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2-Propensäure-2-methoxyethylester

2-Methoxyethyl acrylate

HCID 18392
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Grundinformationen

CAS
3121-61-7
Standard-SMILES
C=CC(=O)OCCOC
InChIKey
HFCUBKYHMMPGBY-UHFFFAOYSA-N
Summenformel
C6H10O3
Durchschnittliche Molmasse
130,14 g/mol
Monoisotopische Masse
130,06299418

Überblick

2-methoxyethyl acrylate is a clear colorless liquid with a sharp musty odor. (NTP, 1992)

Namen und Bezeichner

Bevorzugter Name
2-Methoxyethyl acrylate
IUPAC
2-methoxyethyl prop-2-enoate
Lokaler Name
2-Propensäure-2-methoxyethylester
Englischer Name
2-Methoxyethyl acrylate
Summenformel
C6H10O3
Molmasse
130.14

Namen und Synonyme

2-METHOXYETHYL ACRYLATE3121-61-7Methoxyethyl acrylate2-Propenoic acid, 2-methoxyethyl esterEthylene glycol methyl ether acrylateMethyl cellosolve acrylateEthylene glycol monomethyl ether acrylate2-Methoxyethanol, acrylateSipomer MCAAcrylic acid, 2-methoxyethyl esterGlycol monomethyl ether acrylateAcrylic acid, 2-methoxyethoxy ester
Weitere Namen anzeigen
2-MTAsipomermcaSipomer MTA2-Methoxyethylacrylat2-Mehtoxyethyl Acryate2-methoxy-ethanoacrylatemethylcellosolveacrylate
Ethanol, 2-methoxy-, acrylate2-Propenioc acid, 2-methoxyethyl esterNSC 24153Ageflex MEAEINECS 221-499-3BRN 1754333AI3-15726NSC-24153

Datenbank-Bezeichner

CAS
3121-61-7

Eigenschaften

Berechnete StruktureigenschaftenWird ergänzt

XLogP
0,3
Polarare Oberfläche (TPSA)
35,5 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
3
Frei drehbare Bindungen
5
Schwere Atome
9
Formalladung
0
Komplexität
98,5

Experimentelle und physikochemische Eigenschaften

Chemical ClassesFlammable agents - 2nd degree
Density1.0131 at 68 °F (NTP, 1992) - Denser than water; will sink
Solubilitygreater than or equal to 100 mg/mL at 64 °F (NTP, 1992)
Flash Point180 °F (NTP, 1992)
Boiling Point312.8 °F at 760 mmHg (NTP, 1992)
Melting Point-48.3 °F (NTP, 1992)
Vapor Density4.49 (NTP, 1992) - Heavier than air; will sink (Relative to Air)
Physical Description · 2 Einträge

2-methoxyethyl acrylate is a clear colorless liquid with a sharp musty odor. (NTP, 1992)

Liquid

Physikochemische Eigenschaften

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

GHS-Klassifizierung

GHS Classification · 6 Einträge

Danger

H226: Flammable liquid and vapor [Warning Flammable liquids]

P203, P210, P233, P240, P241, P242, P243, P260, P261, P264, P264+P265, P270, P271, P272, P280, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P317, P318, P321, P330, P333+P317, P362+P364, P363, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Danger

H226 (89.4%): Flammable liquid and vapor [Warning Flammable liquids]

P203, P210, P233, P240, P241, P242, P243, P260, P261, P262, P264, P264+P265, P270, P271, P272, P273, P280, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P303+P361+P353, P304+P340, P305+P351+P338, P305+P354+P338, P316, P317, P318, P319, P321, P330, P332+P317, P333+P317, P337+P317, P361+P364, P362+P364, P363, P370+P378, P391, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Gefahrenhinweise

Regulatory Information · 6 Einträge

Chemical: 2-Propenoic acid, 2-methoxyethyl ester

Hazard Traits - Reproductive Toxicity

2-Propenoic acid, 2-methoxyethyl ester is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 2-Propenoic acid, 2-methoxyethyl ester are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 05-04-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/13492

(2-Methoxyethyl) acrylate: Does not have an individual approval but may be used under an appropriate group standard

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

Other Safety InformationEvaluation - 2-Propenoic acid, 2-methoxyethyl ester ((2-methoxyethyl acrylate)

Chemie und Industrie

Verwendung und Herstellung

U.S. Production2023: 660,242 lb
Consumer UsesNot Known or Reasonably Ascertainable
Industry UsesMonomers
General Manufacturing Information · 2 Einträge

Rubber Product Manufacturing

2-Propenoic acid, 2-methoxyethyl ester: ACTIVE

Anwendungen · 2 Einträge

Beschreibung2-Methoxyethyl Acrylate (MTA) is a specialty monomer for synthesizing specific polymers in the coatings, paint, adhesive, and plastic market segments. Polymers containing MTA have improved bendability, flexibility at lower temperatures, UV resistance, water resistance, and adhesion. It improves oil resistance due to its polarity when used as an additive.

Verwenden2-Methoxyethyl acrylate can undergo RAFT copolymerization with itaconic anhydride.

Zugehörige Reaktionen

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Reaktionsgleichung von HRID 389788
HRID 389788als Eduktuspto-grants-2013_02
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Reaktionsgleichung von HRID 1914434
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Reaktionsgleichung von HRID 2051462
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Reaktionsgleichung von HRID 2206658
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Reaktionsgleichung von HRID 2389203
HRID 2389203als Eduktuspto-grants-2012_09

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PubChem CID
18392
DTXSID
DTXSID7025554
UNII
515K4I683Y
EC Number
221-499-3
Nikkaji
J55.297F
Schmelzpunkt
-30 °C · -30°C
Siedepunkt
56 °C12 · 56 °C12 mm Hg(lit.)
Dichte
1.012 g/mL · 1.012 g/mL at 25 °C(lit.)
Dampfdruck
2.81 hPa · 2.81hPa at 25℃
Brechungsindex
20 · n20/D 1.427(lit.)
Flammpunkt
140 °F · 140 °F
storage temp.
2 · 2-8°C(protect from light)
Löslichkeit
Soluble in water
Aggregatzustand
Liquid
Farbe
Clear colorless to slightly yellow
Wasserlöslichkeit
144 g/L · 144g/L at 20℃
BRN
1754333 · 1754333
Kosmetik-Inhaltsstoffe Funktionen
FILM FORMING
InChI
1S/C6H10O3/c1-3-6(7)9-5-4-8-2/h3H,1,4-5H2,2H3
InChIKey
HFCUBKYHMMPGBY-UHFFFAOYSA-N
SMILES
COCCOC(=O)C=C
LogP
0.9 at · 0.9 at 25℃
CAS Datenbank
3121 · 3121-61-7(CAS DataBase Reference)
EPA chemische Informationen
Ethylene glycol monomethyl ether acrylate (3121-61-7)
DOT LabelPoison
Fire HazardsThis chemical is combustible. (NTP, 1992)
Health HazardsSYMPTOMS: The vapors of this chemical may be irritating to the mucous membranes. Dermatitis may develop in susceptible individuals. It may cause skin irritation.
Reactive GroupEthers
Reactivity AlertsPolymerizable
Reactivity Profile2-METHOXYETHYL ACRYLATE is sensitive to heat and light. Incompatible with strong oxidizing agents and polymerization initiators (NTP, 1992).
Air and Water ReactionsWater soluble.
Hazard Classes and Categories · 6 Einträge

Flam. Liq. 3 (89.4%)

Flammable liquid - category 3

Flammable liquids - Category 4

Acute toxicity (Oral) - Category 4

Skin corrosion/irritation - Category 1

Flammable agents - 2nd degree, Reactive agents - 2nd degree

Sicherheit und Schutzausrüstung

Fire FightingFires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. A water spray may also be used. (NTP, 1992)
First Aid · 1 Eintrag

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Nonfire Spill Response · 1 Eintrag

SMALL SPILLS AND LEAKAGE: If you should spill this chemical, use absorbent paper to pick up all liquid spill material. Seal the absorbent paper, as well as any of your clothing which may be contaminated, in a vapor-tight plastic bag for eventual disposal. Wash any surfaces you may have contaminated with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Isolation and EvacuationExcerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]:
Personal Protective Equipment (PPE)MINIMUM PROTECTIVE CLOTHING: If Tyvek-type disposable protective clothing is not worn during handling of this chemical, wear disposable Tyvek-type sleeves taped to your gloves.

Sicherheitsdaten

wgk
1
tsca
TSCA listed
ridadr
UN 1992 3/PG 3
hs_code
29161290
RTECS-Nr.
KL6000000
risk_code
20/22-24-41-61-60-48/22-43-34
hazard_code
T,C
safety_code
16-26-36/37/39-45-53-27/28-23
hazard_class
6.1
packing_group
II
Speicherklasse
3 - Flammable liquids
Hazard Classifications
Acute Tox. 3 DermalAcute Tox. 3 InhalationAcute Tox. 4 OralAquatic Chronic 3Eye Dam. 1Flam. Liq. 3Muta. 2Repr. 1BSkin Corr. 1CSkin Sens. 1STOT RE 2