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Copper(II) fluoborate

HCID 170058
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Grundinformationen

CAS
14735-84-3
Standard-SMILES
F[B-](F)(F)F.F[B-](F)(F)F.[Cu+2]
InChIKey
HMUNZEYTSRPVBE-UHFFFAOYSA-N
Summenformel
B2CuF8
Durchschnittliche Molmasse
237,16 g/mol
Monoisotopische Masse
236,935433

Überblick

Copper fluoroborate is a dark-blue odorless aqueous solution. Sinks and mixes with water. (USCG, 1999)

Namen und Bezeichner

Bevorzugter Name
Copper(II) fluoborate
IUPAC
copper ditetrafluoroborate
Englischer Name
Copper(II) tetrafluoroborate hydrate
Summenformel
BCuF4H2O+
Molmasse
168.36

Namen und Synonyme

Copper fluoroborateCopper(II) TetrafluoroborateCopper fluoborateCupric fluoborateBorate(1-), tetrafluoro-, copper(2+) (2:1)Copper(II) fluoborateCopper(2+) tetrafluoroborate(1-)EINECS 253-959-4DTXSID90885722RefChem:578895CUPRIC FLUOBORATE SOLUTIONCopper(2+) tetrafluoroborate(1)
Weitere Namen anzeigen
Copper(II) tetrafluoroborate xhydrateCOPPER(II)TETRAFLUOROBORATEHYDRATE,99%Copper(2+) tetrafluoroborate hydrate (1:2:1)Borate(1-), tetrafluoro-, copper(2+) (2:1), hydrate (9CI)
DTXCID001025085COPPER BOROFLUORIDE SOLUTIONCOPPER(II) FLUOBORATE SOLUTIONTetrafluoroboric acid, copper(II) saltBorate(1), tetrafluoro, copper(2+) (2:1)253-959-4629-673-4207121-39-9

Datenbank-Bezeichner

CAS
14735-84-3、207121-39-9、38465-60-0
PubChem CID
170058
DTXSID
DTXSID90885722

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA)
0 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
10
Frei drehbare Bindungen
0
Schwere Atome
11
Formalladung
0
Komplexität
19,1

Experimentelle und physikochemische Eigenschaften

Chemical ClassesMetals -> Metals, Inorganic Compounds
Density1.54 at 68 °F (USCG, 1999) - Denser than water; will sink
Boiling Point212 °F at 760 mmHg (approx.) (USCG, 1999)
Physical Description · 2 Einträge

Copper fluoroborate is a dark-blue odorless aqueous solution. Sinks and mixes with water. (USCG, 1999)

Aqueous solution: Dark-blue odorless liquid; [CAMEO] Hexahydrate: Blue crystals; [Strem Chemicals MSDS]

Physikochemische Eigenschaften

storage temp.
Store at room temperature, keep dry and cool
Aggregatzustand
crystal
Farbe
blue
InChI
1S/2BF4.Cu.H2O/c2*2-1(3,4)5;;/h;;;1H2/q2*-1;+2;
InChIKey
JYLPBVRGTDBGBM-UHFFFAOYSA-N
SMILES
O.[Cu++].F[B-](F)(F)F.F[B-](F)(F)F

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

GHS-Klassifizierung

GHS Classification · 6 Einträge

Danger

H302 (97.5%): Harmful if swallowed [Warning Acute toxicity, oral]

P260, P261, P264, P270, P271, P280, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P330, P362+P364, P363, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 40 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

H290 (71.4%): May be corrosive to metals [Warning Corrosive to Metals]

Gefahrenhinweise

Regulatory Information · 3 Einträge

Chemical: Borate(1-), tetrafluoro-, copper(2+) (2:1)

REACH registered substance: Copper(2+) tetrafluoroborate(1-) (EC: 253-959-4)

Borate(1-), tetrafluoro-, copper(2+) (2:1): Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

DOT LabelPoison Corrosive
Fire HazardsSpecial Hazards of Combustion Products: Irritating hydrogen fluoride gas may form in fires. (USCG, 1999)
Health HazardsInhalation of mist irritates nose and throat. Ingestion causes pain and vomiting. Contact causes severe irritation of eyes and irritation of skin. (USCG, 1999)
Hazards Summary · 1 Eintrag

A skin, eye, and respiratory tract irritant; [CAMEO] A severe skin and eye irritant; [CHRIS] Acute copper poisoning after ingestion can cause liver injury, methemoglobinemia, and hemolytic anemia. Acute renal failure may result, secondary to massive hemoglobinuria. [Goldfrank, p. 1259] An irritant that may cause serious eye injury and delayed deep skin burns; [Strem Chemicals MSDS] See Potassium tetrafluoroborate. See Copper.

Chemie und Industrie

Verwendung und Herstellung

Uses · 2 Einträge

Used in copper plating and to produce printed circuits; [Ullmann]

Electroplating [Category: Plate]

General Manufacturing InformationBorate(1-), tetrafluoro-, copper(2+) (2:1): ACTIVE

Anwendungen

VerwendenStarting material for homometallic, trinuclear heteroscorpionate complexes applied in studies of electronic and magnetic properties.1

Anbieter77 Anbieter

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EC Number
253-959-4、629-673-4、679-083-6
Reactive GroupNon-Redox-Active Inorganic Compounds
Reactivity ProfileCOPPER FLUOROBORATE may corrode some metals (USCG, 1999).
Air and Water ReactionsMixes with water.
Hazard Classes and Categories · 2 Einträge

Met. Corr. 1 (71.4%)

Acute Tox. 4 (97.5%)

Sicherheit und Schutzausrüstung

Fire FightingExcerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
First AidINHALATION: move to fresh air.
Exposure Control and Personal Protection0.01 [mg/m3], respirable fraction (Cu, inorganic cmpnds)[German Research Foundation (DFG)]
Nonfire Spill ResponseNeutralizing Agents for Acids and Caustics: Flush with water, rinse with dilute solution of sodium bicarbonate or soda ash. (USCG, 1999)
Isolation and EvacuationExcerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Threshold Limit Values (TLV)1.0 [mg/m3], as Cu
Permissible Exposure Limit (PEL)1.0 [mg/m3], as Cu
Personal Protective Equipment (PPE)Goggles or face shield; rubber apron and gloves (USCG, 1999)
Immediately Dangerous to Life or Health (IDLH)100.0 [mg/m3], as Cu

Toxikologische Informationen

Adverse EffectsOccupational hepatotoxin - Secondary hepatotoxins: the potential for toxic effect in the occupational setting is based on cases of poisoning by human ingestion or animal experimentation.

Sicherheitsdaten

wgk
3
ridadr
UN 3260 8/PG 2
risk_code
20/21/22-34
hazard_code
C
safety_code
26-36/37/39-45
hazard_class
8
Speicherklasse
8A - Combustible corrosive hazardous materials
Hazard Classifications
Acute Tox. 4 DermalAcute Tox. 4 InhalationAcute Tox. 4 OralEye Dam. 1Skin Corr. 1B
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