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Silberbromat

Silver bromate

HCID 22763417
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Grundinformationen

CAS
7783-89-3
Standard-SMILES
[Ag+].[O-][Br+3]([O-])([O-])[O-]
InChIKey
BVUZULNXSIDAFI-UHFFFAOYSA-N
Summenformel
AgBrO4
Durchschnittliche Molmasse
251,77 g/mol
Monoisotopische Masse
249,80309

Überblick

Silver bromate is a chemical compound of silver and bromine. It is used as an oxidant for the transformation of tetrahydropyranyl ethers to carbonyl compounds. Bromine is a halogen element with the symbol Br and atomic number 35. Diatomic bromine does not occur naturally, but bromine salts can be found in crustal rock. Silver is a metallic element with the chemical symbol Ag and atomic number 47. It occurs naturally in its pure, free form, as an alloy with gold and other metals, and in minerals such as argentite and chlorargyrite. (L808, L809, L625, L636)

Namen und Bezeichner

Bevorzugter Name
Silver bromate
IUPAC
silver perbromate
Lokaler Name
Silberbromat
Englischer Name
SILVER BROMATE
Summenformel
AgBrHO3
Molmasse
236.78

Namen und Synonyme

DTXSID60999042argentio bromateRefChem:886277DTXCID101426020232-032-87783-89-3Silver bromateSilver(1+) perbromateEINECS 232-032-8Silver(I) bromateSilver bromate,97%Bromic acid silver(I) salt
Weitere Namen anzeigen
SILVER BROMATE ISO 9001:2015 REACHSILVER BROMATE, 97%SILVER BROMATE, 97%SILVER BROMATE, 97%

Datenbank-Bezeichner

CAS
7783-89-3
PubChem CID
22763417
DTXSID
DTXSID60999042
EC Number
232-032-8

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA)
74,3 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
4
Frei drehbare Bindungen
0
Schwere Atome
6
Formalladung
0
Komplexität
95,8

Physikochemische Eigenschaften

Dichte
5.206 g/mL · 5.206 g/mL at 25 °C(lit.)
Aggregatzustand
white tetragonal crystals
Farbe
white tetragonal crystals, crystalline
Wasserlöslichkeit
100 g · g/100g solution H2O: 0.193 (25°C), 1.325 (90°C) [KRU93]
CAS Datenbank
7783 · 7783-89-3(CAS DataBase Reference)

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

GHS-Klassifizierung

GHS Classification · 4 Einträge

Danger

H272 (100%): May intensify fire; oxidizer [Danger Oxidizing liquids; Oxidizing solids]

P210, P220, P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 39 reports by companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Gefahrenhinweise

Hazard Classes and CategoriesOx. Sol. 2 (100%)

Toxikologische Informationen

Treatment · 1 Eintrag

EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.

Health Effects · 1 Eintrag

Bromine vapour causes irritation and direct damage to the mucous membranes. Elemental bromine also burns the skin. The bromide ion is a central nervous system depressant and chronic exposure produces neuronal effects. This is called bromism and can result in central reactions reaching from somnolence to coma, cachexia, exicosis, loss of reflexes or pathologic reflexes, clonic seizures, tremor, ataxia, loss of neural sensitivity, paresis, papillar edema of the eyes, abnormal speech, cerebral edema, delirium, aggressiveness, and psychoses. Bromate is also a potential carcinogen. Exposure to high levels of silver for a long period of time may result in a condition called arygria, a blue-gray discoloration of the skin and other body tissues. Argyria is a permanent effect but does not appear to be harmful to health. While silver itself is not toxic, most silver salts are, and may damage the liver, kidney, and central nervous system, as well as be carcinogenic. (L808, L809, L810, L625, L626, L627, L638)

Chemie und Industrie

Pharmakologische Informationen

Metabolism/Metabolites · 1 Eintrag

Bromine is mainly absorbed via inhalation, but may also enter the body through dermal contact. Bromine salts can be ingested. Due to its reactivity, bromine quickly forms bromide and may be deposited in the tissues, displacing other halogens. Silver compounds can also be absorbed orally and dermally. It distributes throughout the body in the blood, particularily to the liver. Insoluble silver salts are transformed into soluble silver sulfide albuminates, bind to amino or carboxyl groups in RNA, DNA, and proteins, or are reduced to metallic silver by ascorbic acid or catecholamines. Metallic silver is oxidized and may deposit in the tissues, causing arygria. Silver is eliminated primarily in the faeces. (L808, L626)

Verwendung und Herstellung

UsesSilver bromate is used as an oxidant for the transformation of tetrahydropyranyl ethers to carbonyl compounds. (L636)

Anwendungen

VerwendenSilver bromate is useful oxidant for the transformation of tetrahydropyranyl ethers to carbonyl compounds.1

Vor- und nachgelagerte Produkte

Vorgelagerte Rohstoffe

Disilber(1+)sulfat

Nachgelagerte Produkte

Bromsure

Anbieter8 Anbieter

上海迈瑞尔生化科技有限公司4006356688 18621169109 · [email protected]

Zugehörige Reaktionen

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Notizen zur Verbindung

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Exposure RoutesOral (L626) ; inhalation (L626) ; dermal (L626)
Toxicity Summary · 1 Eintrag

Bromine is a powerful oxidizing agent and is able to release oxygen free radicals from the water in mucous membranes. These free radicals are also potent oxidizers and produce tissue damage. In additon, the formation of hydrobromic and bromic acids will result in secondary irritation. The bromide ion is also known to affect the central nervous system, causing bromism. This is believed to be a result of bromide ions substituting for chloride ions in the in actions of neurotransmitters and transport systems, thus affecting numerous synaptic processes. Metallic silver is oxidized and may deposit in the tissues, causing arygria. The silver ion is known to inhibit glutathione peroxidase and NA+,K+-ATPase activity, disrupting selenium-catalyzed sulfhydryl oxidation-reduction reactions and intracellular ion concentrations, respectively. Silver nanoparticles are believed to disrupt the mitochondrial respiratory chain, causing oxidative stress, reduced ATP synthesis, and DNA damage. (L808, A243, A244, A245, A246, L626, L627, A543)

Signs and Symptoms · 1 Eintrag

Bromine vapour causes irritation and direct damage to the mucous membranes. Symptoms include lacrimation, rhinorrhoea, eye irritation with mucous secretions from the oropharyngeal and upper airways, coughing, dyspnoea, choking, wheezing, epistaxis, and headache. The bromide ion is a central nervous system depressant producing ataxia, slurred speech, tremor, nausea, vomiting, lethargy, dizziness, visual disturbances, unsteadiness, headaches, impaired memory and concentration, disorientation and hallucinations. This is called bromism. Exposure to high levels of silver for a long period of time may result in a condition called arygria, a blue-gray discoloration of the skin and other body tissues. Argyria is a permanent effect but does not appear to be harmful to health. Exposure to high levels of silver in the air has resulted in breathing problems, lung and throat irritation, and stomach pains. Skin contact with silver can cause mild allergic reactions such as rash, swelling, and inflammation in some people. (L808, L626, L627)

Carcinogen ClassificationPotassium bromate: 2B, possibly carcinogenic to humans. (L135)

Sicherheitsdaten

F
8
wgk
3
ridadr
UN 1450 5.1/PG 2
hs_code
28432900
risk_code
8-36/37/38
hazard_code
O,Xi
safety_code
17-26-36
hazard_class
5.1
packing_group
II
上海景颜化工科技有限公司
13817811078 · [email protected]
赛默飞世尔科技(中国)有限公司800-810-5118 · [email protected]
Shaanxi Didu New Materials Co. Ltd+86-86-17392712779 +86-13289823923 · [email protected]
厦门盈融达化工有限公司+86-0592-6210733 · [email protected]
陕西缔都医药化工有限公司029-029-029-81148696 18161915376 · [email protected]
XIAMEN AMITY INDUSTRY AND TRADE CO., LTD.+8618950047208 · [email protected]
DAYANG CHEM (HANGZHOU) CO.,LTD+86-88938639 +86-17705817739 · [email protected]