HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
(1S,4S)-3-(Heptafluorobutyryl)camphor
3-(PERFLUOROBUTYRYL)-I-CAMPHOR · 3-(perfluorobutyryl)-l-camphor · 3-(Heptafluorobutyryl)-I-camphor · 3-(heptafluorobutyryl)-L-camphor · 3-HEPTAFLUOROBUTYRYL-(-)-CAMPHOR · 3-(Perfluorobutyryl)-(-)-camphor, 98% · 3-(Heptafluorobutyryl)-L-camphor, 3-Heptafluorobutyryl-(-)-camphor · Bicyclo[2.2.1]heptan-2-one, 3-(2,2,3,3,4,4,4-heptafluoro-1-oxobutyl)-1,7,7-trimethyl-, (1S,4S)-
Identifikatoren & physikalische Daten
| CAS No. | 115224-00-5 |
|---|---|
| Summenformel | C14H15F7O2 |
| Durchschnittliche Molmasse | 348,258 g/mol |
| Monoisotopische Masse | 348,09602726 g/mol |
| SMILES | CC1(C)[C@H]2CC[C@]1(C)C(=O)C2C(=O)C(F)(F)C(F)(F)C(F)(F)F |
| InChIKey | PEWOESYEGLBLNR-NSMOOJLNSA-N |
| PubChem CID | 16211892 |
| EC No. | 623-236-1 |
| DTXSID | DTXSID50583510 |
Chemische & physikalische Eigenschaften
| Siedepunkt | 266.9±0.0 °C(Predicted) |
|---|---|
| Dichte | 1.218 g/mL at 25 °C (lit.) |
| Brechungsindex | n20/D 1.422(lit.) |
| Flammpunkt | 201 °F |
| pKa (Säurekonstante) | 7.94±0.60(Predicted) |
| BRN | 2306496 |
| InChI | 1S/C14H15F7O2/c1-10(2)6-4-5-11(10,3)8(22)7(6)9(23)12(15,16)13(17,18)14(19,20)21/h6-7H,4-5H2,1-3H3/t6-,7,11+/m0/s1 |
| InChIKey | PEWOESYEGLBLNR-NSMOOJLNSA-N |
| SMILES | CC1(C)C2CC[C@]1(C)C(=O)C2C(=O)C(F)(F)C(F)(F)C(F)(F)F |
| EPA chemische Informationen | (1S,4S)-3-(Heptafluorobutyryl)camphor (115224-00-5) |
Sicherheit & Vorschriften
| Wassergefährdungsklasse (WGK) | 3 |
|---|---|
| R-Sätze (R) | 36/37/38 |
| Gefahrensymbole | Xi |
| Sicherheitshinweise (S) | 26-36 |
| Lagerklasse | 10 - Combustible liquids |
| Gefahrenklasse | Eye Irrit. 2Skin Irrit. 2STOT SE 3 |
Anwendungen & Verwendung
Verwenden
3-(Perfluorobutyryl)-()-camphor can be used:To prepare mesoporous metal-organichybrid materials, which are used as catalysts in the asymmetric hetero-Diels-Alder cyclization of Danishefsky′s diene with benzaldehydes.As a precursor in the synthesis of chiral tetrakis(β-diketonate) Ln(III) complexes.