Grundinformationen
- CAS
4499-86-9- Standard-SMILES
CCC[N+](CCC)(CCC)CCC.[OH-]- InChIKey
LPSKDVINWQNWFE-UHFFFAOYSA-M- Summenformel
- C12H29NO
- Durchschnittliche Molmasse
- 203,36 g/mol
- Monoisotopische Masse
- 203,22491455
Namen und Bezeichner
- Bevorzugter Name
- Tetrapropylammonium hydroxide
- IUPAC
- tetrapropylazanium hydroxide
- Lokaler Name
- Tetrapropylammoniumhydroxid
- Englischer Name
- Tetrapropylammonium hydroxide
- Summenformel
- C12H29NO
- Molmasse
- 203.37
Namen und Synonyme
Tetrapropylammonium hydroxideTPAOHTetra-n-propylammonium hydroxideTetrapropylammonium oxideFluka 881101-Propanaminium, N,N,N-tripropyl-, hydroxideAMMONIUM, TETRAPROPYL-, HYDROXIDEUNII-T686LUY7NKEINECS 224-800-6T686LUY7NKN,N,N-Tripropyl-1-propanaminium hydroxideAI3-24161
Weitere Namen anzeigen
tpahtetrapropylammonium hydroxide solutionTPA-1OHSKL1630fluka88110N3,3,3,3OHIPC-TPA-OHTetrapropyLtetrapropylammoniumoxide
1-Propanaminium, N,N,N-tripropyl-, hydroxide (1:1)DTXSID7052107EC 224-800-6RefChem:188867Tetranpropylammonium hydroxideAmmonium, tetrapropyl, hydroxideDTXCID9030674N,N,NTripropyl1propanaminium hydroxide
Datenbank-Bezeichner
- CAS
4499-86-9- PubChem CID
- 20586
- DTXSID
DTXSID7052107- UNII
- T686LUY7NK
- EC Number
- 224-800-6
Eigenschaften
Berechnete Struktureigenschaften
- Polarare Oberfläche (TPSA)
- 1 Ų
- H-Brücken-Donoren
- 1
- H-Brücken-Akzeptoren
- 1
- Frei drehbare Bindungen
- 8
- Schwere Atome
- 14
- Formalladung
- 0
- Komplexität
- 80
Experimentelle und physikochemische Eigenschaften
Density1.012 @25 °C
Physical Description
Liquid
40% Aqueous solution: Yellow liquid with an odor like amines; [Alfa Aesar MSDS]
Physikochemische Eigenschaften
- Siedepunkt
- 100 · 100-102 °C
- Dichte
- 1 g/mL · 1.00 g/mL at 20 °C
- Brechungsindex
- 20 · n20/D 1.370
- Flammpunkt
- 102 °C · 102°C
- storage temp.
- 30 °C · Store below +30°C.
- Löslichkeit
- Miscible with strong electrolytes.
- Aggregatzustand
- Liquid
- Wichte
- 1.012 · 1.012
- Farbe
- Clear colorless
- PH
- 7 · >7 (H2O, 20°C) (undiluted)
- Wasserlöslichkeit
- Miscible in water
- BRN
- 4207983 · 4207983
- InChI
- 1S/C12H28N.H2O/c1-5-9-13(10-6-2,11-7-3)12-8-4;/h5-12H2,1-4H3;1H2/q+1;/p-1
- InChIKey
- LPSKDVINWQNWFE-UHFFFAOYSA-M
- SMILES
- [OH-].CCC[N+](CCC)(CCC)CCC
- CAS Datenbank
- 4499 · 4499-86-9(CAS DataBase Reference)
- EPA chemische Informationen
- 1 · 1-Propanaminium, N,N,N-tripropyl-, hydroxide (4499-86-9)
Sicherheit und Regulatorisches
Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.
GHS-Klassifizierung
GHS Classification
This chemical does not meet GHS hazard criteria for 17% (33 of 194) of reports.
Danger
H302 (53.6%): Harmful if swallowed [Warning Acute toxicity, oral]；H311 (53.6%): Toxic in contact with skin [Danger Acute toxicity, dermal]；H314 (83%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]；H318 (57.7%): Causes serious eye damage [Danger Serious eye damage/eye irritation]；H411 (54.1%): Toxic to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard]
P260, P262, P264, P264+P265, P270, P273, P280, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P330, P361+P364, P363, P391, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 194 reports by companies from 8 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Reported as not meeting GHS hazard criteria per 33 of 194 reports by companies.；There are 7 notifications provided by 161 of 194 reports by companies with hazard statement code(s).；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.
Gefahrenhinweise
Regulatory Information
1-Propanaminium, N,N,N-tripropyl-, hydroxide (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 1-Propanaminium, N,N,N-tripropyl-, hydroxide (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
Status: Active Update: 15-09-2020 https://echa.europa.eu/registration-dossier/-/registered-dossier/10485
1-Propanaminium, N,N,N-tripropyl-, hydroxide: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.
Hazards Summary40% Aqueous solution: Causes burns; Inhalation may cause corrosive injuries to upper respiratory tract; [Alfa Aesar MSDS]
Hazard Classes and CategoriesAcute Tox. 4 (53.6%)；Acute Tox. 3 (53.6%)；Skin Corr. 1A (83%)；Eye Dam. 1 (57.7%)；Aquatic Chronic 2 (54.1%)
Sicherheit und Schutzausrüstung
Protective Action Criteria (PAC)
1.2 [mg/m3]
13 [mg/m3]
79 [mg/m3]
Toxikologische Informationen
Adverse EffectsDermatotoxin - Skin burns.
Regulatorische Informationen
Regulatory Information
1-Propanaminium, N,N,N-tripropyl-, hydroxide (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 1-Propanaminium, N,N,N-tripropyl-, hydroxide (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
Status: Active Update: 15-09-2020 https://echa.europa.eu/registration-dossier/-/registered-dossier/10485
1-Propanaminium, N,N,N-tripropyl-, hydroxide: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.
Sicherheitsdaten
- F
- 4.4-10-34
- wgk
- 3
- tsca
- TSCA listed
- ridadr
- UN 3267 8/PG 3
- hs_code
- 2923 90 00
- RTECS-Nr.
- BS8400000
- risk_code
- 34
- hazard_code
- C
- safety_code
- 26-36/37/39-45
- hazard_class
- 8
- packing_group
- II
- Speicherklasse
- 8A - Combustible corrosive hazardous materials
- Hazard Classifications
- Skin Corr. 1B
Chemie und Industrie
Verwendung und Herstellung
U.S. Production2023: <75,000 lb；2022: 500,000 - <1,000,000 lb；2021: 500,000 - <1,000,000 lb；2020: 500,000 - <1,000,000 lb
Industry UsesIon exchange agent；Laboratory chemicals；Intermediate
General Manufacturing Information
All Other Basic Inorganic Chemical Manufacturing；All Other Basic Organic Chemical Manufacturing；Photographic Film, Paper, Plate, and Chemical Manufacturing；All Other Chemical Product and Preparation Manufacturing
1-Propanaminium, N,N,N-tripropyl-, hydroxide (1:1): ACTIVE
Anwendungen
VerwendenTetra-n-propylammonium hydroxide is used as an intermediate, ion exchange agent, surface-active agent and solvent. Further, it is used as an antistatic agent, detergent sanitizers, softener for textiles and paper products, emulsifying agents and pigment dispersers. It finds application as curing accelerators. In addition to this, it acts as a phase transfer catalyst in organic synthesis to enhance the reaction rate.
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