Dimethylhexadecylamine

HCID 16221CAS 112-69-6

Grundinformationen

Standard-SMILES
CCCCCCCCCCCCCCCCN(C)C
InChIKey
NHLUVTZJQOJKCC-UHFFFAOYSA-N
Summenformel
C18H39N
Durchschnittliche Molmasse
269,5 g/mol
Monoisotopische Masse
269,30825025

Namen und Bezeichner

Bevorzugter Name
Dimethylhexadecylamine
IUPAC
N,N-dimethylhexadecan-1-amine
Englischer Name
Hexadecyldimethylamine
Summenformel
C18H39N
Molmasse
269.51

Namen und Synonyme

Hexadecyldimethylamine112-69-6N,N-dimethylhexadecan-1-amineCetyldimethylamineDimethyl palmitamineDimethylhexadecylaminePalmityl dimethyl amine1-HEXADECANAMINE, N,N-DIMETHYL-DimethylpalmitylaminePalmityldimethylamineArmeen DM16DFarmin DM 60
Weitere Namen anzeigen
N,N-DIMETHYLHEXADECYLAMINEDMA16N-CetyldimethylamineN,N-dimethyl-1-aminohexadecaneAdma 16DMA1697NoKe DMA16
Genamin 16R302DBairdcat B16IPL 67Dimethyl palmitylamine5E4QI660PWNSC-404177DMHDA compoundRefChem:145988

Datenbank-Bezeichner

CAS
112-69-6、68037-93-4、68037-96-7、68439-70-3、75444-69-8
PubChem CID
16221
DTXSID
DTXSID9026924
ChEMBL
CHEMBL1877748
UNII
5E4QI660PW
EC Number
203-997-2
Nikkaji
J106.586F

Eigenschaften

Berechnete Struktureigenschaften

XLogP
8
Polarare Oberfläche (TPSA)
3,2 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
1
Frei drehbare Bindungen
15
Schwere Atome
19

Experimentelle und physikochemische Eigenschaften

Physical Description · 3 Einträge

Dimethyl hexadecanamine appears as a clear yellow colored liquid with a fishlike odor. Insoluble in water and less dense than water. Hence floats on water. Contact may irritate skin, eyes and mucous membranes. May be toxic by ingestion, inhalation or skin absorption. Used to make other chemicals.

Liquid

Clear yellow liquid with a fishy odor; [CAMEO] Clear light yellow liquid; [Sigma-Aldrich MSDS]

Kovats Retention Index1894

Physikochemische Eigenschaften

Schmelzpunkt
12 °C · 12°C
Siedepunkt
148 °C · 148 °C / 2mmHg
Dichte
0.801 g/mL · 0.801 g/mL at 20 °C (lit.)
Dampfdruck
0.02 · 0.02-0.36Pa at 20-50℃
Brechungsindex
20 · n20/D 1.444
Flammpunkt
147 °C · 147°C

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 6 Einträge

This chemical does not meet GHS hazard criteria for 0.5% (4 of 771) of reports.

Danger

H302 (88.2%): Harmful if swallowed [Warning Acute toxicity, oral];H314 (99.2%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation];H318 (26.3%): Causes serious eye damage [Danger Serious eye damage/eye irritation];H400 (88.1%): Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard];H410 (23%): Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquatic environment, long-term hazard]

P260, P264, P264+P265, P270, P273, P280, P301+P317, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P330, P363, P391, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 771 reports by companies from 23 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.;Reported as not meeting GHS hazard criteria per 4 of 771 reports by companies.;There are 22 notifications provided by 767 of 771 reports by companies with hazard statement code(s).;Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

Gefahrenhinweise

Regulatory Information · 4 Einträge

Chemical: 1-Hexadecanamine, N,N-dimethyl-

1-Hexadecanamine, N,N-dimethyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 1-Hexadecanamine, N,N-dimethyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 25-09-2021 https://echa.europa.eu/registration-dossier/-/registered-dossier/14932

1-Hexadecanamine, N,N-dimethyl-: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationIMAP assessments - Tertiary aliphatic (C12-22) and fatty amines: Human health tier II assessment
DOT LabelCorrosive
Fire Hazards · 1 Eintrag

Excerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]:;Combustible material: may burn but does not ignite readily. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. Corrosives in contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form. (ERG, 2024)

Health Hazards · 1 Eintrag

Excerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]:;TOXIC and/or CORROSIVE; inhalation, ingestion or skin contact with material may cause severe injury or death. Methyl bromoacetate (UN2643) is an eye irritant/lachrymator (causes flow of tears). Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause environmental contamination. (ERG, 2024)

Hazards SummaryCauses burns; Inhalation may cause corrosive injuries to upper respiratory tract; [Sigma-Aldrich MSDS]

Sicherheit und Schutzausrüstung

Fire Fighting · 1 Eintrag

Excerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]:;SMALL FIRE: Dry chemical, CO2 or water spray.;LARGE FIRE: Dry chemical, CO2, alcohol-resistant foam or water spray. If it can be done safely, move undamaged containers away from the area around the fire. Dike runoff from fire control for later disposal.;FIRE INVOLVING TANKS, RAIL TANK CARS OR HIGHWAY TANKS: Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles. Do not get water inside containers. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks in direct contact with flames. (ERG, 2024)

First Aid · 1 Eintrag

Excerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]:;Refer to the "General First Aid" section. Specific First Aid: For corrosives, in case of contact, immediately flush skin or eyes with running water for at least 30 minutes. Additional flushing may be required. Removal of solidified molten material from skin requires medical assistance. (ERG, 2024)

Nonfire Spill Response · 1 Eintrag

Excerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]:;ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. DO NOT GET WATER INSIDE CONTAINERS. (ERG, 2024)

Isolation and Evacuation · 1 Eintrag

Excerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]:;IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.;SPILL: Increase the immediate precautionary measure distance, in the downwind direction, as necessary.;FIRE: If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2024)

Personal Protective Equipment (PPE) · 1 Eintrag

Excerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]:;Wear positive pressure self-contained breathing apparatus (SCBA). Wear chemical protective clothing that is specifically recommended by the manufacturer when there is NO RISK OF FIRE. Structural firefighters' protective clothing provides thermal protection but only limited chemical protection. (ERG, 2024)

Toxikologische Informationen

Adverse EffectsDermatotoxin - Skin burns.
Toxicity SummarySafe in the present practices of use and concentration. Ingredient, concentration, and use information are available in documents discoverable at https://cir-reports.cir-safety.org

Regulatorische Informationen

Regulatory Information · 4 Einträge

Chemical: 1-Hexadecanamine, N,N-dimethyl-

1-Hexadecanamine, N,N-dimethyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 1-Hexadecanamine, N,N-dimethyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 25-09-2021 https://echa.europa.eu/registration-dossier/-/registered-dossier/14932

1-Hexadecanamine, N,N-dimethyl-: Does not have an individual approval but may be used under an appropriate group standard

Sicherheitsdaten

F
10-34
wgk
2
tsca
TSCA listed
ridadr
UN 2735 8/PG 3
hs_code
29211990
RTECS-Nr.
MM0750000

Chemie und Industrie

Verwendung und Herstellung

Uses · 3 Einträge

CIR ingredient: Dimethyl Palmitamine

Used in chemical manufacture; [CAMEO] Used as a catalyst, laboratory reagent, and to make other products (detergents, hydraulic fluids, lubricants-greases, metalworking fluids, polymers, and heat transfer fluids); [ExPub: ECHA REACH Registrations] Permitted for use as an inert ingredient in non-food pesticide products; [EPA]

Metal Machining [Category: Heat or Machine]

U.S. Production2023: 7,000,000 - <8,500,000 lb;2022: 10,000,000 - <25,000,000 lb;2021: 10,000,000 - <25,000,000 lb;2020: 10,000,000 - <25,000,000 lb
Consumer UsesSurfactant (surface active agent)
Industry UsesSurfactant (surface active agent);Corrosion inhibitor;Not Known or Reasonably Ascertainable;Intermediate
Use ClassificationCosmetics -> Antistatic; Hair conditioning; Emulsifying
General Manufacturing Information · 2 Einträge

Oil and Gas Drilling, Extraction, and Support activities;Soap, Cleaning Compound, and Toilet Preparation Manufacturing;Wholesale and Retail Trade;All Other Basic Organic Chemical Manufacturing

1-Hexadecanamine, N,N-dimethyl-: ACTIVE

Anwendungen

VerwendenBarlene(R) tertiary amines are used as chemical intermediates for the manufacture of quaternary ammonium compounds, amine oxide and betaine surfactants

Anbieter8 Anbieter

陕西缔都医药化工有限公司+86-29-87569262 +86-15003564040 · [email protected]
Alfa Chemistry1-516-6625404 · [email protected]
上海岚克医药科技发展有限公司0086-21-58956006
杭州洁汉化工有限公司+86-571-86217390; +8618058761490 · [email protected]
湖北摆渡化学有限公司027-59106051 13627137652 · [email protected]

Zugehörige Reaktionen

19

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