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Palladiumsulfat

Sulfuric acid, palladium(2+) salt (1:1)

HCID 166846
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Grundinformationen

CAS
13566-03-5
Standard-SMILES
O=S(=O)([O-])[O-].[Pd+2]
InChIKey
RFLFDJSIZCCYIP-UHFFFAOYSA-L
Summenformel
O4PdS
Durchschnittliche Molmasse
202,49 g/mol
Monoisotopische Masse
201,85521

Überblick

Palladium(II) sulfate is a sulfate of palladium. Palladium is a chemical element with the chemical symbol Pd and an atomic number of 46. It is found as a free metal alloyed with gold and other platinum group metals and in the rare minerals cooperite and polarite. (L794)

Namen und Bezeichner

Bevorzugter Name
Sulfuric acid, palladium(2+) salt (1:1)
IUPAC
palladium(2+) sulfate
Lokaler Name
Palladiumsulfat
Englischer Name
Palladium(II) sulfate
Summenformel
O4PdS
Molmasse
202.48

Namen und Synonyme

13566-03-5Palladium(2+) sulfatePalladium sulphatePalladium monosulfatePalladium sulfate (PdSO4)Sulfuric acid, palladium(2+) salt (1:1)DTXSID30884517EINECS 236-957-8RefChem:889914DTXCID501023953236-957-8Palladium(II) sulfate
Weitere Namen anzeigen
Dichloro[1,1'-bis(di-t-butylphosphino)ferrocene]palladium(II)palladium(ii) sulfate, solutionadium(II) suLPALLADOUSSULPHATEPalladium(Ⅱ) sulfatePalladium(II) Sufate
Palladium sulfatePalladous sulfatepalladium(2+);sulfateSulfuric acid, palladium saltMFCD00011173Palladium( cento) sulfate22723-63-3Q4445811

Datenbank-Bezeichner

CAS
13566-03-5、22723-63-3
PubChem CID
166846
DTXSID
DTXSID30884517
EC Number
236-957-8

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA)
88,6 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
4
Frei drehbare Bindungen
0
Schwere Atome
6
Formalladung
0
Komplexität
62,2

Physikochemische Eigenschaften

Siedepunkt
330 ℃ · 330℃(lit.)
Dichte
3.24 · 3.24[at 20℃]
storage temp.
Inert atmosphere,Room Temperature
Aggregatzustand
crystal
Farbe
brown
Wasserlöslichkeit
Fully miscible with water.
Major Application
PEM fuel cellshomogeneous catalystmaterial synthesis precursor
InChI
InChI=1S/H2O4S.Pd/c1-5(2,3)4;/h(H2,1,2,3,4);/q;+2/p-2
InChIKey
RFLFDJSIZCCYIP-UHFFFAOYSA-L
SMILES
S([O-])([O-])(=O)=O.[Pd+2]
CAS Datenbank
13566 · 13566-03-5(CAS DataBase Reference)
EPA chemische Informationen
Sulfuric acid, palladium(2+) salt (1:1) (13566-03-5)

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

GHS-Klassifizierung

GHS Classification · 4 Einträge

Danger

H290 (23.3%): May be corrosive to metals [Warning Corrosive to Metals]

P234, P260, P264, P264+P265, P270, P273, P280, P301+P317, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P330, P363, P390, P391, P405, P406, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 129 reports by companies from 8 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Gefahrenhinweise

Regulatory Information · 3 Einträge

Chemical: Sulfuric acid, palladium(2+) salt (1:1)

REACH registered substance: Palladium sulphate (EC: 236-957-8)

Sulfuric acid, palladium(2+) salt (1:1): Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Other Safety InformationIMAP assessments - Sulfuric acid, palladium(2+) salt (1:1): Environment tier I assessment
Hazard Classes and CategoriesMet. Corr. 1 (23.3%)

Toxikologische Informationen

Treatment · 1 Eintrag

EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.

Chemie und Industrie

Pharmakologische Informationen

Metabolism/Metabolites · 1 Eintrag

Palladium may be absorbed through oral, dermal, and inhalation exposure. Once in the body it distributes to the kidney, liver, spleen, lymph nodes, adrenal gland, lung and bone. Palladium's ability to form complexes allows it the bind to amino acids, proteins, DNA, and other macromolecules. Palladium and its metabolites are excreted in the urine and faeces. (A21)

Verwendung und Herstellung

General Manufacturing InformationSulfuric acid, palladium(2+) salt (1:1): ACTIVE

Anwendungen

VerwendenPalladium(II) sulfate is used as a catalyst in chemical synthesis.Palladium(II) sulfate was used with a phosphomolybdovanadic acid to convert 1-butene (R = C2H5) to 2-butanone with more than 95% selectivity at 98% conversion.

Anbieter100 Anbieter

北京华美互利生物化工010-56205725 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
河南多贝化工有限公司0370-6999054 17550096163 · [email protected]
上海腾准生物科技有限公司19821570922 · [email protected]
上海毕得医药科技股份有限公司400-1647117 13681763483 · [email protected]
清宁生物(江苏博泉生物科技有限公司)19352250998 · [email protected]

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Nikkaji
J241.188A
Health EffectsContact with palladium may cause palladium sensitivity and allergy. Animal studies have shown that palladium may damage the liver and kidney. (L798)
Toxicity Summary · 1 Eintrag

Due to their ability to form strong complexes with both inorganic and organic ligands, palladium ions can disturb cellular equilibria, replace other essential ions, and interact with functional groups of macromolecules, such as proteins or DNA. Palladium complexes binding to DNA and RNA leads to strand breakage. Palladium ions are able to inhibit most major cellular functions, including DNA and RNA synthesis. Palladium compounds have been shown to bind to and inhibit various enzymes, including creatine kinase and prolyl hydroxylase. (L798)

Signs and SymptomsSkin contact with palladium may cause contact dermatitis, erythema, and oedema. (L798)
Carcinogen ClassificationNo indication of carcinogenicity to humans (not listed by IARC).

Sicherheitsdaten

wgk
3
tsca
TSCA listed
ridadr
UN 3260 8/PG 2
risk_code
34
hazard_code
C
safety_code
22-26-36/37/39-45
hazard_class
8
Speicherklasse
8A - Combustible corrosive hazardous materials
Hazard Classifications
Eye Dam. 1Met. Corr. 1Skin Corr. 1B
T&W GROUP021-61551611 13296011611 · [email protected]
Dayang Chem (Hangzhou) Co.,Ltd.+86-0571-88938639 17705817739 · [email protected]
上海卡伦姆生化科技有限公司15837198050 · [email protected]
郑州德元凯化工有限公司17837139533 · [email protected]
上海晶抗生物工程有限公司021-54721350 13524668266 · [email protected]
阿法埃莎(中国)化学有限公司400-6106006 · [email protected]
安耐吉化学&3A(安徽泽升科技股份有限公司)400-0056266 · [email protected]
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Hebei Qige Biological Technology Co. Ltd+86 +8618733132031
艾科试剂4008-755-333 18080918076 · [email protected]
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Alfa Chemistry+1-5166625404 · [email protected]
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上海石洋化工有限公司+86-021-56795779 +86-13651600618 · [email protected]
湖北万业众诚化学试剂有限责任公司18671296875 · [email protected]
启源(广东)医药化工有限公司18026564465 · [email protected]
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上海源叶生物科技有限公司13636370518 · [email protected]
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