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Copper sulfide (CuS)

HCID 165914
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GrundinformationenÜberblickNamen und BezeichnerEigenschaftenSicherheit und RegulatorischesChemie und IndustrieZugehörige ReaktionenNotizen zur Verbindung
TeilstruktursucheÄhnliche Strukturen suchen

Grundinformationen

CAS
11115-78-9
Standard-SMILES
[Cu+2].[S-2]
InChIKey
OMZSGWSJDCOLKM-UHFFFAOYSA-N
Summenformel
CuS
Durchschnittliche Molmasse
95,61 g/mol
Monoisotopische Masse
94,9016685

Überblick

Copper(II) sulfide is a copper sulfide in which the metal is in the +2 oxidation state.

Namen und Bezeichner

Bevorzugter Name
Copper sulfide (CuS)
IUPAC
copper sulfide
Englischer Name
Cu2S
Molmasse
0

Namen und Synonyme

Copper(2+) sulfideCopper BlueMonocopper monosulfideKL4YU612X7DTXSID0061666CHEBI:51110NSC-47694CI 77450RefChem:127880DTXCID401507829cpd with unspecified MF of cupric sulfide215-271-2
Weitere Namen anzeigen
Cu2S
1317-40-4C.I. 77450Copper sulfide (CuS)Copper(II) sulfideCupric sulfideHorace Vernet's BlueNatural covellitesulfanylidenecopper

Datenbank-Bezeichner

CAS
11115-78-9、12054-07-8、1317-40-4
PubChem CID
165914
DTXSID
DTXSID0061666
ChEBI
CHEBI:51110
UNII
KL4YU612X7

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA)
1 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
1
Frei drehbare Bindungen
0
Schwere Atome
2
Formalladung
0
Komplexität
0

Experimentelle und physikochemische Eigenschaften

Chemical ClassesMetals -> Metals, Inorganic Compounds
SpringerMaterials Propertieselectron density of states
Density · 2 Einträge

4.76

4.6 @25 °C

Color/Form · 2 Einträge

Black powder or lumps

Black hexagonal crystals

Solubility · 3 Einträge

0.000033 G/100 CC WATER @ 18 °C.

Insoluble in water, ethanol, dilute acids and alkaline solutions

Virtually insoluble in water, but soluble in alkali cyanides and in aqueous ammonia solution with complex ion formation

Boiling Point200 °C @760 [mm Hg]
DecompositionMelting point= 220 °C (decomp)
Refractive IndexINDEX OF REFRACTION: 1.45
Physical Description · 2 Einträge

Large Crystals; Other Solid; Wet Solid

Black solid; [Merck Index]

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

Gefahrenhinweise

Regulatory Information · 3 Einträge

Chemical: Copper sulfide (CuS)

Copper sulfide (CuS) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Copper sulfide (CuS) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Copper sulfide (CuS): Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationIMAP assessments - Copper sulfide (CuS): Human health tier I assessment
Hazards SummaryMay decompose on exposure to moisture; May cause irritation; [MSDSonline] See Copper.
NIOSH RecommendationsRecommended Exposure Limit: 10 Hr Time-Weighted Avg: 1 mg/cu m. /Copper (dusts and mists)/
Clean Water Act RequirementsToxic pollutant designated pursuant to section 307(a)(1) of the Federal Water Pollution Control Act and is subject to effluent limitations. /Copper and cmpd/
State Drinking Water Guidelines(AZ) ARIZONA 1300 ug/l /Copper/
Federal Drinking Water StandardsEPA 1300 ug/l (Action Level) /Copper/
Federal Drinking Water GuidelinesEPA 1000 ug/l /Copper/
Hazardous Reactivities and Incompatibilities · 3 Einträge

HYDROGEN PEROXIDE REACTS VIGOROUSLY WITH ... CUPRIC SULFIDE.

Copper sulfide explodes on contact with a concn soln of chloric acid or chlorates of cadmium, magnesium, or zinc.

Chemie und Industrie

Pharmakologische Informationen

Bionecessity · 1 Eintrag

Copper /is/ essential for erythropoiesis in rats fed a milk-based diet. /Anemia was able to be corrected/ by the addition to the diet of ash from animal or vegetable sources. ... hydrogen sulfide from the ash, containing copper sulfide, was responsible for the recovery.

Metabolism/Metabolites · 1 Eintrag

Copper is mainly absorbed through the gastrointestinal tract, but it can also be inhalated and absorbed dermally. It passes through the basolateral membrane, possibly via regulatory copper transporters, and is transported to the liver and kidney bound to serum albumin. The liver is the critical organ for copper homoeostasis. In the liver and other tissues, copper is stored bound to metallothionein, amino acids, and in association with copper-dependent enzymes, then partitioned for excretion through the bile or incorporation into intra- and extracellular proteins. The transport of copper to the peripheral tissues is accomplished through the plasma attached to serum albumin, ceruloplasmin or low-molecular-weight complexes. Copper may induce the production of metallothionein and ceruloplasmin. The membrane-bound copper transporting adenosine triphosphatase (Cu-ATPase) transports copper ions into and out of cells. Physiologically normal levels of copper in the body are held constant by alterations in the rate and amount of copper absorption, compartmental distribution, and excretion. (L277, L279)

Absorption, Distribution and Excretion · 2 Einträge

... COPPER SULFIDES ... ARE POORLY ABSORBED. /COPPER SULFIDES/

Ionic copper is absorbed from the stomach, duodenum, & jejunum. The initial absorption is about 30%, but the effective net absorption is only about 5% due to excretion of copper into the bile; biliary copper is bound to protein, & this complex is not reabsorbed. Absorption is influenced by a number of factors including the chemical forms of copper: oxides, hydroxides, iodides, glutamates, citrates, & pyrophosphates of copper are readily absorbed, but copper sulfides & other water insoluble salts are poorly absorbed. Copper complexes of some amino acids are easily absorbed, whereas copper porphyrins present in meat are very poorly absorbed. /Soluble copper salts/

Verwendung und Herstellung

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Auf dieser SeiteGrundinformationenÜberblickNamen und BezeichnerEigenschaftenSicherheit und RegulatorischesChemie und IndustrieZugehörige ReaktionenNotizen zur Verbindung
Stability/Shelf LifeSTABLE IN AIR WHEN DRY; OXIDIZED TO COPPER SULFATE BY MOIST AIR.
Other Experimental Properties · 4 Einträge

TRANSITION POINT @ 103 °C.

Stable in air when dry oxidized to copper sulfate by moist air

Decomposes at 220 °C; decomposed by hot nitric acid; it is stable in dry air, but is slowly oxidized to copper(II) sulfate in moist air.

transition 507 °C

Physikochemische Eigenschaften

Dichte
4.68 g/cm3 · 4.68 g/cm3
EPA chemische Informationen
Copper sulfide (11115-78-9)

Solutions of sodium hypobromite are decomposed by powerful catalytic action of cupric ions, even as impurities. /Cupric salts/

Sicherheit und Schutzausrüstung

Exposure Control and Personal Protection0.01 [mg/m3], respirable fraction (Cu, inorganic cmpnds)[German Research Foundation (DFG)]
Disposal Methods · 2 Einträge

SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

ETHYLENEDIAMINE TETRAACETIC ACID USED AS AN INHIBITOR OF COPPER SULFIDE PRECIPITATION IN ITS REMOVAL FROM WASTEWATER.

Minimum Risk LevelAcute Oral: 0.01 mg/kg/day (L134) Intermediate Oral: 0.01 mg/kg/day (L134)
Threshold Limit Values (TLV) · 3 Einträge

1.0 [mg/m3], as Cu

8 hr Time Weighted Avg (TWA): 1 mg/cu m. /Copper dusts and mists, as Cu/

Excursion Limit Recommendation: Excursions in worker exposure levels may exceed 3 times the TLV-TWA for no more than a total of 30 minutes during a work day, and under no circumstances should they exceed 5 times the TLV-TWA, provided that the TLV-TWA is not exceeded. /Copper dusts and mists, as Cu/

Permissible Exposure Limit (PEL)1.0 [mg/m3], as Cu
Protective Action Criteria (PAC) · 3 Einträge

0.3 [mg/m3]

3.3 [mg/m3]

20 [mg/m3]

Immediately Dangerous to Life or Health (IDLH)100.0 [mg/m3], as Cu

Toxikologische Informationen

Treatment · 1 Eintrag

EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.

Health Effects · 1 Eintrag

People must absorb small amounts of copper every day because copper is essential for good health, however, high levels of copper can be harmful. Very-high doses of copper can cause damage to your liver and kidneys, and can even cause death. Copper may induce allergic responses in sensitive individuals. (L278, L279)

Adverse EffectsOccupational hepatotoxin - Secondary hepatotoxins: the potential for toxic effect in the occupational setting is based on cases of poisoning by human ingestion or animal experimentation.
Exposure RoutesOral (L277) ; inhalation (L277) ; dermal (L277)
Toxicity Summary · 1 Eintrag

Excess copper is sequestered within hepatocyte lysosomes, where it is complexed with metallothionein. Copper hepatotoxicity is believed to occur when the lysosomes become saturated and copper accumulates in the nucleus, causing nuclear damage. This damage is possibly a result of oxidative damage, including lipid peroxidation. Copper inhibits the sulfhydryl group enzymes such as glucose-6-phosphate 1-dehydrogenase, glutathione reductase, and paraoxonases, which protect the cell from free oxygen radicals. It also influences gene expression and is a co-factor for oxidative enzymes such as cytochrome C oxidase and lysyl oxidase. In addition, the oxidative stress induced by copper is thought to activate acid sphingomyelinase, which lead to the production of ceramide, an apoptotic signal, as well as cause hemolytic anemia. Copper-induced emesis results from stimulation of the vagus nerve. (L277, T49, A174, L280)

Signs and SymptomsBreathing high levels of copper can cause irritation of the nose and throat. Ingesting high levels of copper can cause nausea, vomiting, diarrhea, headache, dizziness, and respiratory difficulty. (L278, L279)
Natural Pollution SourcesOccurs in nature as the mineral covellite, or indigo copper (blue, hexagonal or monoclinic crystals).
Artificial Pollution Sources... Copper sulfides ... may originate from mining and ore crushing and beneficiation processes. /Copper sulfides/
Carcinogen ClassificationNo indication of carcinogenicity to humans (not listed by IARC).
Non-Human Toxicity Excerpts · 5 Einträge

THE EFFECT ON THE CHINESE HAMSTER OVARY CELLS EXPOSED TO CRYSTALLINE CUPRIC SULFIDE AT 10 UG/ML FOR 24 HR WAS INDUCTION OF DNA STRAND BREAKS.

EXPERIMENTS ON THE EFFECT OF DIFFERENT ZINC & COPPER SALTS UPON THE ACTINOMYCETALES WERE CARRIED OUT USING THE POT METHOD BASED ON INSERTION OF DIFFERENT METAL SALTS @ 7500 PPM (IN TERMS OF METAL) INTO PREPD FOREST SOIL. COPPER SULFIDE SHOWED NO TOXIC EFFECT.

The carcinogenicity of cupric oxide, cupric sulfide, and cuprous sulfide in 2 to 3 month old Wistar rats /was studied/. Groups of 30-32 rats were given single im injections containing 20 mg of cupric oxide (16 mg copper), cupric sulfide (13.3 mg copper), and cuprous sulfide (16 mg copper) into the left and the right thigh of each rat. All animals were observed for up to 20 months, after which histopathological evaluation was conducted. Controls were not reported. Of the animals receiving cupric oxide, cupric sulfide, and cuprous sulfate, the ratios of animals surviving the experiment/animals dosed were 10/32, 19/30, and 18/30, respectively. No injection site tumors were observed, and the groups of animals receiving cupric oxide, cupric sulfide, and cuprous sulfide had 0, 2 (mammary fibroadenomas and reticulocytoma), and 1 (mammary fibroadenoma), respectively.

Enhanced simian adenovirus transformation /was induced/ in Syrian hamster embryonic cells with the addition of 0.38 mM copper sulfide and to a lesser extent with copper sulfate. Single strand breaks in DNA in isolated rat hepatocytes were detected after exposure to 1.0 mM, but not 0.03 or 0.3 mM cupric sulfate. This is a false positive because cytotoxicity was greater than 30% and cell lysis would result in DNA fragmentation.

For more Non-Human Toxicity Excerpts (Complete) data for CUPRIC SULFIDE (7 total), please visit the HSDB record page.

Antidote and Emergency Treatment · 2 Einträge

Basic treatment: Establish a patent airway. Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for shock and treat if necessary ... . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with normal saline during transport ... . Do not use emetics. For ingestion, rinse mouth and administer 5 ml/kg up to 200 ml of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool. Administer activated charcoal ... . /Copper and related compounds/

Advanced treatment: Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious. Start an IV with lactated Ringer's /SRP: "To keep open", minimal flow rate/. Watch for signs of fluid overload. For hypotension with signs of hypovolemia, administer fluid cautiously. Consider vasopressors if hypotensive with a normal fluid volume. Watch for signs of fluid overload ... . Use proparacaine, hydrochloride to assist eye irrigation ... . /Copper and related compounds/

Regulatorische Informationen

Clean Water Act RequirementsToxic pollutant designated pursuant to section 307(a)(1) of the Federal Water Pollution Control Act and is subject to effluent limitations. /Copper and cmpd/
State Drinking Water Guidelines(AZ) ARIZONA 1300 ug/l /Copper/
Federal Drinking Water StandardsEPA 1300 ug/l (Action Level) /Copper/
Federal Drinking Water GuidelinesEPA 1000 ug/l /Copper/
Uses · 6 Einträge

Occurs in nature as the mineral covellite; [Merck Index] Used in antifouling paints, mixed catalysts, and to develop aniline black dyes in textile printing; Also used as a varnish pigment, oxidizing agent, component of solid state electrodes, and thin-film solar cell with cadmium sulfide; [HSDB]

Semiconductor Manufacturing [Category: Industry]

In antifouling paints, in prepn of mixed catalysts; in development of aniline black dye in textile printing.

PIGMENT FOR LINSEED OIL VARNISHES.

OXIDIZING AGENT, EG, IN LITHIUM BATTERIES.

COMPONENT OF SOLID STATE ELECTRODES.

U.S. Production · 2 Einträge

2023: 50,000,000 - <100,000,000 lb

(1977) AT LEAST 4.5X10+8 G

Industry UsesOther
Methods of Manufacturing · 4 Einträge

Prepn: Glemser, Sauer in Handbook of Preparative Inorganic Chemistry, vol 2, G Brauer, ed (Academic Press, New York, 2nd ed, p 1017 (1965).

By passing hydrogen sulfide gas into a soln of a copper salt.

REACTION OF COPPER WITH MOLTEN SULFUR FOLLOWED BY BOILING IN SODIUM HYDROXIDE; REACTION OF SODIUM SULFIDE WITH AQUEOUS COPPER SULFATE.

Prepared by melting an excess of sulfur with copper(I) sulfide or by precipitation with hydrogen sulfide from a solution of anhydrous copper(II) chloride in anhydrous ethanol.

General Manufacturing Information · 3 Einträge

Primary Metal Manufacturing

Copper sulfide (CuS): ACTIVE

A LITHIUM-CUPRIC SULFIDE CELL WHICH MAKES MAX USE OF THE SHAPE OF A PACEMAKER'S BATTERY COMPARTMENT WAS DEVELOPED. THE CELL HAS A STABLE VOLTAGE THROUGHOUT 90% OF ITS LIFETIME.

Anbieter1 Anbieter

Service Chemical Inc.[email protected]