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tert-Butyl methacrylate

HCID 178940709
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GrundinformationenÜberblickNamen und BezeichnerEigenschaftenSicherheit und RegulatorischesChemie und IndustrieZugehörige ReaktionenNotizen zur Verbindung
TeilstruktursucheÄhnliche Strukturen suchen

Grundinformationen

CAS
25189-00-8
Standard-SMILES
C=C(C)C(=O)OC(C)(C)C
InChIKey
SJMYWORNLPSJQO-UHFFFAOYSA-N
Summenformel
C8H14O2
Durchschnittliche Molmasse
142,2 g/mol

Überblick

Tert-butyl methacrylate appears as a colorless liquid with an ester like odor. Less dense than water and insoluble in water.

Namen und Bezeichner

Bevorzugter Name
tert-Butyl methacrylate
IUPAC
tert-butyl 2-methylprop-2-enoate
Englischer Name
Poly(t-butyl methacrylate)
Summenformel
C8H14O2
Molmasse
142.19556

Namen und Synonyme

tert-Butyl methacrylate585-07-9T-BUTYL METHACRYLATEMethacrylic acid, tert-butyl ester2-Propenoic acid, 2-methyl-, 1,1-dimethylethyl estertert-Butyl 2-methylacrylateCCRIS 70391,1-Dimethylethyl 2-methyl-2-propenoateEINECS 209-548-7NSC 20957tert-Butyl 2-methylpropenoate1,1-dimethylethyl methacrylate
Weitere Namen anzeigen
POLY(TERT-BUTYL METHACRYLATE)ButylmethacrylateresinT-BUTYL METHACRYLATE RESINPoly(t-butyl methacrylate)tert-Butyl methacrylate resinPOLY(TERT-BUTYL METHACRYLATE) 2'500POLY(TERT-BUTYL METHACRYLATE) 5'000tert-butyl methacrylate homopolymerPOLY(TERT-BUTYL METHACRYLATE) 10'000POLY(TERT-BUTYL METHACRYLATE) 20'000
BRN 1746394tert-Butyl alcohol methacrylateNSC-20957DTXSID3060405F9029V5818BUTYL METHACRYLATE, TERT-EC 209-548-7TERT-BUTYL .ALPHA.-METHACRYLATE

Eigenschaften

Berechnete Struktureigenschaften

XLogP
2,5
Polarare Oberfläche (TPSA)
26,3 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
2
Frei drehbare Bindungen
3
Schwere Atome
10
Formalladung
0
Komplexität
151

Experimentelle und physikochemische Eigenschaften

Cosmetics · 2 Einträge

Cosmetic ingredients (t-Butyl Methacrylate) -> CIR (Cosmetic Ingredient Review)

Cosmetic ingredients (t-Butyl methacrylate) -> CIR (Cosmetic Ingredient Review)

SpringerMaterials PropertiesBoiling point
LogP2.54
Food Contact SubstancesFCS -> FDA Inventory of Food Contact Substances Listed in 21 CFR
Physical Description · 2 Einträge

Tert-butyl methacrylate appears as a colorless liquid with an ester like odor. Less dense than water and insoluble in water.

Liquid

Physikochemische Eigenschaften

Schmelzpunkt
0 °C · 0°C
Siedepunkt
0 °C · 0°C
Dichte
1.022 g/mL · 1.022 g/mL at 25 °C (lit.)
Brechungsindex
20 · n20/D 1.4638(lit.)
Flammpunkt

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

GHS-Klassifizierung

GHS Classification · 6 Einträge

This chemical does not meet GHS hazard criteria for 27.8% (71 of 255) of reports.

Warning

H226 (68.6%): Flammable liquid and vapor [Warning Flammable liquids]

P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 255 reports by companies from 12 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Warning

Gefahrenhinweise

Regulatory Information · 4 Einträge

2-Propenoic acid, 2-methyl-, 1,1-dimethylethyl ester is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 2-Propenoic acid, 2-methyl-, 1,1-dimethylethyl ester are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

PMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.

Status: Active Update: 06-04-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/2073

2-Propenoic acid, 2-methyl-, 1,1-dimethylethyl ester: Does not have an individual approval but may be used under an appropriate group standard

DOT LabelFlammable Liquid
Fire HazardsExcerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]:
Health HazardsExcerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]:
Reactive GroupAcrylates and Acrylic Acids

Chemie und Industrie

Verwendung und Herstellung

Uses · 2 Einträge

CIR ingredient: t-Butyl Methacrylate

CIR ingredient: t-Butyl methacrylate

U.S. Production2023: 250,000 - <550,000 lb
Industry UsesIntermediate
General Manufacturing Information · 2 Einträge

Paint and Coating Manufacturing

2-Propenoic acid, 2-methyl-, 1,1-dimethylethyl ester: ACTIVE

Anwendungen

VerwendenThese triblock terpolymers precursors may be used for the preparation of novel multi-compartmental core-crosslinked polymeric nanoparticles for various nanostructured systems.

Anbieter21 Anbieter

郑州阿尔法化工有限公司+86-18530059196 · [email protected]
济南百隆化学有限公司[email protected] · [email protected]
咸宁深蓝生物医药研发有限公司18171815831 · [email protected]
上海赛可锐生物科技有限公司021-58000709 13120558703 · [email protected]
安耐吉化学&3A(安徽泽升科技有限公司)021-58432009 400-005-6266 · [email protected]
上海维亦特生物科技有限公司15317051735 · [email protected]
山东西亚化学有限公司13355009207 13355009207 · [email protected]

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Datenbank-Bezeichner

CAS
25189-00-8
UNII
F9029V5818
EC Number
209-548-7
Nikkaji
J47.811C
0 °C · 0°C
Löslichkeit
8.65 solubility · 8.65 solubility parameter
Aggregatzustand
crystalline
Wasserlöslichkeit
8.65 · 8.65 (solubility parameter)
InChI
1S/C8H14O2/c1-6(2)7(9)10-8(3,4)5/h1H2,2-5H3
InChIKey
SJMYWORNLPSJQO-UHFFFAOYSA-N
SMILES
CC(=C)C(=O)OC(C)(C)C
Oberflächenspannung
30.4 mN/m · 30.4mN/m at 20°C
Reactivity AlertsHighly Flammable
Reactivity Profile · 1 Eintrag

TERT-BUTYL METHACRYLATE is an acrylate ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.

Air and Water ReactionsHighly flammable. Insoluble in water.
Hazard Classes and Categories · 3 Einträge

Flam. Liq. 3 (68.6%)

Flammable liquids - Category 3

Flammable liquids - Category 3

Sicherheit und Schutzausrüstung

Fire FightingExcerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]:
First AidExcerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]:
Nonfire Spill ResponseExcerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]:
Isolation and EvacuationExcerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]:
Personal Protective Equipment (PPE)Excerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]:

Toxikologische Informationen

Toxicity Summary · 2 Einträge

Based on available data, the CIR Expert Panel concluded that ... t-Butyl Methacrylate is safe as used in nail enhancement products when skin contact is avoided. Products containing these ingredients should be accompanied with directions to avoid skin contact, because of the sensitizing potential of Methacrylates.

Safe for use in cosmetics, with qualifications

Sicherheitsdaten

wgk
3
safety_code
24/25
Speicherklasse
11 - Combustible Solids
杭州宇昊化工科技有限公司0571-82693216 · [email protected]
Sigma-Aldrich西格玛奥德里奇(上海)贸易有限公司021-61415566 800-8193336 · [email protected]
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD+8613676922317 · [email protected]
济南睿遥明志医疗科技有限公司15662630077 15662630077 · [email protected]
上海阿拉丁生化科技股份有限公司6206333 13167063860 · [email protected]
陕西缔都医药化工有限公司029-029-81120477 17792793610 · [email protected]
山东小野化学股份有限公司0539-6362799 20)
深圳市丽晶生化科技有限公司0755-85201366 18938635012 · [email protected]
career henan chemical co+86-0371-86658258 · [email protected]
上海贝万塔生物科技有限公司021-67187366 19901745723 · [email protected]
上海万纳巨合高分子技术有限公司13661897211 · [email protected]
河南科弘生物科技有限公司0371-55969461 18638736641 · [email protected]
上海甄准生物科技有限公司18019219489 18901678489 · [email protected]
湖北省汉卿生物医药科技有限公司15827479330 · [email protected]