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Chlorsure

Chloric acid

HCID 19654
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Grundinformationen

CAS
7790-93-4
Standard-SMILES
[O-][Cl+2]([O-])O
InChIKey
LSUVGSGHYCLVPU-UHFFFAOYSA-N
Summenformel
ClHO3
Durchschnittliche Molmasse
84,46 g/mol
Monoisotopische Masse
83,96142157

Überblick

Chloric acid is a colorless liquid. It will accelerate the burning of combustible materials and can ignite most on contact. It is corrosive to metals and tissue. It is used as a reagent in chemical analysis and to make other chemicals.

Namen und Bezeichner

Bevorzugter Name
Chloric acid
IUPAC
chloric acid
Lokaler Name
Chlorsure
Englischer Name
CHLORIC ACID
Summenformel
ClHO3
Molmasse
84.46

Namen und Synonyme

CHLORIC ACID7790-93-4Z0V9L75H3KDTXSID1047449CHEBI:17322RefChem:5667DTXCID9027449CLO2--Portable sterilization card232-233-0ChlorsaeureChloric(V) acidUNII-Z0V9L75H3K
Weitere Namen anzeigen
Chloride AcidC01485NA-9191chloricNA 2626Hypure CchloricacidChloric acid solutionCHLORIC ACID, 35 WT. % SOLUTIONCHLORIC ACID ISO 9001:2015 REACH
hydrogenchloric acidEINECS 232-233-0UN2626hydrogen chloric acidHClO3hydroxidodioxidochlorineCHLORIC ACID [MI]SCHEMBL18802

Datenbank-Bezeichner

CAS
7790-93-4
PubChem CID
19654
DTXSID
DTXSID1047449
ChEMBL
CHEMBL1161633
ChEBI
CHEBI:17322

Eigenschaften

Berechnete StruktureigenschaftenWird ergänzt

XLogP
2,1
Polarare Oberfläche (TPSA)
54,4 Ų
H-Brücken-Donoren
1
H-Brücken-Akzeptoren
3
Frei drehbare Bindungen
0
Schwere Atome
4
Formalladung
0
Komplexität
46,2

Experimentelle und physikochemische Eigenschaften

Chemical Classes · 2 Einträge

Toxic Gases & Vapors -> Acids, Inorganic

Reactive agents - 4th degree

Physical Description · 2 Einträge

Chloric acid is a colorless liquid. It will accelerate the burning of combustible materials and can ignite most on contact. It is corrosive to metals and tissue. It is used as a reagent in chemical analysis and to make other chemicals.

Found only in aqueous solution; [Merck Index] Clear colorless liquid; [MSDSonline]

Physikochemische Eigenschaften

Schmelzpunkt
-20 ℃ · <-20℃ [CRC10]
Siedepunkt
100 °C · >100 °C
Dichte
1.2 g/mL · 1.2 g/mL at 25 °C
Löslichkeit
2 O · very soluble in H2O
Farbe
exists only in aqueous solution
Wasserlöslichkeit
2 O · very soluble H2O [CRC10]
Merck
13 · 13,2109

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

GHS-Klassifizierung

GHS Classification · 6 Einträge

Danger

H271 (100%): May cause fire or explosion; strong Oxidizer [Danger Oxidizing liquids; Oxidizing solids]

P210, P220, P260, P264, P280, P283, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P306+P360, P316, P321, P363, P370+P378, P371+P380+P375, P405, P420, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 39 reports by companies from 1 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

H271: May cause fire or explosion; strong Oxidizer [Danger Oxidizing liquids; Oxidizing solids]

Gefahrenhinweise

Regulatory Information · 2 Einträge

Chloric acid: Does not have an individual approval but may be used under an appropriate group standard

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

DOT LabelOxidizer
Fire Hazards · 2 Einträge

Excerpt from ERG Guide 140 [Oxidizers]:

CAUTION: Ammonium nitrate products may explode if involved in fire or contaminated with hydrocarbons (fuels), organic matter, other contaminants or when hot molten and contained. Treat as an explosive (GUIDE 112).

Health Hazards · 2 Einträge

Excerpt from ERG Guide 140 [Oxidizers]:

· Inhalation, ingestion or contact (skin, eyes) with vapors or substance may cause severe injury, burns or death.

Hazards Summary · 1 Eintrag

A strong skin and mucous membrane irritant; [Merck Index] Corrosive to tissue; [CAMEO] An eye irritant; [eChemPortal: ERMA] A corrosive substance that can cause injury to the skin, eyes, and respiratory tract; Inhalation may cause chemical pneumonitis and pulmonary edema; [MSDSonline]

Chemie und Industrie

Verwendung und Herstellung

UsesUsed as an oxidizing agent and as a catalyst in acrylonitrile polymerization; [Merck Index] Used in chemical analysis and to make other chemicals; [CAMEO]
General Manufacturing InformationChloric acid: ACTIVE
Anwendungen · 2 Einträge

BeschreibungChloric acid, HClO3, is an oxoacid of chloride, and the formal precursor of chlorate salts. It is a strong acid (pKa=-1) and a strong oxidizing agent. It is stable in cold aqueous solution up to a concentration of approximately 30%, and solution of up to 40% can be prepared by careful evaporation under reduced pressure. Above these concentrations, and on warming, chloric acid solutions decompose to give a variety of products, for example: 8HClO3→4HClO4+2H2O+2Cl2+3O2 Note that it disproportionates into perchloric acid in which the chlorine atom has a+7 oxidation state and also the zero oxidation state of chlorine gas (an oxidation–reduction reaction). Thus, under the proper conditions, it can also be used to make perchloric acid. 3HClO3→HClO4+H2O+2ClO2

VerwendenOxidizing agent; with H2SO3 as catalyst in acrylonitrile polymerization.

Vor- und nachgelagerte Produkte

Nachgelagerte Produkte

Moclobemidesodium oleyl sarcosinateCyclopropylaminNatriumiodatKristallviolett (C.I. 42555)NatriumbutylnaphthalinsulfonatHydrazine hydrate

Zugehörige Reaktionen

15
Reaktionsaufzeichnung erstellen
Reaktionsgleichung von HRID 5280
HRID 5280als Eduktuspto-grants-1993_09
Reaktionsgleichung von HRID 5283
HRID 5283als Eduktuspto-grants-1993_09
Reaktionsgleichung von HRID 61321
HRID 61321als Eduktuspto-grants-2016_09
Reaktionsgleichung von HRID 93419
HRID 93419als EduktTraining data from https://doi.org/10.1039/C8SC04228D (2/10)
Reaktionsgleichung von HRID 291636
HRID 291636als EduktTraining data from https://doi.org/10.1039/C8SC04228D (8/10)
Reaktionsgleichung von HRID 298530
HRID 298530als EduktTraining data from https://doi.org/10.1039/C8SC04228D (8/10)
Reaktionsgleichung von HRID 481927
HRID 481927als Produktuspto-grants-1998_08
Reaktionsgleichung von HRID 944683
HRID 944683als EduktValidation data from https://doi.org/10.1039/C8SC04228D
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Weitere Aktionen
Neue NotizNeue ReaktionAnfrage stellen
UNII
Z0V9L75H3K
EC Number
232-233-0
Nikkaji
J74.689D
CAS Datenbank
7790 · 7790-93-4
EPA chemische Informationen
Chloric acid (7790-93-4)
DOT ID and Guide2626 140
Reactive GroupAcids, Strong Oxidizing
Reactivity AlertsStrong Oxidizing Agent
Reactivity Profile · 1 Eintrag

Self-reactive. Concentrations of CHLORIC ACID above 40% decompose [Mellor 2 Supp. 1:576 1956]. Antimony sulfide and concentrated solutions of chloric acid react with incandescence [Mellor Supp. II Part I:584 1956]. Arsenic sulfide and concentrated solutions of chloric acid react with incandescence. Reacts with vigor even explodes with other metal sulfides, i.e. copper sulfide [Mellor Supp. II Part I:584 1956]. In contact with oxidizable materials, including ammonia, reactions can be extremely violent. Filter paper ignites after soaking in chloric acid, [Mellor, 1946, Vol. 2, 310]. Explosions have been recorded by mixtures of chloric acid solution with metals such as: antimony, bismuth, and iron. This is due to the formation of explosive compounds including hydrogen.

Air and Water ReactionsWater soluble.
Hazard Classes and Categories · 3 Einträge

Ox. Liq. 1 (100%)

Oxidizing liquids - Category 1-2

Reactive agents - 4th degree

Sicherheit und Schutzausrüstung

Fire FightingExcerpt from ERG Guide 140 [Oxidizers]:
Accidental Release Measures · 2 Einträge

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· Keep combustibles (wood, paper, oil, etc.) away from spilled material.

First Aid · 2 Einträge

Excerpt from ERG Guide 140 [Oxidizers]:

General First Aid:

Exposure Control and Personal Protection· Wear positive pressure self-contained breathing apparatus (SCBA).
Nonfire Spill ResponseExcerpt from ERG Guide 140 [Oxidizers]:
Isolation and Evacuation · 2 Einträge

Excerpt from ERG Guide 140 [Oxidizers]:

Immediate precautionary measure

Personal Protective Equipment (PPE)Excerpt from ERG Guide 140 [Oxidizers]:
Emergency Response Planning GuidelinesSmall Fire

Toxikologische Informationen

Adverse EffectsDermatotoxin - Skin burns.

Sicherheitsdaten

tsca
TSCA listed
ridadr
UN 2626
risk_code
8-34
hazard_code
O,C
safety_code
17-26-36/37/39-45
hazard_class
5.1
packing_group
II
Estron
Starch, oxidized
alkyl phenylsufonate
Natriumchlorat
1-Amino-4-hydroxy-2-phenoxyanthrachinon
CI 77492
Cobaltoxid
CHLORIDE STANDARD
2-AMINO-4-CHLORO-6-NITROBENZOIC ACID