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Tetraaluminiumtricarbid

Aluminum carbide (Al4C3)

HCID 16685054
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Grundinformationen

CAS
12656-43-8
Standard-SMILES
[Al]#[C][Al]=[C]=[Al][C]#[Al]
InChIKey
CAVCGVPGBKGDTG-UHFFFAOYSA-N
Summenformel
C3Al4
Durchschnittliche Molmasse
143,96 g/mol
Monoisotopische Masse
143,926154

Überblick

Aluminum carbide appears as a yellow powder or crystals. Used to make other chemicals.

Namen und Bezeichner

Bevorzugter Name
Aluminum carbide (Al4C3)
IUPAC
alumanylidynemethyl(alumanylidynemethylalumanylidenemethylidene)alumane
Lokaler Name
Tetraaluminiumtricarbid
Englischer Name
ALUMINUM CARBIDE
Summenformel
C3Al4
Molmasse
143.96

Namen und Synonyme

ALUMINUM CARBIDE1299-86-1Aluminum carbide (Al4C3)RefChem:111655DTXSID10107594DTXCID301324571215-076-212656-43-8alumanylidynemethyl(alumanylidynemethylalumanylidenemethylidene)alumaneTetraaluminium tricarbideEINECS 215-076-2UN1394
Weitere Namen anzeigen
AL4C3luminiumcarbideALUMINIUM CARBIDEAluminum carbidieAluminumcarbide,98%aluminumcarbide(al4c3)Tetraaluminum tricarbideAluminiumcarbide,metalsbasis
SCHEMBL29353792Al4C3 Aluminium carbide (H?gan?s)Aluminum carbide, powder, ~325 mesh, 95%Aluminum carbide [UN1394] [Dangerous when wet]

Datenbank-Bezeichner

CAS
12656-43-8、1299-86-1
PubChem CID
16685054
DTXSID
DTXSID10107594

Eigenschaften

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Polarare Oberfläche (TPSA)
0 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
0
Frei drehbare Bindungen
0
Schwere Atome
7
Formalladung
0
Komplexität
164

Experimentelle und physikochemische Eigenschaften

Chemical Classes · 2 Einträge

Metals -> Metals, Inorganic Compounds

Flammable agents - 3rd degree

SpringerMaterials Propertieselectron density of states
Density2.36 @25 °C
Melting Point2100 °C
Physical Description · 2 Einträge

Aluminum carbide appears as a yellow powder or crystals. Used to make other chemicals.

Yellow solid; [Merck Index] Yellow powder; [Alfa Aesar MSDS]

Physikochemische Eigenschaften

Schmelzpunkt
2100 °C · 2100°C
Siedepunkt
2200 °C · 2200°C (estimate)
Dichte
2.36 g/mL · 2.36 g/mL at 25 °C (lit.)
Löslichkeit
Soluble in dilute hydrochloric acid.
Aggregatzustand
powder
Farbe
Dark gray

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

GHS-Klassifizierung

GHS Classification · 5 Einträge

This chemical does not meet GHS hazard criteria for 2.1% (1 of 47) of reports.

Danger

H261 (97.9%): In contact with water releases flammable gas [Danger Substances and mixtures which in contact with water, emit flammable gases]

P231+P232, P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P402+P404, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 47 reports by companies from 7 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Gefahrenhinweise

Regulatory InformationThe New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)
DOT LabelDangerous When Wet
Fire Hazards · 2 Einträge

Excerpt from ERG Guide 138 [Substances - Water-Reactive (Emitting Flammable Gases)]:

· Produce flammable gases on contact with water.

Health Hazards · 2 Einträge

Excerpt from ERG Guide 138 [Substances - Water-Reactive (Emitting Flammable Gases)]:

· Inhalation or contact with vapors, substance or decomposition products may cause severe injury or death.

Hazards Summary · 1 Eintrag

Decomposes in water producing flammable methane; [Merck Index] A strong reducing agent that reacts with water; [CAMEO] Liberates highly flammable gases on contact with water; A skin, mucous membrane, and strong eye irritant; [Alfa Aesar MSDS] See CARBIDES.

Chemie und Industrie

Pharmakologische Informationen

Metabolism/Metabolites · 1 Eintrag

Aluminum is poorly absorbed following either oral or inhalation exposure and is essentially not absorbed dermally. The bioavailability of aluminum is strongly influenced by the aluminum compound and the presence of dietary constituents which can complex with aluminum and enhance or inhibit its absorption. Aluminum binds to various ligands in the blood and distributes to every organ, with highest concentrations found in bone and lung tissues. In living organisms, aluminum is believed to exist in four different forms: as free ions, as low-molecular-weight complexes, as physically bound macromolecular complexes, and as covalently bound macromolecular complexes. Absorbed aluminum is excreted principally in the urine and, to a lesser extent, in the bile, while unabsorbed aluminum is excreted in the faeces. (L739)

Verwendung und Herstellung

Uses · 3 Einträge

Used to reduce metal oxides and to make aluminum nitride and methane; [Merck Index] Also used as a catalyst, drying agent, and in metallurgy; [Hawley]

Metal Extraction and Refining [Category: Industry]

Aluminium carbide is a common impurity of technical calcium carbide and often forms as a corrosion product of graphite electrodes. It is used an abrasive in high-speed cutting tools and in pyrotechnics. (L750)

General Manufacturing InformationAluminum carbide (Al4C3): ACTIVE

Anwendungen

VerwendenAluminum carbide is used as an abrasive material for cutting tools. It is also used to reduce metal oxides and to prepare aluminum nitride and methane. It and also finds use in metallurgy. Further, it acts as a catalyst and a drying agent.

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EC Number
215-076-2
Wichte
2.36 · 2.36
Wasserlöslichkeit
4 in · decomposes with the evolution of CH4 in H2O [MER06]
Merck
14 · 14,335
Stabilität
4 · Decomposes in water with evolution of CH4
InChI
1S/3C.4Al
InChIKey
CAVCGVPGBKGDTG-UHFFFAOYSA-N
SMILES
[Al]#C[Al]=C=[Al]C#[Al]
CAS Datenbank
1299 · 1299-86-1
EPA chemische Informationen
Aluminum carbide (Al4C3) (1299-86-1)
DOT ID and Guide1394 138
Reactive GroupNitrides, Phosphides, Carbides, and Silicides
Reactivity AlertsStrong Reducing Agent
Reactivity ProfileALUMINUM CARBIDE is a reducing agent. May react vigorously with oxidizing materials. Incandescence on warming with lead dioxide or potassium permanganate, [Mellor, 1946, Vol. 5, 872].
DOT Hazard Classification · 4 Einträge

Aluminum carbide

UN1394

Div 4.3 Dangerous when wet material (49 eCFR § 173.124)

PG II: the degree of danger presented by the material is medium

Air and Water ReactionsDecomposes slowly in presence of water or moist air to generate heat and flammable methane gas [Merck 12th ed. 1989]. Consequently a dangerous fire risk.
Hazard Classes and Categories · 2 Einträge

Water-react. 2 (97.9%)

Flammable agents - 3rd degree, Reactive agents - 3rd degree

Sicherheit und Schutzausrüstung

Fire FightingExcerpt from ERG Guide 138 [Substances - Water-Reactive (Emitting Flammable Gases)]:
Accidental Release Measures · 2 Einträge

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

First Aid · 2 Einträge

Excerpt from ERG Guide 138 [Substances - Water-Reactive (Emitting Flammable Gases)]:

General First Aid:

Exposure Control and Personal Protection· Wear positive pressure self-contained breathing apparatus (SCBA).
Nonfire Spill ResponseExcerpt from ERG Guide 138 [Substances - Water-Reactive (Emitting Flammable Gases)]:
Isolation and Evacuation · 2 Einträge

Excerpt from ERG Guide 138 [Substances - Water-Reactive (Emitting Flammable Gases)]:

Immediate precautionary measure

Minimum Risk LevelIntermediate Oral: 1.0 mg/kg/day (L134) Chronic Oral: 1.0 mg/kg/day (L134)
Protective Action Criteria (PAC) · 3 Einträge

13 [mg/m3]

150 [mg/m3]

880 [mg/m3]

Personal Protective Equipment (PPE)Excerpt from ERG Guide 138 [Substances - Water-Reactive (Emitting Flammable Gases)]:
Emergency Response Planning Guidelines· DO NOT USE WATER OR FOAM.

Toxikologische Informationen

Health Effects · 1 Eintrag

Aluminum targets the nervous system and causes decreased nervous system performance and is associated with altered function of the blood-brain barrier. The accumulation of aluminum in the body may cause bone or brain diseases. High levels of aluminum have been linked to Alzheimer's disease. A small percentage of people are allergic to aluminium and experience contact dermatitis, digestive disorders, vomiting or other symptoms upon contact or ingestion of products containing aluminium. (L739, L740)

Exposure RoutesOral (L739) ; inhalation (L739)
Toxicity Summary · 1 Eintrag

The main target organs of aluminum are the central nervous system and bone. Aluminum binds with dietary phosphorus and impairs gastrointestinal absorption of phosphorus. The decreased phosphate body burden results in osteomalacia (softening of the bones due to defective bone mineralization) and rickets. Aluminum's neurotoxicity is believed to involve several mechanisms. Changes in cytoskeletal protein functions as a results of altered phosphorylation, proteolysis, transport, and synthesis are believed to be one cause. Aluminum may induce neurobehavioral effects by affecting permeability of the blood-brain barrier, cholinergic activity, signal transduction pathways, lipid peroxidation, and impair neuronal glutamate nitric oxide-cyclic GMP pathway, as well as interfere with metabolism of essential trace elements because of similar coordination chemistries and consequent competitive interactions. It has been suggested that aluminum's interaction with estrogen receptors increases the expression of estrogen-related genes and thereby contributes to the progression of breast cancer (A235), but studies have not been able to establish a clear link between aluminum and increased risk of breast cancer (A15468). Certain aluminum salts induce immune responses by activating inflammasomes. (L739, A235, A236)

Signs and Symptoms · 1 Eintrag

Inhalating aluminum dust causes coughing and abnormal chest X-rays. A small percentage of people are allergic to aluminium and experience contact dermatitis, digestive disorders, vomiting or other symptoms upon contact or ingestion of products containing aluminium. (L739, L740)

Carcinogen Classification · 1 Eintrag

Not listed by IARC. IARC classified aluminum production as carcinogenic to humans (Group 1), but did not implicate aluminum itself as a human carcinogen. (L135) A link between use of aluminum-containing antiperspirants and increased risk of breast cancer has been proposed (A235), but studies have not been able to establish a clear link (A15468).

Sicherheitsdaten

wgk
3
tsca
TSCA listed
ridadr
UN 1394
risk_code
15-36/37/38
hazard_code
F,Xi
safety_code
26-43
hazard_class
4.3
packing_group
II
Speicherklasse
4.3 - Hazardous materials which set free flammable gases upon contact with water
Hazard Classifications
Eye Irrit. 2Skin Irrit. 2STOT SE 3Water-react 2
Dimethylquecksilber