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Aluminatesilicate

HCID 159743
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Grundinformationen

CAS
1327-36-2
Standard-SMILES
O=[Si]([O-])[O-].O=[Si]([O-])[O-].O=[Si]([O-])[O-].[Al+3].[Al+3]
InChIKey
PGZIKUPSQINGKT-UHFFFAOYSA-N
Summenformel
Al2O9Si3
Durchschnittliche Molmasse
282,21 g/mol
Monoisotopische Masse
281,84808843

Überblick

Aluminium silicate is a chemical compound of aluminum and silicon. Aluminum is the most abundant metal in the earth's crust and is always found combined with other elements such as oxygen, silicon, and fluorine. (L739, L740)

Namen und Bezeichner

Bevorzugter Name
Aluminatesilicate
IUPAC
dialuminum;tris(dioxido(oxo)silane)
Englischer Name
ALUMINUM SILICATE
Summenformel
Al2O5Si
Molmasse
162.05

Namen und Synonyme

1327-36-2AluminumsilicateScories du SiliciumRefChem:556316HYDRANAL Humidity absorberAluminatesilicate, PyrophylliteDTXSID6052796KA160Laitier de la fabrication du Silicium215-475-1AluminatesilicateSilicic acid, aluminum salt
Weitere Namen anzeigen
ALUMINIUM SILICATESILLIMANITEPYRAX ABBANDALUSITEPYROPHYLLITEFIBERFRAX(R)SILICA-ALUMINA CATALYST SUPPORTCATALYST (ALUMINUM PILLARED CLAY)montmorillonit (aluminum pillared clay)
139264-88-314504-95-11335-30-4dialuminum;dioxido(oxo)silaneAluminum silicate (Al2SiO5)Silicic acid (H2SiO3), aluminum salt (3:2)Montmorillonite (Aluminum Pillared Clay)Aluminum oxide (Al2O3), compd. with montmorillonite ((Al1.33-1.67Mg0.33-0.67)(Ca0-1Na0-1)0.33Si4(OH)2O10.xH2O) (9CI)

Datenbank-Bezeichner

CAS
1327-36-2、1335-30-4、139264-88-3、14504-95-1

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA)
190 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
9
Frei drehbare Bindungen
0
Schwere Atome
14
Formalladung
0
Komplexität
18,8

Experimentelle und physikochemische Eigenschaften

Chemical ClassesMetals -> Metals, Inorganic Compounds
CosmeticsAbsorbent; Opacifying; Abrasive
Food Contact SubstancesFCS -> FDA Inventory of Food Contact Substances Listed in 21 CFR
Physical Description · 3 Einträge

Dry Powder; Other Solid; Large Crystals

Large Crystals; CBI; Dry Powder; Other Solid

Solid; [IUCLID] Orange solid; [Sigma-Aldrich MSDS]

Physikochemische Eigenschaften

Aggregatzustand
fibers
PH
4 · 4-5
InChI
1S/2Al.O2Si.3O/c;;1-3-2;;;
InChIKey
HNPSIPDUKPIQMN-UHFFFAOYSA-N
SMILES
O=[Si]=O.O=[Al]O[Al]=O

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

GHS-Klassifizierung

GHS Classification · 6 Einträge

This chemical does not meet GHS hazard criteria for 91.7% (265 of 289) of all reports.

Not Classified

Aggregated GHS information provided per 289 reports by companies from 4 notifications to the ECHA C&L Inventory.

This chemical does not meet GHS hazard criteria for 27.3% (56 of 205) of reports.

Danger

H318 (72.7%): Causes serious eye damage [Danger Serious eye damage/eye irritation]

Gefahrenhinweise

Regulatory Information · 6 Einträge

Chemical: Aluminatesilicate

Silicic acid, aluminum salt is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Silicic acid, aluminum salt are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Aluminatesilicate is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Aluminatesilicate are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 13-10-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/5198

Status: Active Update: 30-05-2018 https://echa.europa.eu/registration-dossier/-/registered-dossier/13331

Aluminatesilicate: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Other Safety InformationIMAP assessments - Aluminatesilicate: Human health tier I assessment
Hazards Summary · 1 Eintrag

Composed of silicon dioxide (quartz, CAS# 14808-60-7), amorphous silicon dioxide (CAS# 7631-86-9), aluminum oxide (CAS# 1344-28-1), titanium dioxide (CAS# 13463-67-7), and disodium oxide (CAS# 1313-59-3); [ECHA REACH Registrations] May cause irritation; [Sigma-Aldrich MSDS] See Sodium aluminum silicate, Aluminum silicate, anhydrous, and Aluminum silicate.

Chemie und Industrie

Pharmakologische Informationen

Metabolism/Metabolites · 1 Eintrag

Aluminum is poorly absorbed following either oral or inhalation exposure and is essentially not absorbed dermally. The bioavailability of aluminum is strongly influenced by the aluminum compound and the presence of dietary constituents which can complex with aluminum and enhance or inhibit its absorption. Aluminum binds to various ligands in the blood and distributes to every organ, with highest concentrations found in bone and lung tissues. In living organisms, aluminum is believed to exist in four different forms: as free ions, as low-molecular-weight complexes, as physically bound macromolecular complexes, and as covalently bound macromolecular complexes. Absorbed aluminum is excreted principally in the urine and, to a lesser extent, in the bile, while unabsorbed aluminum is excreted in the faeces. (L739)

Verwendung und Herstellung

Uses · 1 Eintrag

Used in the fuel industry, for chemical synthesis, as a filler, absorbent/adsorbent, and in cosmetics; [IUCLID] Used in manufacturing, to formulate adsorbents and laboratory chemicals, as a carrier material, and catalyst/catalyst carrier; [ECHA REACH Registrations] Permitted for use as an inert ingredient in non-food pesticide products; [EPA]

U.S. Production · 2 Einträge

2023: 7,000,000 - <8,500,000 lb

2023: 7,000,000 - <8,500,000 lb

Consumer Uses · 2 Einträge

Processing aids not otherwise specified

Absorbent

Industry Uses · 2 Einträge

Processing aids not otherwise specified

Abrasives

Household ProductsInformation on 24 consumer products that contain Silicic acid, aluminum salt in the following categories is provided:
Use ClassificationCosmetics -> Absorbent; Opacifying; Abrasive

Zugehörige Reaktionen

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Reaktionsaufzeichnung erstellen

Keine Reaktionsaufzeichnungen unter den aktuellen Filterkriterien.

Notizen zur Verbindung

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Auf dieser SeiteGrundinformationenÜberblickNamen und BezeichnerEigenschaftenSicherheit und RegulatorischesChemie und IndustrieZugehörige ReaktionenNotizen zur Verbindung
PubChem CID
159743
DTXSID
DTXSID701014506
EC Number
215-475-1、215-628-2、238-509-7、629-654-0
Hazard Classes and Categories · 3 Einträge

Eye Dam. 1 (72.7%)

Not Classified

Skin Irrit. 2 (97.5%)

Sicherheit und Schutzausrüstung

Minimum Risk LevelIntermediate Oral: 1.0 mg/kg/day (L134) Chronic Oral: 1.0 mg/kg/day (L134)

Toxikologische Informationen

Treatment · 1 Eintrag

EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.

Health Effects · 1 Eintrag

Aluminum targets the nervous system and causes decreased nervous system performance and is associated with altered function of the blood-brain barrier. The accumulation of aluminum in the body may cause bone or brain diseases. High levels of aluminum have been linked to Alzheimer's disease. A small percentage of people are allergic to aluminium and experience contact dermatitis, digestive disorders, vomiting or other symptoms upon contact or ingestion of products containing aluminium. (L739, L740)

Exposure RoutesOral (L739) ; inhalation (L739)
Toxicity Summary · 1 Eintrag

The main target organs of aluminum are the central nervous system and bone. Aluminum binds with dietary phosphorus and impairs gastrointestinal absorption of phosphorus. The decreased phosphate body burden results in osteomalacia (softening of the bones due to defective bone mineralization) and rickets. Aluminum's neurotoxicity is believed to involve several mechanisms. Changes in cytoskeletal protein functions as a results of altered phosphorylation, proteolysis, transport, and synthesis are believed to be one cause. Aluminum may induce neurobehavioral effects by affecting permeability of the blood-brain barrier, cholinergic activity, signal transduction pathways, lipid peroxidation, and impair neuronal glutamate nitric oxide-cyclic GMP pathway, as well as interfere with metabolism of essential trace elements because of similar coordination chemistries and consequent competitive interactions. It has been suggested that aluminum's interaction with estrogen receptors increases the expression of estrogen-related genes and thereby contributes to the progression of breast cancer (A235), but studies have not been able to establish a clear link between aluminum and increased risk of breast cancer (A15468). Certain aluminum salts induce immune responses by activating inflammasomes. (L739, A235, A236)

Signs and Symptoms · 1 Eintrag

Inhalating aluminum dust causes coughing and abnormal chest X-rays. A small percentage of people are allergic to aluminium and experience contact dermatitis, digestive disorders, vomiting or other symptoms upon contact or ingestion of products containing aluminium. (L739, L740)

Carcinogen Classification · 1 Eintrag

Not listed by IARC. IARC classified aluminum production as carcinogenic to humans (Group 1), but did not implicate aluminum itself as a human carcinogen. (L135) A link between use of aluminum-containing antiperspirants and increased risk of breast cancer has been proposed (A235), but studies have not been able to establish a clear link (A15468).

Sicherheitsdaten

wgk
3
RTECS-Nr.
ZG6800000
risk_code
36/37/38
hazard_code
Xn,Xi
safety_code
26-36-7/9
Speicherklasse
11 - Combustible Solids
Hazard Classifications
Eye Irrit. 2Skin Irrit. 2STOT SE 3
General Manufacturing Information · 5 Einträge

Petroleum Refineries

All Other Chemical Product and Preparation Manufacturing

Aluminatesilicate: ACTIVE

Silicic acid, aluminum salt: ACTIVE

Silicic acid (H2SiO3), aluminum salt (3:2): ACTIVE

Anwendungen · 2 Einträge

BeschreibungALUMINUM SILICATE (Andalusite), kyanite, and sillimanite are three polymorphs minerals that belong to the nesosilicate minerals. Hence they have the same chemical formula [Al2SiO5 = Al2O3·SiO2] and all contain theoretically 62.92 wt.% Al2O3 and 37.08 wt.% SiO2. Andalusite decomposes gradually from 1380 to1400°C with a low volume increase of 5 to 6 vol.%.

VerwendenMontmorillonite (Aluminum Pillared Clay) can be used to prepare poly(methyl methacrylate) (PMMA) based nanocomposite materials.

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