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Lead diacetate trihydrate

HCID 22456
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Grundinformationen

CAS
6080-56-4
Standard-SMILES
CC(=O)[O-].CC(=O)[O-].O.O.O.[Pb+2]
InChIKey
MCEUZMYFCCOOQO-UHFFFAOYSA-L
Summenformel
Pb(C2H3O2)2.3H2O.
Durchschnittliche Molmasse
379 g/mol
Monoisotopische Masse
380,03495482

Überblick

Lead acetate trihydrate appears as white powder or white chunky solid. Slight odor. pH (5% aqueous solution at 77 °F) 5.5-6.5. (NTP, 1992)

Namen und Bezeichner

Bevorzugter Name
Lead diacetate trihydrate
IUPAC
lead(2+);diacetate;trihydrate
Englischer Name
Lead acetate trihydrate
Summenformel
C4H12O7Pb
Molmasse
379.33

Namen und Synonyme

6080-56-4Lead(II) acetate trihydrateLead diacetate trihydrateBleiazetatDTXSID3031521Acetic acid, lead(+2) salt trihydrateRefChem:1088392DTXCID501478104612-031-2CHEBI:33112LEAD ACETATE TRIHYDRATELead acetate [JAN]
Weitere Namen anzeigen
lead acetatLeaddiacetatetrihydrateLeadAcetatePureLeadAcetate3H2OAcsNormalleadacet-atePLATINIZING SOLUTIONLead(II) acetate triLead acetate hydrate
Plumbous Acetate TrihydrateLead acetate (II) trihydrateRX077P88RYLead acetate (JAN)Lead acetate paperLead acetate cottonlead(2+) diacetate trihydratelead diacetate-trihydrate

Datenbank-Bezeichner

CAS
6080-56-4
PubChem CID
22456
DTXSID
DTXSID3031521
UNII
RX077P88RY
EC Number

Eigenschaften

Berechnete StruktureigenschaftenWird ergänzt

Polarare Oberfläche (TPSA)
83,3 Ų
H-Brücken-Donoren
3
H-Brücken-Akzeptoren
7
Frei drehbare Bindungen
0
Schwere Atome
12
Formalladung
0
Komplexität
25,5

Experimentelle und physikochemische Eigenschaften

Chemical ClassesMetals -> Organic Acids, Metal Salts
Density · 2 Einträge

2.55 (NTP, 1992) - Denser than water; will sink

2.55 @25 °C

Solubilitygreater than or equal to 100 mg/mL at 68 °F (NTP, 1992)
Boiling Point392 °F at 760 mmHg (decomposes) (NTP, 1992)
Melting Point · 2 Einträge

167 °F (NTP, 1992)

Melting point equals 167 °F

Physical Description · 3 Einträge

Lead acetate trihydrate appears as white powder or white chunky solid. Slight odor. pH (5% aqueous solution at 77 °F) 5.5-6.5. (NTP, 1992)

Liquid

Water soluble white powder; [CAMEO]

Physikochemische Eigenschaften

Schmelzpunkt
75 °C · 75 °C (dec.)(lit.)
Siedepunkt
280 °C · 280°C
Dichte
2 · 2,55 g/cm3

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

GHS-Klassifizierung

GHS Classification · 6 Einträge

Danger

H302+H332 (43.1%): Harmful if swallowed or if inhaled [Warning Acute toxicity, oral; acute toxicity, inhalation]

P203, P260, P261, P264, P270, P271, P273, P280, P301+P317, P304+P340, P317, P318, P319, P330, P391, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 283 reports by companies from 12 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

H402: Harmful to aquatic life [Hazardous to the aquatic environment, acute hazard]

P273, and P501 (click each P-code to see the statement)

Gefahrenhinweise

Regulatory Information · 3 Einträge

Chemical: Acetic acid, lead(2+) salt, trihydrate

Acetic acid, lead(2+) salt, trihydrate is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Acetic acid, lead(2+) salt, trihydrate are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Lead (II) acetate, trihydrate: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationIMAP assessments - Lead acetates: Human health tier II assessment
DOT LabelPoison
Fire HazardsLiterature sources indicate that this chemical is nonflammable. (NTP, 1992)
Health Hazards · 1 Eintrag

SYMPTOMS: Symptoms of exposure to this compound include irritation of the skin, eyes and respiratory tract, nausea, vomiting, shock, weakness, headache, coma and death. Symptoms of mild exposure include lethargy, moroseness, constipation, flatulence and occasional abdominal pain. Advanced poisoning may cause loss of appetite, anemia and gradual paralysis of the muscles (especially in the arms). Other symptoms include metallic taste, muscle and joint pain or soreness, fine tremors, hyperactivity, colic and wrist drop. It may also cause a black or blue line on the gums, basophilic stippling on erythrocytes and, in pregnant women, tonic contractions of the uterus which may result in abortion. Exposure may cause convulsions, delirium, stupor, encephalopathy leading to blindness (due to injury to the optic nerves by pressure or direct toxic action), encrustations, opacities in previously injured corneas and optic atrophy.

Chemie und Industrie

Verwendung und Herstellung

Uses · 2 Einträge

Used as a cotton dye mordant, a water repellant, and as a raw material in cosmetics and to make other lead compounds; [Ullmann]

Textiles (Printing, Dyeing, or Finishing) [Category: Industry]

U.S. Production2023: 128,899 lb
Industry UsesAdsorbent
General Manufacturing InformationAll Other Basic Inorganic Chemical Manufacturing
Anwendungen · 1 Eintrag

VerwendenLead acetate trihydrate, the usual commercial form, is used in the preparation of basic lead carbonate and lead chromate, as a mordant in cotton dyes, as a reagent for the manufacture of lead salts of higher fatty acids, as a water repellant, as a component in combined toning and fixing baths for daylight printing papers, and as a means of treating awnings and outdoor furniture to prevent removal of mildew- and rotproofing agents by rain or laundering. Other uses include preparation of rubber antioxidants; processing agent in the cosmetic, perfume, and toiletry industries; component of coloring agents for adhesives; and preparation of organic lead soaps as driers of paints and inks.

Vor- und nachgelagerte Produkte

Vorgelagerte Rohstoffe

SchwefelwasserstoffBleisulfidBleimonoxidLUMOGALLIONEssigsureSOD EDTAComplexing agent

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Neue NotizNeue ReaktionAnfrage stellen
612-031-2
storage temp.
2 · 2-8°C
Löslichkeit
443 g/l · 443g/l
Aggregatzustand
Solid
Farbe
White or colorless, efflorescent
Wichte
2.55 · 2.55
PH
5.5 · 5.5-6.5 (50g/l, H2O, 20℃)
Wasserlöslichkeit
625 g/L · 625 g/L
Merck
14 · 14,5397
BRN
3730298 · 3730298
InChI
1S/2C2H4O2.3H2O.Pb/c2*1-2(3)4;;;;/h2*1H3,(H,3,4);3*1H2;/q;;;;;+2/p-2
InChIKey
DYRQFRHCGBQJII-UHFFFAOYSA-M
SMILES
O.O.O.CC(=O)O[PbH2]OC(C)=O
CAS Datenbank
6080 · 6080-56-4(CAS DataBase Reference)
EPA chemische Informationen
Lead(II) acetate trihydrate (6080-56-4)
Hazards SummarySee Lead and linked occupational diseases.
Reactive GroupSalts, Basic
Reactivity Profile · 1 Eintrag

LEAD ACETATE TRIHYDRATE may react with acids and oxidizing agents. Is incompatible with sulfates, citrates, tartrates, chlorides, carbonates, alkalis, tannin, resorcinol, salicylic acid, phenol, chloral hydrate, sulfites, vegetable infusions and tinctures. Incompatible with phosphates (NTP, 1992). Incompatible with KBrO3 and with EDTA.

Air and Water ReactionsSlowly effloresces in air. Water soluble but solutions absorb carbon dioxide from the air and to give incompletely soluble products.
Hazard Classes and Categories · 4 Einträge

Acute Tox. 4 (71.7%)

Acute toxicity - category 4

Acute toxicity (Oral) - Category 5

Hazardous to the aquatic environment (Acute) - Category 3

Sicherheit und Schutzausrüstung

Fire FightingFires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. A water spray may also be used. (NTP, 1992)
First Aid · 1 Eintrag

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Exposure Control and Personal ProtectionBiological Exposure Indices (BEI) [ACGIH] - Lead in blood = 200 ug/L (20 ug/100 ml); sampling time not critical; [ACGIH]
Nonfire Spill Response · 1 Eintrag

SMALL SPILLS AND LEAKAGE: If you spill this chemical, you should dampen the solid spill material with water, then transfer the dampened material to a suitable container. Use absorbent paper dampened with water to pick up any remaining material. Seal your contaminated clothing and the absorbent paper in a vapor-tight plastic bag for eventual disposal. Wash all contaminated surfaces with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Isolation and EvacuationExcerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Threshold Limit Values (TLV)0.05 [mg/m3], as Pb
Permissible Exposure Limit (PEL)0.05 [mg/m3], as Pb
Protective Action Criteria (PAC) · 3 Einträge

0.73 [mg/m3]

150 [mg/m3]

920 [mg/m3]

Personal Protective Equipment (PPE)MINIMUM PROTECTIVE CLOTHING: If Tyvek-type disposable protective clothing is not worn during handling of this chemical, wear disposable Tyvek-type sleeves taped to your gloves.

Toxikologische Informationen

Adverse EffectsNeurotoxin - Predominantly motor

Sicherheitsdaten

wgk
2
tsca
Yes
ridadr
UN 1616 6.1/PG 3
hs_code
29152900
RTECS-Nr.
OF8050000
risk_code
61-33-48/22-50/53-62
Toxizität
LD50 orally in Rabbit: 4665 mg/kg
hazard_code
T,N
safety_code
53-45-60-61
hazard_class
6.1
packing_group
III
Speicherklasse
6.1C - Combustible acute toxic Cat.3toxic compounds or compounds which causing chronic effects
Hazard Classifications
Aquatic Acute 1Aquatic Chronic 1Carc. 2Eye Dam. 1Lact.Repr. 1ASTOT RE 1
Blei

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