Lithiumhexafluorophosphat(1-)

Lithium hexafluorophosphate

HCID 23688915
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Grundinformationen

CAS
21324-40-3
Standard-SMILES
F[P-](F)(F)(F)(F)F.[Li+]
InChIKey
AXPLOJNSKRXQPA-UHFFFAOYSA-N
Summenformel
F6LiP
Durchschnittliche Molmasse
151,9 g/mol
Monoisotopische Masse
151,9801844

Namen und Bezeichner

Bevorzugter Name
Lithium hexafluorophosphate
IUPAC
lithium hexafluorophosphate
Lokaler Name
Lithiumhexafluorophosphat(1-)
Englischer Name
Lithium hexafluorophosphate
Summenformel
F6LiP
Molmasse
151.91

Namen und Synonyme

Lithium hexafluorophosphate21324-40-3Lithium hexafluorophosphate(V)LiPF6lithium,hexafluorophosphatelithium;hexafluorophosphatePhosphate(1-), hexafluoro-, lithiumT9T8DY51J3Lithium hexafluorophosphate(1-)MFCD00011096UNII-T9T8DY51J3Phosphate(1-), hexafluoro-, lithium (1:1)
Weitere Namen anzeigen
1.0 M LiPF6 DMCPurelytePowerlyte1.0 M LiPF6 PC1.0 M LiPF6 DEC1.0 M LiPF6 EMC1.0 M LiPF6 MEC1.0 M LiPF6 EC/DMC
EINECS 244-334-7Lithium hexafluorophosphate (Battery Grade)EC 244-334-7F6LiPLithium phosphorus fluorideLithiumhexafluorophosphate(V)hexafluorophosphate lithium saltDTXSID2066698

Datenbank-Bezeichner

CAS
21324-40-3
PubChem CID
23688915
DTXSID
DTXSID2066698
ChEBI
CHEBI:172376
UNII
T9T8DY51J3
EC Number
244-334-7

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA)
0 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
7
Frei drehbare Bindungen
0
Schwere Atome
8

Experimentelle und physikochemische Eigenschaften

Density1.5 @25 °C
Melting Point200 °C
Physical Description · 2 Einträge

Liquid; CBI; Other Solid; Dry Powder

White to almost white hygroscopic powder; [Acros Organics MSDS]

Physikochemische Eigenschaften

Schmelzpunkt
200 °C · 200 °C (dec.) (lit.)
Siedepunkt
90 °C · 90°C
Dichte
1.5 g/mL · 1.5 g/mL (lit.)
Flammpunkt
25 °C · 25 °C
storage temp.
Inert atmosphere,Room Temperature
Löslichkeit
2 O: · H2O: slightly soluble(lit.)

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 5 Einträge

Danger

H301 (79.7%): Toxic if swallowed [Danger Acute toxicity, oral]；H302 (20.3%): Harmful if swallowed [Warning Acute toxicity, oral]；H311 (16.2%): Toxic in contact with skin [Danger Acute toxicity, dermal]；H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]；H318 (69.9%): Causes serious eye damage [Danger Serious eye damage/eye irritation]；H372 (81.8%): Causes damage to organs through prolonged or repeated exposure [Danger Specific target organ toxicity, repeated exposure]

P260, P262, P264, P264+P265, P270, P280, P301+P316, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P319, P321, P330, P361+P364, P363, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 296 reports by companies from 22 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

Gefahrenhinweise

Regulatory Information · 4 Einträge

Chemical: Phosphate(1-), hexafluoro-, lithium

Phosphate(1-), hexafluoro-, lithium (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Phosphate(1-), hexafluoro-, lithium (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

PMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.

Status: Active Update: 02-11-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/13201

Hazards SummaryCauses burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; Harmful by ingestion; Toxic by skin absorption; [Acros Organics MSDS] See FLUORIDES.
Hazard Classes and CategoriesAcute Tox. 3 (79.7%)；Acute Tox. 4 (20.3%)；Acute Tox. 3 (16.2%)；Skin Corr. 1A (100%)；Eye Dam. 1 (69.9%)；STOT RE 1 (81.8%)

Sicherheit und Schutzausrüstung

Exposure Control and Personal Protection · 2 Einträge

Biological Exposure Indices (BEI) [ACGIH] - Fluorides in urine = 2 mg/L prior to shift or 3 mg/L at end of shift; (Repeated measurements recommended.)

1.0 [mg/m3], inhalable fraction, as F (0.2 mg/m3, inhalable fraction, as Li)[German Research Foundation (DFG)]

Threshold Limit Values (TLV)2.5 [mg/m3], as F
Permissible Exposure Limit (PEL)2.5 [mg/m3], as F
Protective Action Criteria (PAC) · 3 Einträge

0.90 [mg/m3]

9.9 [mg/m3]

59 [mg/m3]

Immediately Dangerous to Life or Health (IDLH)250.0 [mg/m3], as F

Toxikologische Informationen

Adverse EffectsDermatotoxin - Skin burns.；Toxic Pneumonitis - Inflammation of the lungs induced by inhalation of metal fumes or toxic gases and vapors.

Regulatorische Informationen

Regulatory Information · 4 Einträge

Chemical: Phosphate(1-), hexafluoro-, lithium

Phosphate(1-), hexafluoro-, lithium (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Phosphate(1-), hexafluoro-, lithium (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

PMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.

Status: Active Update: 02-11-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/13201

Sicherheitsdaten

F
3-10
wgk
3
tsca
TSCA listed
ridadr
UN 3260 8/PG 1
hs_code
28269020
risk_code
34-24-22-37-10-48/23/24/25-35-11

Chemie und Industrie

Verwendung und Herstellung

U.S. Production2023: 10,000,000 - <25,000,000 lb；2022: 8,500,000 - <10,000,000 lb；2021: 4,000,000 - <5,500,000 lb；2020: 1,000,000 - <5,000,000 lb
Consumer UsesIon exchange agent；Conductive agent
Industry UsesConductive agent；Ion exchange agent
General Manufacturing Information · 2 Einträge

Services；Other (requires additional information)；All Other Chemical Product and Preparation Manufacturing；Transportation Equipment Manufacturing；Electrical Equipment, Appliance, and Component Manufacturing

Phosphate(1-), hexafluoro-, lithium (1:1): ACTIVE

Anwendungen

VerwendenLithium hexafluorophosphate (LiPF6) is the most widely used solute in liquid and gelled-type electrolytes，which has good solubility in various solvents such as PC (propylene carbonate) .

Vor- und nachgelagerte Produkte

Nachgelagerte Produkte

Anbieter100 Anbieter

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
河北创海生物科技有限公司+86-86-13131129325 · [email protected]
湖南嘉航医药科技有限公司85521272 15200744171 · [email protected]
T&W GROUP021-61551611 13296011611 · [email protected]
Hebei Yanxi Chemical Co., Ltd.+86-17531190177 · [email protected]

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