Titanium tetrabutoxide

0.998 at 77 °F (USCG, 1999) - Less dense than water; will float

0.998 @ 25 °C (liquid)

0.998 @25 °C

COLORLESS TO LIGHT-YELLOW LIQUID

Pale yellow, viscous liquid

Sol in most organic solvents except ketones

Sol in aliphatic aromatic, chlorinated, and oxygenated solvents

170 °F (USCG, 1999)

170 °F (CLOSED CUP)

593 °F at 760 mmHg (USCG, 1999)

312 °C

292.4 °C @760 [mm Hg]

-67 °F (USCG, 1999)

-55 °C

-55 °C

This chemical does not meet GHS hazard criteria for 6.5% (102 of 1561) of reports.

Danger

H226 (84.2%): Flammable liquid and vapor [Warning Flammable liquids]

P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P305+P354+P338, P317, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 1561 reports by companies from 46 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Warning

Chemical: 1-Butanol, titanium(4+) salt

1-Butanol, titanium(4+) salt (4:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 1-Butanol, titanium(4+) salt (4:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 27-04-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/14260

1-Butanol, titanium (IV) salt: Does not have an individual approval but may be used under an appropriate group standard

Decomposed by water producing butanol and titanium dioxide; A skin, eye, and respiratory tract irritant; May cause corneal damage; [HSDB] Reacts with water forming butanol and titanium dioxide; A skin and eye irritant; [CAMEO] A skin irritant; Corrosive to eyes; [eChemPortal: ERMA] A corrosive substance that can cause injury to the skin, eyes, and respiratory tract; Inhalation may cause chemical pneumonitis; [MSDSonline]

Organometallics are strongly reactive with many other groups. Incompatible with acids and bases. Organometallics are good reducing agents and therefore incompatible with oxidizing agents. Often reactive with water to generate toxic or flammable gases. Generally highly toxic. Often react on contact with tissues to give toxic products.

Flam. Liq. 3 (84.2%)

Flammable liquids - Category 4

IN GENERAL, MATERIALS ... TOXIC AS STORED OR WHICH CAN DECOMP INTO TOXIC COMPONENTS ... SHOULD BE STORED IN COOL ... VENTILATED PLACE, OUT OF ... SUN, AWAY FROM ... FIRE HAZARD ... BE PERIODICALLY INSPECTED & MONITORED. INCOMPATIBLE MATERIALS SHOULD BE ISOLATED ... .

SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

9.4 [mg/m3]

100 [mg/m3]

620 [mg/m3]

Excerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:

SELF-CONTAINED BREATHING APPARATUS OR ORGANIC CANISTER MASK; GOGGLES OR FACE SHIELD; RUBBER GLOVES.

INHALATION CAUSES NONSPECIFIC IRRITATION OF THE UPPER RESP TRACT. CONTACT WITH LIQUID MAY CAUSE CORNEAL DAMAGE IN EYES AND LOCAL IRRITATION OF SKIN. INGESTION CAUSES NONSPECIFIC IRRITATION OF GI TRACT, NAUSEA, VOMITING, CRAMPS, AND DIARRHEA; IN SEVERE CASES, CENTRAL NERVOUS SYSTEM DEPRESSION MAY RESULT.

LD50 Rat oral 3122 mg/kg

LD50 Mouse iv 180 mg/kg

Used in ester exchange reactions, heat-resistant paints, medical/dental bonding compositions, and anhydrous hair set compositions; Also used as an adhesion promoter (paints, rubber, and plastics-metal), curing agent (alkyl, epoxy, and silicon resins), catalyst, and glass coating; [HSDB]

Painting (Pigments, Binders, and Biocides) [Category: Paint]

Ester exchange reactions; heat-resistant paints (up to 500 °C); improving adhesion of paints, rubber, and plastics to metal surfaces; cross linking agent; condensation catalyst

Esterification/alcoholysis catalysts; alkyl/epoxy/silicon resin crosslinking agent; Ziegler catalyst component; high temperature coatings ingredient; glass surface treatment agent

Petrochemical Manufacturing

1-Butanol, titanium(4+) salt (4:1): ACTIVE

IN DENTAL OR MEDICAL BONDING COMPOSITIONS

IN ANHYDROUS HAIR SET COMPOSITION