tert-Butylacrylat

tert-Butyl acrylate

HCID 15458CAS 1663-39-4

Grundinformationen

Standard-SMILES
C=CC(=O)OC(C)(C)C
InChIKey
ISXSCDLOGDJUNJ-UHFFFAOYSA-N
Summenformel
C7H12O2
Durchschnittliche Molmasse
128,17 g/mol
Monoisotopische Masse
128,08372962

Überblick

structure in first source

Namen und Bezeichner

Bevorzugter Name
tert-Butyl acrylate
IUPAC
tert-butyl prop-2-enoate
Lokaler Name
tert-Butylacrylat
Englischer Name
tert-Butyl acrylate
Summenformel
C7H12O2
Molmasse
128.17

Namen und Synonyme

tert-Butyl acrylate1663-39-4tert-Butyl propenoateAcrylic acid, tert-butyl ester2-PROPENOIC ACID, 1,1-DIMETHYLETHYL ESTERDTXSID802965292M2CD1O3GNSC-20950DTXCID409652RefChem:894614216-768-7tert-butyl prop-2-enoate
Weitere Namen anzeigen
TBATERTIARY-BUTYL ACRYLATETERT-BUTYL ACRYLATE (TBA)tert-butylpropenoateAcrylic acid tert-butylTBA tert-Butyl acrylate
t-Butyl acrylateAcrylic Acid tert-Butyl Ester2-propenoic acid tert-butyl ester1,1-dimethylethyl 2-propenoatetert-Butyl 2-propenoateMFCD00008809tert-Butyl Acrylate (stabilized with MEHQ)acrylics

Datenbank-Bezeichner

CAS
1663-39-4
PubChem CID
15458
DTXSID
DTXSID8029652
ChEMBL
CHEMBL3560064
UNII
92M2CD1O3G
EC Number
216-768-7
Nikkaji
J82.107A

Eigenschaften

Berechnete Struktureigenschaften

XLogP
1,7
Polarare Oberfläche (TPSA)
26,3 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
2
Frei drehbare Bindungen
3
Schwere Atome
9

Experimentelle und physikochemische Eigenschaften

PolymersPlastics & Rubber -> (Meth)acrylates
SpringerMaterials PropertiesOptical coefficient
Density0.879 AT 25 °C
Color/FormLIQUID
Flash Point66 °F OC
Boiling Point120 °C

Physikochemische Eigenschaften

Schmelzpunkt
-69 °C · -69°C
Siedepunkt
61 · 61-63 °C/60 mmHg (lit.)
Dichte
0.875 g/mL · 0.875 g/mL at 25 °C (lit.)
Dampfdruck
20 hPa · 20hPa at 23.4℃
Brechungsindex
20 · n20/D 1.410(lit.)
Flammpunkt
63 °F · 63 °F

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 6 Einträge

Danger

H225: Highly Flammable liquid and vapor [Danger Flammable liquids]

P210, P233, P240, P241, P242, P243, P261, P264, P270, P271, P272, P273, P280, P301+P317, P302+P352, P303+P361+P353, P304+P340, P317, P319, P321, P330, P332+P317, P333+P317, P362+P364, P370+P378, P391, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

This chemical does not meet GHS hazard criteria for 0.2% (1 of 556) of reports.

Danger

H225 (99.8%): Highly Flammable liquid and vapor [Danger Flammable liquids]

Gefahrenhinweise

Regulatory Information · 4 Einträge

Chemical: 2-Propenoic acid, 1,1-dimethylethyl ester

2-Propenoic acid, 1,1-dimethylethyl ester is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 2-Propenoic acid, 1,1-dimethylethyl ester are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 07-03-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/12806

2-Propenoic acid, 1,1-dimethylethyl ester: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Fire PotentialFLAMMABLE, DANGEROUS FIRE RISK.
Hazards Summary · 1 Eintrag

Allergic contact dermatitis reported in workers handling dental prostheses; [Kanerva, p. 1739] Flammable liquid that poses a fire risk; Emergency treatment: Irritants; [HSDB] May polymerize; A skin and respiratory tract irritant; May cause skin sensitization; Harmful by ingestion, inhalation, and skin absorption; [Alfa Aesar MSDS] Butyl acrylates, stabilized (UN2348) has warning of explosive polymerization; [ERG 2016]

DOT Emergency Guidelines · 5 Einträge

/GUIDE 130P: FLAMMABLE LIQUIDS (NON-POLAR/WATER-IMMISCIBLE/NOXIOUS)/ Fire or Explosion: HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Those substances designated with a "P" may polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. /Butyl acrylates; Butyl acrylates, inhibited; Butyl acrylates, stabilized/

/GUIDE 130P: FLAMMABLE LIQUIDS (NON-POLAR/WATER-IMMISCIBLE/NOXIOUS)/ Health: May cause toxic effects if inhaled or absorbed through skin. Inhalation or contact with material may irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution. /Butyl acrylates; Butyl acrylates, inhibited; Butyl acrylates, stabilized/

/GUIDE 130P: FLAMMABLE LIQUIDS (NON-POLAR/WATER-IMMISCIBLE/NOXIOUS)/ Public Safety: CALL Emergency Response Telephone Number ... . As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate closed spaces before entering. /Butyl acrylates; Butyl acrylates, inhibited; Butyl acrylates, stabilized/

/GUIDE 130P: FLAMMABLE LIQUIDS (NON-POLAR/WATER-IMMISCIBLE/NOXIOUS)/ Protective Clothing: Wear positive pressure self-contained breathing apparatus (SCBA). Structural firefighters' protective clothing will only provide limited protection. /Butyl acrylates; Butyl acrylates, inhibited; Butyl acrylates, stabilized/

For more DOT Emergency Guidelines (Complete) data for 2-PROPENOIC ACID, 1,1-DIMETHYLETHYL ESTER (8 total), please visit the HSDB record page.

Hazard Classes and Categories · 4 Einträge

Flam. Liq. 2 (99.8%)

Flammable liquid - category 2

Flammable liquids - Category 2

Flam. Liq. 2

Sicherheit und Schutzausrüstung

Preventive MeasuresADEQUATE EXHAUST VENTILATION SHOULD BE PROVIDED TO PROTECT THE WORKER FROM INHALATION OF FUMES. WORKERS SHOULD BE PROVIDED WITH HAND PROTECTION & EYE & FACE PROTECTION. MAINTENANCE & GOOD HOUSEKEEPING SHOULD BE ENSURED. /ACRYLIC RESINS/

Toxikologische Informationen

Adverse EffectsSkin Sensitizer - An agent that can induce an allergic reaction in the skin.
Human Toxicity ExcerptsTHE LOWER-MOLECULAR-WT ESTERS OF ACRYLIC ACIDS ARE IRRITANTS TO SKIN, EYES, & MUCOUS MEMBRANES. /ESTERS OF ACRYLIC ACID/
Toxicity DataLC50 (rat) = 7,000 mg/m3/4hr

Sicherheitsdaten

F
10
wgk
2
tsca
TSCA listed
ridadr
UN 1993 3/PG 2
hs_code
29161290
risk_code
11-20/21/22-37/38-43-52/53-51/53

Chemie und Industrie

Verwendung und Herstellung

Uses · 4 Einträge

Used as a monomer for acrylic resins used in surface coatings; [HSDB] Used as an intermediate for homopolymers and copolymers; Also used as a feedstock for chemical synthesis; [OECD SIDS]

Plastic Composites Manufacturing [Category: Industry]

MONOMER FOR ACRYLIC RESINS

MONOMER FOR ACRYLIC RESINS USED IN SURFACE COATINGS

U.S. Exports · 2 Einträge

(1979) No Data

(1981) No Data

U.S. Imports · 2 Einträge

(1979) No Data

(1981) No Data

U.S. Production · 3 Einträge

2023: 75,000 - <500,000 lb

(1979) No Data

(1981) No Data

Industry UsesIntermediate
Methods of ManufacturingREACTION OF ISOBUTYLENE WITH METHACRYLIC ACID; REACTION OF TERT-BUTYL ALCOHOL WITH METHACRYLOYL CHLORIDE
Anwendungen · 1 Eintrag

Verwendentert-Butyl acrylate is a monomer used in the production of poly(tert-butyl acrylate) polymers, poly(acrylic acid) polyelectrolyte brushes and 3-(3-methyl-but-3-enyloxy)-propionic acid tert-butyl ester. It is also used in paints, coatings, high polymer paper conditioner, nursing polymer products and carbonyl reforming polyolefin. Further, it serves as an important raw material in organic synthesis.

Darstellung · 1 Eintrag

synthetischeAcrylic acid, strongly acidic cation exchange resin, a polymerization inhibitor A, B polymerization inhibitor, liquefied isobutene was 320 parts by mass of the parts, 35 parts, 20 parts, 5 parts, 430 parts. After a dropping time of 3 hours, the esterification reaction temperature was maintained at 10 ° C. After the addition was completed, 10 ° C was under insulation, and thermal insulation was 7 hours. Quality copies obtained 450 parts of tert-butyl acrylate, and the yield was 99.7%.

Anbieter50 Anbieter

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