Antimonpentachlorid

SbCl5 · ANTIMONY PENTACHLORIDE · ANTIMONY CHLORIDE · Antimoine · Antimonio · Butter of antimony · Antimonic chloride · Antimonpentachlorid

https://huagongshe.com/de/chemical/24294

Identifikatoren & physikalische Daten

CAS No.	7647-18-9
Summenformel	Cl5Sb
Durchschnittliche Molmasse	299 g/mol
Monoisotopische Masse	295,7480791 g/mol
SMILES	[Cl][Sb]([Cl])([Cl])([Cl])[Cl]
InChIKey	VMPVEPPRYRXYNP-UHFFFAOYSA-I
PubChem CID	24294
EC No.	231-601-8
DTXSID	DTXSID30893043
Lokaler Name	Antimonpentachlorid

Chemische & physikalische Eigenschaften

Polarare Oberfläche (TPSA)	0
H-Brücken-Donoren	0
H-Brücken-Akzeptoren	0
Frei drehbare Bindungen	0
Schwere Atome	6
Formalladung	0
Komplexität	37,1
Stoffklassen	Metals -> Metalloid Compounds (Antimony)Corrosives
Geruch	Pungentoffensive
Dichte	2.354 at 68 °F (USCG, 1999) - Denser than waterwill sink3.10 g/cu cm2.336 @25 °C2.36 g/mL at 25 °C(lit.)
Viscosity	2.034 cP at 29.4 °C
Color/Form	Colorless or yellow liquidColorless to yellow, oily liquidReddish yellow, oily liquidWhite liquid or monoclinic crystals
Löslichkeit	Reacts with waterSoluble in an aqueous solution of tartaric acid in hydrochloric acid and chloroformSoluble in hydrochloric acid, chloroform, carbon tetrachlorideSoluble in HCl, chloroform, carbon tetrachlorideMiscible with chloroform, hydrochloric acid, tartaric acid, carbon disulfide and carbon tetrachloride.Soluble in water (react), chloroform, hydrochloric acid, and carbon tetrachloride.
Corrosivity	Causes corrosion of metal
Siedepunkt	347 °F at 760 mmHg (est.) (USCG, 1999)140 °CBP: 69 °C at 18 mm Hg79 °C at 22 mm Hg92 °C at 30 mm Hg85 °C at 55 mm Hg102.5 °C at 68 mm HgBoiling point: 68 °C at 1.82 kPa. Decomposes at atmospheric pressure, 101.3 kPa92 °C30 mm Hg(lit.)
Decomposition	Decomposed by excess water into hydrochloric acid and antimony pentoxide.When heated to decomp it emits very toxic fumes of /hydrogen chloride/ and antimony.
Schmelzpunkt	37 °F (USCG, 1999)4 °C2.8 °C(lit.)
Dampfdruck	1.0 [mmHg]1 mm Hg at 22.7 °C1 [mm Hg] @22.7 °C0.13 psi ( 55 °C)
Brechungsindex	Index of refraction: 1.5925 at 22 °C1.601
Dampfdichte	>10.2 (vs air)
Flammpunkt	79°C/22mm
Lagerbedingungen	2-30°C
Aggregatzustand	Liquid
Wichte	2.336
Farbe	Red-yellow
Geruch	offensive odor
Merck	14,695
Dielektrizitätskonstante	3.2200000000000002
Stabilität	Stable, but reacts with moisture and water. Releases highly toxic fumes if involved in a fire.
InChI	1S/5ClH.Sb/h5*1H/q+5/p-5
InChIKey	VMPVEPPRYRXYNP-UHFFFAOYSA-I
SMILES	Cl[Sb](Cl)(Cl)(Cl)Cl
CAS Datenbank	7647-18-9(CAS DataBase Reference)
EPA chemische Informationen	Antimony pentachloride (7647-18-9)

Sicherheit & Vorschriften

GHS-Einstufung	DangerH314: Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]P260, P264, P273, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P363, P391, P405, and P501 (click each P-code to see the statement)H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]
Regulatorische Informationen	Chemical: Antimony chloride (SbCl5)Antimony chloride (SbCl5) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Antimony chloride (SbCl5) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)Status: Active Update: 16-05-2018 https://echa.europa.eu/registration-dossier/-/registered-dossier/24161Antimony (V) chloride: Does not have an individual approval but may be used under an appropriate group standardThe New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)
DOT-Kennzeichnung	Corrosive
Brandgefahren	Behavior in Fire: Irritating fumes of hydrogen chloride given off when water or foam is used to extinguish adjacent fire. (USCG, 1999)Excerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]:· Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Brandpotenzial	Not combustible
Gesundheitsgefahren	Inhalation causes irritation of nose and throat. Contact of liquid with eyes or skin causes severe burns. Ingestion causes vomiting and severe burns of mouth and stomach. Overexposure by any route can cause bloody stools, slow pulse, low blood pressure, coma, convulsions, cardiac arrest. (USCG, 1999)Excerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]:· TOXIC and/or CORROSIVEinhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death.

Anwendungen & Verwendung

Verwenden

Antimony(V) chloride is used as a catalyst and an analytical reagent for testing alkaloids and cesium. It is also used as a polymerization catalyst as well as involved in the chlorination of organic compounds. It acts as a Lewis acid and a strong oxidizing agent.