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Dichlor(phenyl)phosphinsulfid
PHENYLPHOSPHONOTHIOIC DICHLORIDE · AURORA KA-1408 · Thiodichlorophenylphosphine · phenylphosphorusthiodichloride · phenylthiophosphonyldichloride · Phenyldichlorophosphine sulfide · phenylphosphonothioyldichloride · phenyl-phosphonothioicdichlorid
Identifikatoren & physikalische Daten
| CAS No. | 3497-00-5 |
|---|---|
| Summenformel | C6H5Cl2PS |
| Durchschnittliche Molmasse | 211,05 g/mol |
| Monoisotopische Masse | 209,92266315 g/mol |
| SMILES | S=P(Cl)(Cl)c1ccccc1 |
| InChIKey | SXIWNIQDOJKDGB-UHFFFAOYSA-N |
| PubChem CID | 19016 |
| EC No. | 222-494-9 |
| DTXSID | DTXSID2063054 |
| Lokaler Name | Dichlor(phenyl)phosphinsulfid |
Chemische & physikalische Eigenschaften
| XLogP | 4,2 |
|---|---|
| Polarare Oberfläche (TPSA) | 32,1 |
| H-Brücken-Donoren | 0 |
| H-Brücken-Akzeptoren | 1 |
| Frei drehbare Bindungen | 1 |
| Schwere Atome | 10 |
| Formalladung | 0 |
| Komplexität | 148 |
| Stoffklassen | Toxic Gases & Vapors -> Other Toxic Gases & VaporsCorrosives |
| SpringerMaterials Properties | 31P nuclear magnetic resonance spectrum |
| Physical Description | Phenylphosphorus thiodichloride is a colorless liquid with unpleasant acrid pungent odor. Corrodes metals slowly.Colorless liquid with an unpleasant pungent odor[CAMEO] Light yellow liquid[MSDSonline] |
| Schmelzpunkt | 76-77 °C |
| Siedepunkt | 270 °C |
| Dichte | 1,4 g/cm3 |
| Brechungsindex | 1.6178-1.6182 |
| Flammpunkt | 118℃ |
| Aggregatzustand | clear liquid |
| Farbe | Colorless to Light orange to Yellow |
| Löslichkeit | 1.522g/L(23 ºC) |
| InChI | 1S/C6H5Cl2PS/c7-9(8,10)6-4-2-1-3-5-6/h1-5H |
| InChIKey | SXIWNIQDOJKDGB-UHFFFAOYSA-N |
| SMILES | ClP(Cl)(=S)c1ccccc1 |
| CAS Datenbank | 3497-00-5(CAS DataBase Reference) |
| EPA chemische Informationen | Phosphonothioic dichloride, P-phenyl- (3497-00-5) |
Sicherheit & Vorschriften
| GHS-Einstufung | DangerH290 (100%): May be corrosive to metals [Warning Corrosive to Metals]P234, P260, P261, P264, P270, P271, P280, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P330, P362+P364, P363, P390, P405, P406, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 40 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies. |
|---|---|
| Regulatorische Informationen | The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.) |
| DOT-Kennzeichnung | Corrosive |
| Brandgefahren | Excerpt from ERG Guide 137 [Substances - Water-Reactive - Corrosive]:· EXCEPT FOR ACETIC ANHYDRIDE (UN1715), THAT IS FLAMMABLE, some of these materials may burn, but none ignite readily. |
| Gesundheitsgefahren | Excerpt from ERG Guide 137 [Substances - Water-Reactive - Corrosive]:· CORROSIVE and/or TOXICinhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. |
| Gefahrenübersicht | Reacts slowly with water producing hydrogen chlorideCorrosive[CAMEO] Reacts with moisture evolving hydrogen sulfide and hydrogen chlorideA corrosive substance that can cause injury to the skin, eyes, and respiratory tractInhalation may cause chemical pneumonitis and pulmonary edema[MSDSonline] |
| DOT-Nummer und Handbuch | 2799 137 |
| Reaktive Gruppe | Sulfonates, Phosphonates, and Thiophosphonates, Organic |
| Special Reports | WHODiseases Caused by Phosphorus and Its Toxic CompoundsEarly Detection of Occupational Diseases pg 53-62 (1986). Review of diseases and health related effects resulting from exposure to phosphorus or phosphorus cmpd. |
Anwendungen & Verwendung
Verwenden
Phenylthiophosphonic dichloride is a thiophosphonate and has been used to prepare high-refractive-index materials.