Naphthylen-1,5-diisocyanat

1,5-Naphthalene diisocyanate

HCID 18503CAS 25551-28-4
TeilstruktursucheÄhnliche Strukturen suchen

Grundinformationen

Standard-SMILES
O=C=Nc1cccc2c(N=C=O)cccc12
InChIKey
SBJCUZQNHOLYMD-UHFFFAOYSA-N
Summenformel
C12H6N2O2
Durchschnittliche Molmasse
210,19 g/mol
Monoisotopische Masse
210,04292743

Überblick

1,5-naphthalene diisocyanate is a white to light-yellow crystalline flakes. (NIOSH, 2024)

Namen und Bezeichner

Bevorzugter Name
1,5-Naphthalene diisocyanate
IUPAC
1,5-diisocyanatonaphthalene
Lokaler Name
Naphthylen-1,5-diisocyanat
Englischer Name
1,5-Naphthalene diisocyanate
Summenformel
C12H6N2O2
Molmasse
210.19

Namen und Synonyme

3173-72-61,5-Naphthalene diisocyanate1,5-Naphthylene diisocyanateNaphthalene, 1,5-diisocyanato-1,5-Naphthyl diisocyanate1,5-Naphthylene di-isocyanate0ORB22ST7MDTXSID8040145NSC-240728RefChem:73516DTXCID6020145221-641-4
Weitere Namen anzeigen
ndi1,5-naphthaleneNaphthylene-1,5-diisocyanate1,5-NDI40KGS/DRUMdesmodur151,5-Naphthalene diisNAPHTHYLENEDIISOCYANATE
Naphthalene diisocyanate1,5-Diisocyanatonaphthalene1,5-naphthalenediisocyanateISOCYANIC ACID, 1,5-NAPHTHYLENE ESTERMFCD00039588CCRIS 8920EINECS 221-641-4UNII-0ORB22ST7M

Datenbank-Bezeichner

CAS
25551-28-4、3173-72-6
PubChem CID
18503
DTXSID
DTXSID8040145
ChEBI
CHEBI:82496
UNII
0ORB22ST7M
EC Number
221-641-4
Nikkaji
J41.091H

Eigenschaften

Berechnete Struktureigenschaften

XLogP
4,8
Polarare Oberfläche (TPSA)
58,9 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
4
Frei drehbare Bindungen
2
Schwere Atome
16

Experimentelle und physikochemische Eigenschaften

PolymersPlastics & Rubber -> Diisocyanates
DensityRelative density (water = 1): 1.42
Flash Point · 4 Einträge

311 °F (NIOSH, 2024)

192 °C c.c.

311 °F

(oc) 311 °F

Boiling Point · 4 Einträge

505 °F at 760 mmHg (NIOSH, 2024)

at 0.7kPa: 167 °C

505 °F

505 °F

Melting Point · 4 Einträge

261 °F (NIOSH, 2024)

130 °C

261 °F

261 °F

Vapor Pressure · 5 Einträge

0.003 mmHg at 75 °F (NIOSH, 2024)

0.003 [mmHg]

Vapor pressure, Pa at 20 °C:

0.003 mmHg

(75 °F): 0.003 mmHg

Physikochemische Eigenschaften

Schmelzpunkt
130 °C · 130°C
Siedepunkt
244 °C · 244°C (100 torr)
Dichte
1.45 · 1.45
Dampfdruck
0.001 Pa · 0.001Pa at 25℃
Brechungsindex
1.6 · 1.6000 (estimate)
storage temp.
2 · Inert atmosphere,2-8°C

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 6 Einträge

Danger

H315: Causes skin irritation [Warning Skin corrosion/irritation]

P233, P260, P261, P264, P264+P265, P271, P272, P273, P280, P284, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P333+P317, P337+P317, P342+P316, P362+P364, P403, P403+P233, P405, and P501 (click each P-code to see the statement)

Danger

H315: Causes skin irritation [Warning Skin corrosion/irritation]

P233, P260, P261, P264, P264+P265, P271, P272, P273, P280, P284, P302+P352, P304+P340, P305+P351+P338, P316, P319, P320, P321, P332+P317, P333+P317, P337+P317, P342+P316, P362+P364, P403, P403+P233, P405, and P501 (click each P-code to see the statement)

Gefahrenhinweise

Regulatory Information · 6 Einträge

Chemical: Naphthalene, 1,5-diisocyanato-

Hazard Traits - Respiratory Toxicity

Naphthalene, 1,5-diisocyanato- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Naphthalene, 1,5-diisocyanato- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 06-08-2019 https://echa.europa.eu/registration-dossier/-/registered-dossier/10913

Restricted substance: 1,5-naphthylene diisocyanate

1,5-Naphthylene diisocyanate: Does not have an individual approval but may be used under an appropriate group standard

DOT LabelPoison
Fire Hazards · 2 Einträge

Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:

Combustible. Gives off irritating or toxic fumes (or gases) in a fire.

Health HazardsExcerpt from NIOSH Pocket Guide for Naphthalene diisocyanate:
Hazards SummaryMay cause skin sensitization; [ICSC] Biological monitoring of exposure to 1,5-naphthalene diisocyanate and 4,4'-methylenediphenyl diisocyanate. [PMID 16506043] See DIISOCYANATES.
Reactive GroupIsocyanates and Isothiocyanates

Sicherheit und Schutzausrüstung

Fire Fighting · 2 Einträge

Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:

Use foam, powder, carbon dioxide. NO water.

First Aid Measures · 4 Einträge

Fresh air, rest. Refer for medical attention.

Remove contaminated clothes. Rinse skin with plenty of water or shower.

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Rinse mouth. Give one or two glasses of water to drink. Rest. Refer for medical attention .

First Aid · 2 Einträge

Excerpt from NIOSH Pocket Guide for Naphthalene diisocyanate:

(General first aid procedures)

Safe StorageSee Chemical Dangers. Well closed.
Nonfire Spill ResponseExcerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:
Spillage Disposal · 1 Eintrag

Sweep spilled substance into covered sealable containers. Carefully collect remainder. Then store and dispose of according to local regulations. Do NOT let this chemical enter the environment. Personal protection: particulate filter respirator adapted to the airborne concentration of the substance.

Toxikologische Informationen

Target OrgansEyes, respiratory system
Adverse EffectsSkin Sensitizer - An agent that can induce an allergic reaction in the skin.
Exposure Routes · 2 Einträge

The substance can be absorbed into the body by inhalation of its aerosol and by ingestion.

inhalation, ingestion, skin and/or eye contact

Signs and Symptoms · 5 Einträge

Cough. Laboured breathing. Sore throat.

Redness. Pain.

Redness. Pain.

Abdominal pain. Sore throat.

irritation eyes, nose, throat; resp sensitization, cough, pulmonary secretions, chest pain, dyspnea (breathing difficulty); asthma

ICSC Environmental DataThe substance is harmful to aquatic organisms.
Carcinogen Classification · 5 Einträge

1,5-Naphthalene diisocyanate

Group 3: Not classifiable as to its carcinogenicity to humans

Volume 19: (1979) Some Monomers, Plastics and Synthetic Elastomers, and Acrolein

1999

1998

Sicherheitsdaten

OEB
D
OEL
TWA: 0.040 mg/m3 (0.005 ppm), Ceiling: 0.170 mg/m3 (0.020 ppm) [10-minute]
tsca
TSCA listed
ridadr
2206
hs_code
29291090
RTECS-Nr.
NQ9600000

Chemie und Industrie

Verwendung und Herstellung

Uses · 2 Einträge

Occupational asthma reported in rubber manufacturing; [Malo]

Painting (Pigments, Binders, and Biocides) [Category: Paint]

U.S. Production2023: 1,000,000 - <5,000,000 lb
Industry UsesMonomers
General Manufacturing Information · 2 Einträge

Paint and Coating Manufacturing

Naphthalene, 1,5-diisocyanato-: ACTIVE

Anwendungen · 2 Einträge

BeschreibungNaphthalene diisocyanate (NDI) occurs as white to lightyellow crystalline flakes with a characteristic odor. NDI is incompatible with many classes of compounds, reacting exothermically to release toxic gases. Reactions with amines, aldehydes, alcohols, alkali metals, ketones, mercaptans, strong oxidizers, hydrides, phenols, and peroxides can cause vigorous releases of heat. Acids and bases initiate polymerization reactions. NDI can react with water to form amines and liberate carbon dioxide.

VerwendenManufacture of polyurethane solid elastomers.

Darstellung

synthetischeNaphthylene 1,5-diisocyanate (NDI) is prepared from naphthalene as follows:

Vor- und nachgelagerte Produkte

Anbieter50 Anbieter

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
Shandong chuangyingchemical Co., Ltd.18853181302 · [email protected]
上海比阳实业有限公司+86-21-52699951; +8613917686115 · [email protected]
河北创海生物科技有限公司+86-86-13131129325 · [email protected]

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