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Germaniumtetrahydrid
GeH4 · Un2192 · Germane · Monogermane · GeH4 99,999% · GERMANE 99.99+% · Einecs 231-961-6 · germaniumhydride

Identifikatoren & physikalische Daten
| CAS No. | 24968-55-6 |
|---|---|
| Summenformel | GeH4 |
| Durchschnittliche Molmasse | 76,66 g/mol |
| Monoisotopische Masse | 77,95247793 g/mol |
| SMILES | [GeH4] |
| InChIKey | QUZPNFFHZPRKJD-UHFFFAOYSA-N |
| PubChem CID | 23984 |
| ChEBI | CHEBI:30443 |
| EC No. | 231-961-6 |
| DTXSID | DTXSID7052521 |
| Lokaler Name | Germaniumtetrahydrid |
Chemische & physikalische Eigenschaften
| Polarare Oberfläche (TPSA) | 0 |
|---|---|
| H-Brücken-Donoren | 0 |
| H-Brücken-Akzeptoren | 0 |
| Frei drehbare Bindungen | 0 |
| Schwere Atome | 1 |
| Formalladung | 0 |
| Komplexität | 0 |
| Stoffklassen | Toxic Gases & Vapors -> HydridesFlammable agents - 4th degree |
| Geruch | Pungent |
| Dichte | 3.133 g/LRelative density (water = 1): 1.531.523 @ -142°C2.65(relative gas density)1,53 g/cm3 |
| Color/Form | Colorless gasShipped as a compressed gas |
| Löslichkeit | Insoluble (NIOSH, 2024)Soluble in hot hydrochloric acidDecomposes in nitric acidInsoluble in waterSolubility in water: noneinsoluble in H2Oinsoluble H2Osoluble liquid ammonia, slightly soluble hot HCl [HAW93] |
| Flammpunkt | Flammable gasNA (Gas) |
| Siedepunkt | -127 °F at 760 mmHg (NIOSH, 2024)-88.1 °C-88.5 °C-90 °C @760 [mm Hg]-88°C |
| Schmelzpunkt | -267 °F (NIOSH, 2024)-165 °C-165°C |
| Dampfdichte | 2.65 (NIOSH, 2024) - Heavier than airwill sink (Relative to Air)Relative vapor density (air = 1): 2.651.53 (142 °C, vs air) |
| Dampfdruck | greater than 1 atm (NIOSH, 2024)> 1 atmosphere>1 atm |
| Ionization Potential | 11.34 eV |
| Physical Description | Germane is a colorless gas with a pungent odor. It is flammable. The gas is heavier than air and a flame can flash back to the source of leak very easily. It is toxic by inhalation. Prolonged exposure of the containers to fire or intense heat may result in their violent rupturing and rocketing. It is used in making electronics.Colorless gas with a pungent odor. [Note: Shipped as a compressed gas.][NIOSH]COLOURLESS COMPRESSED GAS WITH PUNGENT ODOUR.Colorless gas with a pungent odor. |
| Aggregatzustand | colorless gas |
| Wichte | 1.53 |
| Farbe | colorless gasflammable |
| Spezifische Wärmekapazität | Cp(gas): 0.59 J/(g·K), at 25℃ |
| Merck | 13,4418 |
| CAS Datenbank | 7782-65-2 |
| EPA chemische Informationen | Germane (7782-65-2) |
Sicherheit & Vorschriften
| GHS-Einstufung | DangerH220 (100%): Extremely flammable gas [Danger Flammable gases]P203, P210, P222, P260, P264, P270, P271, P280, P284, P301+P317, P304+P340, P316, P320, P330, P377, P381, P403, P403+P233, P405, P410+P403, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 185 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.H220: Extremely flammable gas [Danger Flammable gases] |
|---|---|
| Hazards Identification | Toxic/poison by inhalation (TIH/PIH) |
| Regulatorische Informationen | The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.) |
| DOT-Kennzeichnung | Poison Gas Flammable Gas |
| Brandgefahren | Excerpt from ERG Guide 119 [Gases - Toxic - Flammable]:· Flammablemay be ignited by heat, sparks or flames.Extremely flammable. Gas/air mixtures are explosive. |
| Gesundheitsgefahren | Excerpt from ERG Guide 119 [Gases - Toxic - Flammable]:· TOXICmay be fatal if inhaled or absorbed through skin. Some may cause severe skin burns and eye damage. |
| Gefahrenübersicht | Germanium tetrahydride appears to have the potential to cause hemolysis similar to that caused by arsine and stibine[ACGIH] A skin, eye, and respiratory tract irritantMay cause damage to red blood cells[ICSC] See Germanium. |
| DOT-Nummer und Handbuch | 2192 119 |
| Reaktive Gruppe | Metal Hydrides, Metal Alkyls, Metal Aryls, and Silanes |
| UN-Einstufung | UN Hazard Class: 2.3UN Subsidiary Risks: 2.1 |
| Reactivity Alerts | Strong Reducing Agent |
Anwendungen & Verwendung
Verwenden
It is used to produce high-purity germaniummetal and as a doping substance for electroniccomponents.