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Sulfonium, diphenyl[(phenylthio)phenyl]-, hexafluorophosphate(1-) (1:1)
PAG-101 · PI-6992 · CPI-992M · TTA UV-6992 · HRcure-6992 · JADEADD PI-001 · Mixed of Triaryl-sulfonium Hexafluoro- Phosphate Salt · Thiophenoxyphenyl)diphenylsulfonium hexafluorophosphate
![Molekülstruktur von Sulfonium, diphenyl[(phenylthio)phenyl]-, hexafluorophosphate(1-) (1:1)](/img/chemical/155018.png)
Identifikatoren & physikalische Daten
| CAS No. | 68156-13-8 |
|---|---|
| Summenformel | C24H19S2.F6P |
| Durchschnittliche Molmasse | 516,5 g/mol |
| Monoisotopische Masse | 516,05699892 g/mol |
| SMILES | F[P-](F)(F)(F)(F)F.c1ccc(Sc2ccccc2[S+](c2ccccc2)c2ccccc2)cc1 |
| InChIKey | SFWSATMGMAKCIF-UHFFFAOYSA-N |
| PubChem CID | 155018 |
| EC No. | 269-006-0 |
| DTXSID | DTXSID30987658 |
Chemische & physikalische Eigenschaften
| Polarare Oberfläche (TPSA) | 26,3 |
|---|---|
| H-Brücken-Donoren | 0 |
| H-Brücken-Akzeptoren | 8 |
| Frei drehbare Bindungen | 5 |
| Schwere Atome | 33 |
| Formalladung | 0 |
| Komplexität | 436 |
| Schmelzpunkt | 112-114 °C(Solv: methanol (67-56-1)) |
| InChI | InChI=1S/C24H19S2.F6P/c1-4-10-20(11-5-1)25-21-16-18-24(19-17-21)26(22-12-6-2-7-13-22)23-14-8-3-9-15-231-7(2,3,4,5)6/h1-19H/q+1 |
| InChIKey | MUVYOKJVJZFJTI-UHFFFAOYSA-N |
| SMILES | [S+](C1=CC=CC=C1)(C1C=CC=CC=1)C1=CC=C(C=C1)SC1=CC=CC=C1.[P-](F)(F)(F)(F)(F)F |
Sicherheit & Vorschriften
| GHS-Einstufung | This chemical does not meet GHS hazard criteria for 2.5% (55 of 2208) of reports.WarningH317 (96.6%): May cause an allergic skin reaction [Warning Sensitization, Skin]P261, P264+P265, P272, P280, P302+P352, P305+P351+P338, P321, P333+P317, P337+P317, P362+P364, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 2208 reports by companies from 7 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.This chemical does not meet GHS hazard criteria for 50% (1 of 2) of reports. |
|---|---|
| Regulatorische Informationen | Chemical: Sulfonium, diphenyl[(phenylthio)phenyl]-, hexafluorophosphate(1-)Diphenyl[(phenylthio)phenyl]sulfonium hexafluorophosphate(1-): Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right. |
| Hazard Classes and Categories | Skin Sens. 1 (96.6%)Skin Irrit. 2 (50%) |
| Alarmwort | Warnung |
| Gefahrenhinweise | Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code H315 |
Anwendungen & Verwendung
Verwenden
Diphenyl[(phenylthio)phenyl]sulfonium hexafluorophosphate (SON) can serve as a cationic photoinitiator in two-component photoinitiating systems with diphenyl sulfone-based dyes (DSOs). These systems are utilized to initiate the cationic polymerization of epoxides (like E51) under a 405 nm LED light source[1].