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Kaliumoleat

Potassium Oleate

HCID 23665571
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Grundinformationen

CAS
143-18-0
Standard-SMILES
CCCCCCCC/C=C\CCCCCCCC(=O)[O-].[K+]
InChIKey
MLICVSDCCDDWMD-KVVVOXFISA-M
Summenformel
C18H33KO2
Durchschnittliche Molmasse
320,6 g/mol
Monoisotopische Masse
320,21176198

Überblick

Potassium oleate appears as brown solid or clear to amber liquid with a soapy odor. Sinks and mixes slowly with water. (USCG, 1999)

Namen und Bezeichner

Bevorzugter Name
Potassium Oleate
IUPAC
potassium (Z)-octadec-9-enoate
Lokaler Name
Kaliumoleat
Englischer Name
Potassium oleate
Summenformel
C18H33KO2
Molmasse
321.56

Namen und Synonyme

Potassium oleate143-18-0Oleic acid potassium saltTrenamine D-200Trenamine D-201Caswell No. 698BHSDB 5643POTASSIUM CIS-9-OCTADECENOIC ACIDPotassium 9-octadecenoate, (Z)-EINECS 205-590-5EPA Pesticide Chemical Code 07909574WHF607EU
Weitere Namen anzeigen
OS SoapKaliumoleattrenamined-200trenamined-201potasisum oleatePotassiunm oleatePotassiumOleate>Oleic Acid PotassiumPotassium Oleate 35%
9-Octadecenoic acid (Z)-, potassium salt9-Octadecenoic acid, potassium saltPOTASSIUM OLEATE [MI]DTXSID0025949POTASSIUM OLEATE [VANDF]E-470(II)OLEIC ACID, POTASSIUM SALTINS-470(II)OLEIC ACID, POTASSIUM SALTPOTASSIUM CIS-9-OCTADECENOIC ACID [HSDB]

Datenbank-Bezeichner

CAS
143-18-0
PubChem CID
23665571
DTXSID
DTXSID0025949

Eigenschaften

Berechnete StruktureigenschaftenWird ergänzt

Polarare Oberfläche (TPSA)
40,1 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
2
Frei drehbare Bindungen
15
Schwere Atome
21
Formalladung
0
Komplexität
239

Experimentelle und physikochemische Eigenschaften

Chemical ClassesOther Uses -> Emulsifiers/Surfactants
Cosmetics · 2 Einträge

Cosmetic ingredients (Potassium Oleate) -> CIR (Cosmetic Ingredient Review)

Surfactant; Emulsifying

Pesticides · 2 Einträge

Agrochemicals -> Pesticide active substances

Active substance -> EU Pesticides database: Not approved

OdorFAINT SOAPY ODOR
Food AdditivesANTIMICROBIAL AGENT, EMULSIFIER OR EMULSIFIER SALT, FORMULATION AID, STABILIZER OR THICKENER -> FDA Substance added to food
Density · 2 Einträge

greater than 1.1 at 68 °F (solid or liquid) (USCG, 1999)

GREATER THAN 1.1 @ 20 °C

Color/Form · 3 Einträge

YELLOWISH OR BROWNISH, SOFT MASS OR CRYSTALS

BROWN SOLID OR LIQUID

GRAY-TAN PASTE

Solubility · 2 Einträge

greater than or equal to 100 mg/mL at 70 °F (NTP, 1992)

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

GHS-Klassifizierung

GHS Classification · 6 Einträge

This chemical does not meet GHS hazard criteria for 6.5% (50 of 770) of reports.

Warning

H315 (41.3%): Causes skin irritation [Warning Skin corrosion/irritation]

P261, P264, P264+P265, P271, P273, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 770 reports by companies from 16 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Warning

Gefahrenhinweise

Regulatory Information · 3 Einträge

Chemical: 9-Octadecenoic acid, potassium salt, (Z)-

9-Octadecenoic acid (9Z)-, potassium salt (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 9-Octadecenoic acid (9Z)-, potassium salt (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Potassium oleate: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Other Safety InformationIMAP assessments - 9-Octadecenoic acid, potassium salt, (Z)-: Human health tier I assessment
Fire HazardsSpecial Hazards of Combustion Products: Irritating vapors and toxic gases, such as carbon dioxide and carbon monoxide, may be formed when involved in fire. (USCG, 1999)
Health HazardsInhalation of dust causes irritation of nose and throat, coughing, and sneezing. Ingestion causes mild irritation of mouth and stomach. Contact with eyes causes irritation. (USCG, 1999)

Chemie und Industrie

Verwendung und Herstellung

Uses · 5 Einträge

CIR ingredient: Potassium Oleate

Used as detergent and emulsifying agent; Also used in fungicidal preparations; [HSDB]

Farming (Pesticides) [Category: Industry]

DETERGENT

EMULSIFYING AGENT

U.S. Production2023: 4,000,000 - <5,500,000 lb
Consumer UsesNot Known or Reasonably Ascertainable
Industry UsesPlasticizer
Household ProductsInformation on 17 consumer products that contain Potassium cis-9-octadecenoic acid in the following categories is provided:
Use Classification · 4 Einträge

EPA Safer Chemical Functional Use Classes -> Surfactants

Safer Chemical Classes -> Green circle - The chemical has been verified to be of low concern

Food Additives -> ANTICAKING_AGENT; EMULSIFIER -> JECFA Functional Classes

Cosmetics -> Surfactant; Emulsifying

General Manufacturing Information · 5 Einträge

Custom Compounding of Purchased Resins

9-Octadecenoic acid (9Z)-, potassium salt (1:1): ACTIVE

BIOCIDAL EFFECTS OF POTASSIUM SALTS OF FATTY ACIDS WERE TESTED ON SEVERAL FOREST INSECT PESTS, INCL BALSAM WOOLLY APHID, SPRUCE GALL APHID, WESTERN BLACKHEADED BUDWORM, FALSE HEMLOCK LOOPER, FOREST-TENT CATERPILLAR, & DOUGLAS-FIR TUSSOCK MOTH. FOR ALMOST ALL SPECIES, THE MOST EFFECTIVE SALTS CAUSING MORTALITY WERE CENTERED AROUND POTASSIUM OLEATE IN THE UNSATURATED C18 SALTS.

OF 11 C6-C22 EVEN-NUMBERED SATURATED & UNSATURATED FATTY ACIDS & THEIR POTASSIUM SALTS TESTED FOR TOXICITY TO BALSAM WOOLLY APHID, ADELGES PICEAE, THE MOST EFFECTIVE FATTY ACID POTASSIUM SALTS WERE CAPRYLATE, CAPRATE, OLEATE, & LINOLEATE. IN GENERAL THE SALTS WERE MORE EFFECTIVE THAN THEIR CORRESPONDING ACIDS; EGGS WERE GENERALLY LESS SENSITIVE TO THE SALTS THAN LATER APHID STAGES.

USED IN FUNGICIDAL PREPN

Zugehörige Reaktionen

20
Reaktionsaufzeichnung erstellen
Reaktionsgleichung von HRID 34516
HRID 34516als Produktuspto-grants-1988_08
Reaktionsgleichung von HRID 34517
HRID 34517als Produktuspto-grants-1988_08
Reaktionsgleichung von HRID 73476
HRID 73476als Eduktuspto-grants-2014_09
Reaktionsgleichung von HRID 231986
HRID 231986als Produktuspto-grants-1989_07
Reaktionsgleichung von HRID 345713
HRID 345713als Produktuspto-grants-1991_10
Reaktionsgleichung von HRID 460399
HRID 460399als Eduktuspto-grants-2007_03
Reaktionsgleichung von HRID 460400
HRID 460400als Eduktuspto-grants-2007_03
Reaktionsgleichung von HRID 1031412
HRID 1031412als Produktuspto-grants-1990_09
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ChEMBL
CHEMBL3122151
UNII
74WHF607EU
EC Number
205-590-5
Nikkaji
J54.270I

25 G/100 CC OF COLD WATER; SOL IN HOT WATER; 4.315 G/100 CC ALCOHOL @ 13.5 °C; 100 G/100 CC ALCOHOL @ 50 °C; 3.5 G/100 CC ETHER @ 35 °C

Flash Point140 °F CC
Melting Point · 2 Einträge

Starts to decompose at approximately 428 °F (NTP, 1992)

FREEZING POINT: 455-464 °F= 235-240 °C= 508-513 DEG K

Food Contact SubstancesFCS -> FDA Inventory of Food Contact Substances Listed in 21 CFR
Refractive IndexINDEX OF REFRACTION: 1.452

Physikochemische Eigenschaften

Dichte
1.1 g/cm3 · >1.1 g/cm3
Flammpunkt
140 °C · 140 °C
storage temp.
2 · 2-8°C
Wasserlöslichkeit
Soluble in water
Aggregatzustand
powder to crystal
Farbe
Pale white powder
Merck
14 · 14,7650
BRN
4167152 · 4167152
Kosmetik-Inhaltsstoffe Funktionen
SURFACTANT - CLEANSINGSURFACTANT - EMULSIFYING
InChI
InChI=1S/C18H34O2.K/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18(19)20;/h9-10H,2-8,11-17H2,1H3,(H,19,20);/q;+1/p-1/b10-9-;
InChIKey
MLICVSDCCDDWMD-KVVVOXFISA-M
SMILES
C(CCCCCC([O-])=O)C/C=C\CCCCCCCC.[K+]
LogP
3.92 · 3.920 (est)
CAS Datenbank
143 · 143-18-0(CAS DataBase Reference)
EPA chemische Informationen
Potassium oleate (143-18-0)
Hazards SummaryAn eye, nose, and throat irritant; [HSDB]; An irritant; [MSDSonline]
Reactive GroupHydrocarbons, Aliphatic Unsaturated
EPA Safer ChemicalChemical: Potassium oleate
Reactivity Profile · 1 Eintrag

Basic salts, such as POTASSIUM OLEATE, are generally soluble in water. The resulting solutions contain moderate concentrations of hydroxide ions and have pH's greater than 7.0. They react as bases to neutralize acids. These neutralizations generate heat, but less or far less than is generated by neutralization of the bases in reactivity group 10 (Bases) and the neutralization of amines. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible.

Air and Water ReactionsWater soluble. Gives basic aqueous solution.
Hazard Classes and Categories · 2 Einträge

Skin Irrit. 2 (41.3%)

Skin corrosion/irritation - Category 2

Skin, Eye, and Respiratory IrritationsINHALATION OF DUST CAUSES IRRITATION OF NOSE & THROAT, COUGHING, & SNEEZING. INGESTION CAUSES IRRITATION OF MOUTH & STOMACH. CONTACT WITH EYES CAUSES IRRITATION.

Sicherheit und Schutzausrüstung

Fire FightingFire Extinguishing Agents Not to Be Used: Water may be ineffective.
First Aid · 1 Eintrag

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Fire Fighting ProceduresDRY CHEMICAL, ALCOHOL FOAM, CARBON DIOXIDE. ... WATER MAY BE INEFFECTIVE.
Nonfire Spill Response · 1 Eintrag

SMALL SPILLS AND LEAKAGE: If you spill this chemical, you should dampen the solid spill material with water, then transfer the dampened material to a suitable container. Use absorbent paper dampened with water to pick up any remaining material. Seal your contaminated clothing and the absorbent paper in a vapor-tight plastic bag for eventual disposal. Wash all contaminated surfaces with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Disposal Methods · 1 Eintrag

SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

Personal Protective Equipment (PPE) · 2 Einträge

Wear full cover clothing, chemical safety glasses, and rubber or plastic gloves. (USCG, 1999)

CHEMICAL GOGGLES & RUBBER GLOVES.

Toxikologische Informationen

Interactions · 1 Eintrag

ESTRADIOL, DIETHYLSTILBESTROL, & TESTOSTERONE INHIBITED BIOSYNTHESIS OF FREE & ESTERIFIED CHOLESTEROL FROM MEVALONIC ACID IN LIVER HOMOGENATE PREPN FROM YOUNG RATS & OLD FEMALE RAT PREPN. POTASSIUM OLEATE TENDED TO DECR THE INHIBITORY EFFECT OF THE SEX HORMONES.

Toxicity Summary · 2 Einträge

The CIR Expert Panel concluded that the following ingredients are safe in the present practices of use andconcentration described in the safety assessment when formulated to be non-irritating and non-sensitizing, which may be basedon a QRA...Potassium Oleate..

Safe for use in cosmetics, with qualifications

Human Toxicity ExcerptsINHALATION OF DUST CAUSES IRRITATION OF NOSE & THROAT, COUGHING, & SNEEZING. INGESTION CAUSES IRRITATION OF MOUTH & STOMACH. CONTACT WITH EYES CAUSES IRRITATION.
Non-Human Toxicity ExcerptsUSING THE RABBIT DRAIZE EYE TEST, POTASSIUM OLEATE (12% AQ) CAUSED CONSIDERABLE EYE IRRITATION COMPARED TO A 70% ISOPROPYL ALC STD.

Sicherheitsdaten

wgk
1
tsca
TSCA listed
hs_code
2916.15.5100
RTECS-Nr.
RK1150000
risk_code
36/37/38
Toxizität
eye-rbt 12 mg/48H JANCA2 56,905,73
hazard_code
Xi
safety_code
26-36
Speicherklasse
11 - Combustible Solids
Giftige Stoffe Daten
143-18-0(Hazardous Substances Data)
Hazard Classifications
Eye Irrit. 2

Anwendungen

VerwendenPotassium Oleate is the potassium salt of oleic acid. it is used as a binder, emulsifier, and anticaking agent.

Vor- und nachgelagerte Produkte

Vorgelagerte Rohstoffe

FormaldehydN-Methylmethanamin, gasförmig

Nachgelagerte Produkte

NatriumoleatOleic acid