4-Morpholincarbaldehyd

N-Formylmorpholine

HCID 20417CAS 4394-85-8
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Grundinformationen

Standard-SMILES
O=CN1CCOCC1
InChIKey
LCEDQNDDFOCWGG-UHFFFAOYSA-N
Summenformel
C5H9NO2
Durchschnittliche Molmasse
115,13 g/mol
Monoisotopische Masse
115,06332853

Überblick

structure in first source

Namen und Bezeichner

Bevorzugter Name
N-Formylmorpholine
IUPAC
morpholine-4-carbaldehyde
Lokaler Name
4-Morpholincarbaldehyd
Englischer Name
4-Formylmorpholine
Summenformel
C5H9NO2
Molmasse
115.13

Namen und Synonyme

4-Formylmorpholine4394-85-84-MorpholinecarboxaldehydeN-FORMYLMORPHOLINEMorpholine, 4-formyl-DTXSID7044427D1E63XO4RHNSC-14833DTXCID5024427RefChem:99981224-518-3morpholine-4-carbaldehyde
Weitere Namen anzeigen
FormmorpholimeN-FormylmorpholN-Formyl MorpholinTIMTEC-BB SBB0076704-Formylmorpholine>
N-FormylmorfolinMFCD000061704-MorpholinecarbaldehydeN-formyl morpholineN-Formylmorfolin [Czech]formyl morpholineUNII-D1E63XO4RHN-formyhnorpholine

Datenbank-Bezeichner

CAS
4394-85-8
PubChem CID
20417
DTXSID
DTXSID7044427
UNII
D1E63XO4RH
EC Number
224-518-3
Nikkaji
J149.689A

Eigenschaften

Berechnete Struktureigenschaften

XLogP
-0,6
Polarare Oberfläche (TPSA)
29,5 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
2
Frei drehbare Bindungen
0
Schwere Atome
8

Experimentelle und physikochemische Eigenschaften

Chemical ClassesNitrogen Compounds -> Morpholines
SpringerMaterials PropertiesBoiling point
Vapor Pressure0.32 [mmHg]
Physical Description · 2 Einträge

Liquid; CBI

Clear colorless liquid; mp = 20-23 deg C; [Sigma-Aldrich MSDS]

Physikochemische Eigenschaften

Schmelzpunkt
20 · 20-23 °C (lit.)
Siedepunkt
236 · 236-237 °C (lit.)
Dichte
1.145 g/mL · 1.145 g/mL at 25 °C (lit.)
Dampfdruck
0.03 hPa · 0.03 hPa (20 °C)
Brechungsindex
20 · n20/D 1.485(lit.)
Flammpunkt
230 °F · >230 °F

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 6 Einträge

Warning

H317 (74.1%): May cause an allergic skin reaction [Warning Sensitization, Skin]

P261, P264+P265, P271, P272, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P333+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 259 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Warning

H317: May cause an allergic skin reaction [Warning Sensitization, Skin]

Gefahrenhinweise

Regulatory Information · 5 Einträge

Chemical: 4-Morpholinecarboxaldehyde

4-Morpholinecarboxaldehyde is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 4-Morpholinecarboxaldehyde are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

PMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.

Status: Active Update: 29-03-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/11158

4-Morpholinecarboxaldehyde: Does not have an individual approval but may be used under an appropriate group standard

Hazards Summary · 1 Eintrag

A mild skin and eye irritant; Oral LD50 (rat) = 6.5 mL/kg; [RTECS] May cause skin sensitization; [ECHA REACH Registrations] Search for (4394-85-8[EC/RN Number]) AND (dermatitis OR allergic OR sensitizer OR sensitization): no results; [PubMed] An eye and mild skin irritant; [Sigma-Aldrich MSDS]

Hazard Classes and Categories · 2 Einträge

Skin Sens. 1 (74.1%)

Skin sensitization - Category 1B

Sicherheitsdaten

wgk
3
tsca
TSCA listed
hs_code
29349990
RTECS-Nr.
QD9694000
risk_code
36/37/38
Toxizität
LD50 orally in Rabbit: > 7360 mg/kg LD50 dermal Rabbit > 18400 mg/kg

Chemie und Industrie

Verwendung und Herstellung

Uses · 2 Einträge

Used as an intermediate, laboratory reagent, in gas treatment, cleaning agents, and professional and consumer coatings; [ECHA REACH Registrations]

Painting (Pigments, Binders, and Biocides) [Category: Paint]

U.S. Production2023: 75,000 - <500,000 lb
Consumer UsesViscosity modifiers
Industry UsesIntermediate
General Manufacturing Information · 2 Einträge

Computer and Electronic Product Manufacturing

4-Morpholinecarboxaldehyde: ACTIVE

Anwendungen · 2 Einträge

Beschreibung4-Formylmorpholine is an excellent non-protonic solvent. It is widely used as a solvent and extractant for aromatics. It is used as a detergent for acid gases. In the field of organic synthesis, it can be used to prepare labelled 14C, 4-(trifluoromethyl)morpholine, 3-alkyl-2-chloro-5,6-dihydrobenzaldehyde, triple-biphenyldialdehyde and phenylpropargyl aldehyde. It plays an important role in the desulphurisation of natural gas, syngas, flue gas and petrol.

Verwenden4-Formylmorpholine is widely used as a solvent and extracting agent for aromatics. It is used as a scrubbing agent for acidic gases. It is employed in the preparation of adenine hydrochloride labeled with 14C, 4-(trifluoromethyl)morpholine, 3-alkyl-2-chloro-5,6-dihydrobenzaldehyde and terphenyl dialdehyde. It plays an important role in the desulfurization of natural gas, synthetic gas, flue gas and gasoline.

Vor- und nachgelagerte Produkte

Anbieter50 Anbieter

国药集团化学试剂有限公司86-21-63210123 · [email protected]
梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
山东前元高分子材料有限公司18678041314 18765609661 · [email protected]
韶远科技（上海）有限公司021-50795510 4000665055 · [email protected]

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