Molybdenum

Excerpt from ERG Guide 170 [Metals (Powders, Dusts, Shavings, Borings, Turnings, or Cuttings, etc.)]:

In case of fire in the surroundings, use appropriate extinguishing media.

Fresh air, rest.

Rinse skin with plenty of water or shower.

Rinse with plenty of water for several minutes (remove contact lenses if easily possible).

Rinse mouth. Give one or two glasses of water to drink.

Excerpt from NIOSH Pocket Guide for Molybdenum:

(General first aid procedures)

Prior to working with this chemical you should be trained on its proper handling and storage. Manganese must be stored to avoid contact with strong oxidizers (such as chlorine, bromine, and fluorine) since violent reactions occur. Store in tightly closed containers in a cool, well ventilated area away from bromine, trifluoride, fluorine, chlorine trifluoride and lead oxide.

Evacuate and restrict persons not wearing protective equipment from area of spill or leak until cleanup is complete. Remove all ignition sources. Use HEPA vacuum or wet method to reduce dust during clean-up. Do not dry sweep. Collect powdered material in the most convenient and safe manner and deposit in sealed containers. Ventilate area after clean-up is complete. It may be necessary to contain and dispose of this chemical as a hazardous waste. If material or contaminated runoff enters waterways, notify downstream users of potentially contaminated waters. Contact your Department of Environmental Protection or your regional office of the federal EPA for specific recommendations. If employees are required to clean up spills, they must be properly trained and equipped. OSHA 1910.120(q) may be applicable.

SRP: The most favorable course of action is to use an alternative chemical product with less inherent propensity for occupational exposure or environmental contamination. Recycle any unused portion of the material for its approved use or return it to the manufacturer or supplier. Ultimate disposal of the chemical must consider: the material's impact on air quality; potential migration in soil or water; effects on animal, aquatic, and plant life; and conformance with environmental and public health regulations.

Recovery is indicated whenever possible. Processes for recovery of molybdenum from scrap, flue dusts, spent catalysts, and other industrial wastes have been developed.

The following wastewater treatment technologies have been investigated for molybdenum: Chemical precipitation.

SRP: The scientific literature for the use of contact lenses in industry is conflicting. The benefit or detrimental effects of wearing contact lenses depend not only upon the substance, but also on factors including the form of the substance, characteristics and duration of the exposure, the uses of other eye protection equipment, and the hygiene of the lenses. However, there may be individual substances whose irritating or corrosive properties are such that the wearing of contact lenses would be harmful to the eye. In those specific cases, contact lenses should not be worn. In any event, the usual eye protection equipment should be worn even when contact lenses are in place.

... A complete respiratory protection program should be instituted which incl regular training, maintenance, inspection, cleaning, and evaluation. /Sol Molybdenum compounds (as Mo); Molybdenum and insoluble molybdenum compounds/

Renal (Urinary System or Kidneys), Respiratory (From the Nose to the Lungs)

Urinary

Eyes, respiratory system, liver, kidneys

inhalation, ingestion, skin and/or eye contact

Ingestion; inhalation

High levels of molybdenum can interfere with the body's uptake of copper, producing copper deficiency. Molybdenum prevents plasma proteins from binding to copper, and it also increases the amount of copper that is excreted in urine. Molybdenum dusts and fumes, which can be generated by mining or metalworking, can be toxic, especially if ingested (including dust trapped in the sinuses and later swallowed). (Wikipedia)

Cough.

Redness.

In Animals: irritation eyes, nose, throat; anorexia, diarrhea, weight loss; listlessness; liver, kidney damage

Molybdenum

Urinary

5 x 10 ^-3 mg/kg-day

The following medical procedures should be made available to each employee who is exposed to molybdenum and insoluble molybdenum compounds at potentially hazardous levels: Initial medical screening: Employees should be screened for history of certain medical conditions /kidney disease; chronic respiratory disease; liver disease/ which might place the employee at increased risk from molybdenum and insoluble molybdenum compounds exposure. Periodic medical exam: Any employee developing the above listed conditions should be referred for further medical examination. /Molybdenum and insoluble molybdenum compounds/

/SIGNS AND SYMPTOMS/ Metallic and poorly soluble molybdenum compounds (such as molybdenum disulfide, molybdenum dioxide) have limited animal experimental data and no human toxicity data. From the scant information available, these materials thought to be poorly soluble and to have low animal and human toxicity. Until toxicologic or human data indicate a more serious threat to human health, these materials are assigned TLV-TWAs of 10 mg/m3 (inhalable particulate mass) and 3 mg/m3 (respirable particulate mass) to protect against any irritant effects of these materials. /Metallic molybdenum and poorly soluble molybdenum/

/SIGNS AND SYMPTOMS/ Pneumoconiosis with X-ray findings and subjective symptoms ... reported in 3 out of 19 workers exposed to metallic molybdenum and molybdenum trioxide. Exposure varied between 1 and 19 mg/cu m for 4 to 7 yr. /Metallic molybdenum and molybdenum trioxide/

/SIGNS AND SYMPTOMS/ Increased blood uric acid values and gout-like symptoms have been reported among workers exposed to molybdenum in a copper-molybdenum plant ... . /Molybdenum and compounds/

/SIGNS AND SYMPTOMS/ In a 1984 review, an increased incidence of nonspecific symptoms, including weakness, fatigue, headache, anorexia, and joint and muscle pains, was reported among mining and metallurgy workers exposed at 60 to 600 mg/cu m molybdenum /Molybdenum dusts/

For more Human Toxicity Excerpts (Complete) data for MOLYBDENUM (7 total), please visit the HSDB record page.

/LABORATORY ANIMALS: Acute Exposure/When rats inhaled dusts of metallic molybdenum for 1 hour at 25 to 30 g/cu m, there were no changes in the condition of the animals observed in the 4 weeks following exposure.

/LABORATORY ANIMALS: Subchronic or Prechronic Exposure/ ... Rats/were exposed/ to aerosols of metallic molybdenum ... 1 hour daily for 30 days. Exposure concentrations were as follows: molybdenum metal, 12 to 15 g/cu m ... . With the exception of slight growth depression, all the rats exposed to metallic molybdenum ... appeared normal during the exposure period. There was considerable deposition of dust in the lungs with thickening of the alveolar septa, which contained connective tissue fibers.

/LABORATORY ANIMALS: Chronic Exposure or Carcinogenicity/ ... Rabbits were given a suspension of powdered molybdenum intratracheally in doses of 70-80 mg/kg. After nine months, diffuse pneumoconiosis with interstitial pneumonia was observed upon histological exam.

/OTHER TOXICITY INFORMATION/ Fume from arcing molybdenum metal causes kidney /and liver/ damage in animals. /Molybdenum fume/

(AZ) ARIZONA 70 ug/L

(FL) FLORIDA 100 ug/L

(ME) MAINE 35 ug/L