as CN[German Research Foundation (DFG)]
Nonfire Spill Response · 1 Eintrag

SMALL SPILLS AND LEAKAGE: If you spill this chemical, FIRST REMOVE ALL SOURCES OF IGNITION. Then, use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Isolation and EvacuationExcerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]:
Permissible Exposure Limit (PEL)5.0 [mg/m3], as CN

Toxikologische Informationen

Adverse EffectsOther Poison - Chemical Asphyxiant
Human Toxicity Excerpts · 2 Einträge

CMPD APPEARS TO BE HAZARDOUS, ESP BY SKIN ABSORPTION

The neurotoxic effects of dimethyl cyanamide are weakness and ataxia. /From table/

Non-Human Toxicity Excerpts · 1 Eintrag

... ORAL ... IN RATS & GUINEA PIGS ... SYMPTOMS WERE WEAKNESS, ATAXIA, GASPING RESPIRATIONS, & UNCONSCIOUSNESS. IT WAS READILY ABSORBED THROUGH GUINEA PIG SKIN ... WITH LITTLE SKIN IRRITATION. IT WAS NOT SEVERE EYE IRRITANT TO RABBIT. NO SKIN SENSITIZATION WAS PRODUCED IN GUINEA PIG.

Toxicity DataLC50 (rat) = 2,500 mg/m3

Sicherheitsdaten

wgk
3
tsca
TSCA listed
ridadr
UN 2810 6.1/PG 3
hs_code
29269095
RTECS-Nr.
GS6475000
risk_code
23/25

Chemie und Industrie

Pharmakologische Informationen

Absorption, Distribution and ExcretionIT WAS READILY ABSORBED THROUGH GUINEA PIG SKIN ... .

Verwendung und Herstellung

Uses · 2 Einträge

Used as chemical intermediate and solvent; [Hawley]

CHEMICAL INTERMEDIATE; SOLVENT

Methods of ManufacturingREACTION OF NITROMETHANE WITH TRIS-(DIMETHYLAMINO)ARSINE; PHOTOISOMERIZATION OF CARBODIIMIDES
General Manufacturing InformationCyanamide, N,N-dimethyl-: ACTIVE
Anwendungen · 1 Eintrag

VerwendenDimethylcyanamide in the presence of tetrachlorosilane and zinc chloride is used as a promoter for one-pot, three component synthesis of a novel series of 1,3-oxazines. Being a dialkylcyanamide, it has been proved to be a more reactive substrate toward metal-mediated nucleophilic addition than alkylcyanides.

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梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
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爱斯特(成都)生物制药股份有限公司+86-28-85122536 85324413 · [email protected]
上海仲因实业有限公司2537653158 16621191650 · [email protected]
Dayang Chem (Hangzhou) Co.,Ltd.+86-0571-88938639 17705817739 · [email protected]

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