Hydrogentetrafluoroborat(1-), Verbindung mit Ethylether (1:1)

Borate(1-), tetrafluoro-, hydrogen, compd. with 1,1'-oxybis(ethane) (1:1:1)

HCID 16211330

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Grundinformationen

CAS: 67969-82-8
Standard-SMILES: CCOCC.F[B-](F)(F)F.[H+]
InChIKey: JDQHPOVUCKSJFJ-UHFFFAOYSA-O
Summenformel: C4H11BF4O
Durchschnittliche Molmasse: 161,94 g/mol
Monoisotopische Masse: 162,08390825

Namen und Bezeichner

Bevorzugter Name: Borate(1-), tetrafluoro-, hydrogen, compd. with 1,1'-oxybis(ethane) (1:1:1)
IUPAC: ethoxyethane;hydron;tetrafluoroborate
Lokaler Name: Hydrogentetrafluoroborat(1-), Verbindung mit Ethylether (1:1)
Englischer Name: Fluoroboric acid diethyl ether complex
Summenformel: C4H11BF4O
Molmasse: 161.93

Namen und Synonyme

DTXSID30889901RefChem:120973DTXCID90102915367969-82-8EINECS 267-983-8HBF4 Et2OHBF4.Et2OSCHEMBL265707JDQHPOVUCKSJFJ-UHFFFAOYSA-Otetrafluoroboric acid diethyl etherAT48179Hydrogen tetrafluoridoborate(1-)--ethoxyethane (1/1/1)

Weitere Namen anzeigen

TETRAFLUOROBORIC ACID DIETHYL ETHER COMPLEXborate(1-),tetrafluoro-,hydrogen,compd.with1,1’-oxybis[ethane](1:1)TFBA ET2Ouoroboric acid-diethyLBF3.Diethyl Ether. HF ComplexTETRAFLUOROBORIC ACID ETHERATE)fluoboric acid/ diethyl ether complexFluoroboric acid diethyl ether complexTetrafluoroboric acid- Diethyl Etherate

Datenbank-Bezeichner

CAS: 67969-82-8
PubChem CID: 16211330
DTXSID: DTXSID30889901
EC Number: 267-983-8

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA): 9,2 Å²
H-Brücken-Donoren: 1
H-Brücken-Akzeptoren: 6
Frei drehbare Bindungen: 2
Schwere Atome: 10
Formalladung: 0
Komplexität: 30,2

Experimentelle und physikochemische Eigenschaften

Chemical ClassesMetals -> Metalloid Compounds (Boron)

Physical DescriptionDark yellow liquid; [Sigma-Aldrich MSDS]

Physikochemische Eigenschaften

Dichte: 1.19 g/mL · 1.19 g/mL at 20 °C(lit.)
Flammpunkt: 40 °F · −40 °F
storage temp.: 2 · 2-8°C
Aggregatzustand: Liquid
Farbe: Colorless to pale orange
Wichte: 1.19 · 1.19
Wasserlöslichkeit: Reacts in water.Miscible with dichloromethane.
Merck: 14 · 14,4149
InChI: InChI=1S/C4H10O.BF4/c1-3-5-4-2;2-1(3,4)5/h3-4H2,1-2H3;/q;-1/p+1
InChIKey: XFHGDBFMJCLEOW-UHFFFAOYSA-N
SMILES: O(CC)CC.[B+3]([F-])([F-])([F-])[F-].[H+]
EPA chemische Informationen: 1 · Borate(1-), tetrafluoro-, hydrogen, compd. with 1,1'-oxybis[ethane] (1:1) (67969-82-8)

Sicherheit und Regulatorisches

Gefahrenhinweise

Hazards SummaryReacts violently with water evolving flammable gases; Causes burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; [Sigma-Aldrich MSDS] See Ethyl ether. See Tetrafluoroboric acid.

Toxikologische Informationen

Adverse EffectsDermatotoxin - Skin burns.

Sicherheitsdaten

F: 3
wgk: 1
tsca: TSCA listed
ridadr: UN 3129 4.3/PG 2
hs_code: 29091990
risk_code: 11-14-34
hazard_code: F,C
safety_code: 26-36/37/39-43-45
hazard_class: 3
packing_group: I
Speicherklasse: 4.3 - Hazardous materials which set free flammable gases upon contact with water
Hazard Classifications: Eye Dam. 1Skin Corr. 1BWater-react 2

Chemie und Industrie

Verwendung und Herstellung

General Manufacturing InformationBorate(1-), tetrafluoro-, hydrogen, compd. with 1,1'-oxybis[ethane] (1:1:1): ACTIVE

Anwendungen · 1 Eintrag

VerwendenTetrafluoroboric acid diethyl ether complex can be used to facilitate phosphine-borane decomplexation from bisphosphine-borane complexes for the preparation of bisphosphine ligands. It can also act as ligands to synthesize with transition-metal complexes.