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2,2',3,3'-Tetrahydro-1,1'-spirobi[indene]-7,7'-diol
(S)-2,2',3,3'-tetrahydro-1,1'-spirobi[indene]-7,7'-diol · SF120084 · 1,1'-SPIROBIINDANE-7,7'-DIOL · (S)-1,1'-Spirobiindane-7,7'-diol · Ra)-1,1'-Spirobiindane-7,7'-Diol · (S)-7,7'-Dihydroxy-1,1'-spirobiindane · (S)-1,1'-spirobiindane-7,7'-diol, (S)-SPINOL · (R)-1,1'-spirobiindane-7,7'-diol, (R)-SPINOL
![Molekülstruktur von 2,2',3,3'-Tetrahydro-1,1'-spirobi[indene]-7,7'-diol](/img/chemical/178719513.png)
Identifikatoren & physikalische Daten
| CAS No. | 223259-63-0 |
|---|---|
| Summenformel | C17H16O2 |
| Durchschnittliche Molmasse | 252,31 g/mol |
| SMILES | Oc1cccc2c1C1(CC2)CCc2cccc(O)c21 |
| InChIKey | YBRDFCQKQVTQKX-UHFFFAOYSA-N |
Chemische & physikalische Eigenschaften
| XLogP | 4,1 |
|---|---|
| Polarare Oberfläche (TPSA) | 40,5 |
| H-Brücken-Donoren | 2 |
| H-Brücken-Akzeptoren | 2 |
| Frei drehbare Bindungen | 0 |
| Schwere Atome | 19 |
| Formalladung | 0 |
| Komplexität | 319 |
| Schmelzpunkt | 155-156℃ |
| Siedepunkt | 433.0±45.0 °C(Predicted) |
| Dichte | 1.34±0.1 g/cm3(Predicted) |
| Lagerbedingungen | under inert gas (nitrogen or Argon) at 2-8°C |
| Löslichkeit | Chloroform (Slightly), Methanol (Slightly) |
| Aggregatzustand | powder to crystaline |
| pKa (Säurekonstante) | 9.70±0.20(Predicted) |
| Farbe | White to Orange to Green |
| InChI | InChI=1S/C17H16O2/c18-13-5-1-3-11-7-9-17(15(11)13)10-8-12-4-2-6-14(19)16(12)17/h1-6,18-19H,7-10H2 |
| InChIKey | YBRDFCQKQVTQKX-UHFFFAOYSA-N |
| SMILES | [C@]12(C3=C(C=CC=C3O)CC1)C1=C(C=CC=C1O)CC2 |
Sicherheit & Vorschriften
| Zollcode | 2907.29.9000 |
|---|
Anwendungen & Verwendung
Verwenden
(S)-SPINOL is used to synthesis a new class of chiral phosphoric acids with spirobiindane as scaffold and employed to catalyze the asymmetric FriedelCrafts reaction of indoles with imines to afford 3-indolyl methanamines.