Bendiocarb (ISO)

Fuam · FICAM · Sedox · tatoo · DYCARB · GARVOX · nc6897 · Niomil

Identifikatoren & physikalische Daten

CAS No.	22781-23-3
Summenformel	C11H13NO4
Durchschnittliche Molmasse	223,22 g/mol
Monoisotopische Masse	223,0844579 g/mol
SMILES	CNC(=O)Oc1cccc2c1OC(C)(C)O2
InChIKey	XEGGRYVFLWGFHI-UHFFFAOYSA-N
PubChem CID	2314
ChEMBL	CHEMBL465018
ChEBI	CHEBI:34556
EC No.	245-216-8
DTXSID	DTXSID9032327
Lokaler Name	Bendiocarb (ISO)

Chemische & physikalische Eigenschaften

XLogP	1,7
Polarare Oberfläche (TPSA)	56,8
H-Brücken-Donoren	1
H-Brücken-Akzeptoren	4
Frei drehbare Bindungen	2
Schwere Atome	16
Formalladung	0
Komplexität	279
pH	Very weak acid
SpringerMaterials Properties	Fusion temperature
Pestizide	InsecticidesActive substance -> EU Pesticides database: Not approvedPesticides -> Carbamate InsecticidesPesticide (Bendiocarb) -> USDA PDB
LogP (Verteilungskoeffizient)	log Kow = 1.70
Geruch	Odorless
Dichte	1.25 g/cu cm at 20 °C1.2500
Color/Form	White powderWhite solidColorless, crystalline solid
Löslichkeit	In water, 260 mg/L at 25 °C200 g/kg acetone100 g/kg dichloromethane200 g/kg dioxane40 g/kg benzene10 g/kg ethanol350 ppm in hexaneIn dichloromethane 200-300, acetone 15-200, methanol 75-100, ethyl acetate 60-75, p-xylene 11.7, n-hexane 0.225 (all in g/L, 20 °C)Solubility in kerosene 0.03%DMF: 30 mg/ml,DMSO: 30 mg/ml,DMSO:PBS (pH 7.2) (1:9): 0.1 mg/ml,Ethanol: 5 mg/ml280 mg l-1 (20 °C)
Corrosivity	Lack of corrosive properties
Decomposition	When heated to decomposition it emits toxic fumes of /nitrogen oxides/.
Schmelzpunkt	129.6 °C"265 °F"129-130°
Dampfdichte	1.25
Siedepunkt	364.51°C (rough estimate)
Dampfdruck	4.6 x 10-3 Pa (25 °C)
Brechungsindex	1.4960 (estimate)
Flammpunkt	>100 °C
Lagerbedingungen	0-6°C
pKa (Säurekonstante)	11.98±0.46(Predicted)
Aggregatzustand	Powder/Solid
Farbe	White
Merck	13,1033
BRN	1315404
Henry-Konstante	2.5×102 mol/(m3Pa) at 25℃, Duchowicz et al. (2020)
Hauptanwendungen	agricultureenvironmental
InChI	1S/C11H13NO4/c1-11(2)15-8-6-4-5-7(9(8)16-11)14-10(13)12-3/h4-6H,1-3H3,(H,12,13)
InChIKey	XEGGRYVFLWGFHI-UHFFFAOYSA-N
SMILES	CNC(=O)Oc1cccc2OC(C)(C)Oc12
CAS Datenbank	22781-23-3(CAS DataBase Reference)
NIST chemische Informationen	Bendiocarb(22781-23-3)
EPA chemische Informationen	Bendiocarb (22781-23-3)

Sicherheit & Vorschriften

GHS-Einstufung	DangerH300: Fatal if swallowed [Danger Acute toxicity, oral]P261, P262, P264, P270, P271, P273, P280, P301+P316, P302+P352, P304+P340, P316, P321, P330, P361+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)H300 (41.9%): Fatal if swallowed [Danger Acute toxicity, oral]P261, P262, P264, P270, P271, P273, P280, P301+P316, P302+P352, P304+P340, P316, P317, P321, P330, P361+P364, P362+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)
Regulatorische Informationen	2002/2076Bendiocarb: HSNO Approval: HSR003444 Approved with controlsThe New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)
Weitere Sicherheitsinformationen	IMAP assessments - 1,3-Benzodioxol-4-ol, 2,2-dimethyl, methyl carbamate: Environment tier I assessment
DOT-Kennzeichnung	Poison
Brandgefahren	Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Gesundheitsgefahren	Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Gefahrenübersicht	The oral LD50 (rats) = 34-156 mg/kg. Skin absorption is the most like route of occupational exposure. [EXTOXNET] Eliminated in urine of human volunteer within 22 hours of oral dosingNot irritating to the skinNo evidence of skin sensitization in animal testingIn a pesticide surveillance study in the UK from 2004-2012, 175 (2.6%) of the 6689 pesticide exposures involved benediocarb. None of these cases was fatal or graded as severe. [ACGIH] See CARBAMATE INSECTICIDES.
Reaktive Gruppe	Carbamates
Special Reports	USEPA/OPPTSR.E.D. Facts: Bendiocarb p.5 EPA 738-F-99-010 (Sept 1999)
RCRA-Anforderungen	U278As stipulated in 40 CFR 261.33, when bendiocarb, as a commercial chemical product or manufacturing chemical intermediate or an off-specification commercial chemical product or a manufacturing chemical intermediate, becomes a waste, it must be managed according to Federal and/or State hazardous waste regulations. Also defined as a hazardous waste is any residue, contaminated soil, water, or other debris resulting from the cleanup of a spill, into water or on dry land, of this waste. Generators of small quantities of this waste may qualify for partial exclusion from hazardous waste regulations (40 CFR 261.5).

Anwendungen & Verwendung

Verwenden

Bendiocarb is a benzodioxolyl carbamate derivative. Bendiocarb is commonly used as an insecticide in agriculture against a wide range of pests and insects. Bendiocarb is one of the insecticides recomm ended by world health organization (WHO) for use in malaria control.