| GHS-Einstufung | WarningH315: Causes skin irritation [Warning Skin corrosion/irritation]P261, P264, P264+P265, P271, P272, P273, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P333+P317, P337+P317, P362+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation] |
|---|
| Regulatorische Informationen | Chemical: 2-Propenoic acid, hexyl ester2-Propenoic acid, hexyl ester is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 2-Propenoic acid, hexyl ester are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)Status: Active Update: 11-05-2018 https://echa.europa.eu/registration-dossier/-/registered-dossier/25826 |
|---|
| Brandgefahren | Combustible. Above 68 °C explosive vapour/air mixtures may be formed. |
|---|
| Gefahrenübersicht | Emergency treatment: IrritantsAcrylic acid esters of lower molecular weight cause skin, eye, and mucous membrane irritation[HSDB] A skin, eye, and respiratory tract irritantThis substance or an additive may cause skin sensitization[ICSC]CombustibleStabilized with hydroquinoneA severe eye irritantMay cause mild skin burns on prolonged contact[MSDSonline] |
|---|
| EG-Einstufung | Symbol: Xi, NR: 36/37/38-43-51/53S: (2)-24-26-37-61 |
|---|
| UN-Einstufung | UN Hazard Class: 9UN Pack Group: III |
|---|
| Chemical Dangers | The substance may polymerize. Decomposes on heating. This produces acrid fumes (acrylic acid, acrolein). |
|---|
| Physical Dangers | Vapours are uninhibited and may polymerize in vents or flame arresters, causing blockage. |
|---|
| Hazard Classes and Categories | Skin Irrit. 2 (100%)Eye irritation - category 2STOT SE 3 |
|---|
| Explosive Limits and Potential | Explosive limits , vol% in air: 0.9-? |
|---|
| Brandbekämpfung | Use dry powder, alcohol-resistant foam, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water. |
|---|
| Erste-Hilfe-Maßnahmen | Fresh air, rest.Remove contaminated clothes. Rinse and then wash skin with water and soap.Rinse with plenty of water (remove contact lenses if easily possible).Rinse mouth. Give one or two glasses of water to drink. Rest. Seek medical attention if you feel unwell. |
|---|
| Sichere Lagerung | Store only if stabilized. Cool. Provision to contain effluent from fire extinguishing. Store in an area without drain or sewer access. |
|---|
| Verschüttetes entsorgen | Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Collect leaking liquid in covered containers. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. |
|---|
| Preventive Measures | ADEQUATE EXHAUST VENTILATION SHOULD BE PROVIDED TO PROTECT THE WORKER FROM INHALATION OF FUMES. WORKERS SHOULD BE PROVIDED WITH HAND PROTECTION & EYE & FACE PROTECTION. MAINTENANCE & GOOD HOUSEKEEPING SHOULD BE ENSURED. /ACRYLIC RESINS/ |
|---|
| Eye Prevention | Wear safety spectacles or eye protection in combination with breathing protection. |
|---|
| Fire Prevention | NO open flames. Above 68 °C use a closed system and ventilation. |
|---|
| Inhalation Risk | No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20 °C. |
|---|
| Skin Prevention | Protective gloves. Protective clothing. |
|---|
| Ingestion Prevention | Do not eat, drink, or smoke during work. |
|---|
| Inhalation Prevention | Use ventilation, local exhaust or breathing protection. |
|---|
| Effects of Long Term Exposure | Repeated or prolonged contact may cause skin sensitization. |
|---|
| Unerwünschte Wirkungen | Dermatotoxin - Skin burns. |
|---|
| Expositionspfade | The substance can be absorbed into the body by inhalation of its aerosol. |
|---|
| Signs and Symptoms | Cough. Sore throat.Redness. Pain. |
|---|
| ICSC Environmental Data | The substance is toxic to aquatic organisms. It is strongly advised not to let the chemical enter into the environment. |
|---|
| Human Toxicity Excerpts | THE LOWER-MOLECULAR-WT ESTERS OF ACRYLIC ACIDS ARE IRRITANTS TO SKIN, EYES, & MUCOUS MEMBRANES. /ESTERS OF ACRYLIC ACID/ |
|---|
| Wassergefährdungsklasse (WGK) | 2 |
|---|
| TSCA-Inventar-Status | TSCA listed |
|---|
| UN-Transportnummer | 3082 |
|---|
| Zollcode | 29161290 |
|---|
| RTECS-Nr. | AT1450000 |
|---|
| R-Sätze (R) | 36/37/38-43-51/53 |
|---|
| Toxizität | rabbit,LD50,skin,5660uL/kg (5.66mL/kg),American Industrial Hygiene Association Journal. Vol. 30, Pg. 470, 1969. |
|---|
| Gefahrensymbole | Xi,N |
|---|
| Sicherheitshinweise (S) | 24-26-37-61 |
|---|
| Gefahrenklasse | 9Aquatic Acute 1Aquatic Chronic 1Eye Irrit. 2Skin Irrit. 2Skin Sens. 1BSTOT SE 3 |
|---|
| Verpackungsgruppe | III |
|---|
| Lagerklasse | 10 - Combustible liquids |
|---|
| Gefahrstoffdaten | 2499-95-8(Hazardous Substances Data) |
|---|
