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Kaliumsulfat

Potassium Sulfate

HCID 24507
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Grundinformationen

CAS
7778-80-5
Standard-SMILES
O=S(=O)([O-])[O-].[K+].[K+]
InChIKey
OTYBMLCTZGSZBG-UHFFFAOYSA-L
Summenformel
K2SO4
Durchschnittliche Molmasse
174,26 g/mol
Monoisotopische Masse
173,87914284

Überblick

Potassium sulfate is an inorganic potassium salt and a potassium salt.

Namen und Bezeichner

Bevorzugter Name
Potassium Sulfate
IUPAC
dipotassium;sulfate
Lokaler Name
Kaliumsulfat
Englischer Name
Potassium sulfate
Summenformel
K2O4S
Molmasse
174.2592

Namen und Synonyme

POTASSIUM SULFATE7778-80-5Dipotassium sulfatePotassium sulphateSulfuric acid dipotassium saltArcanum duplicatumSulfuric acid, dipotassium saltKalium sulphuricumTartarus vitriolatusKali sulphuricumPotassium sulfate (K2(SO4))K2SO4
Weitere Namen anzeigen
sop231-915-5KSOKso4KSO2KH2PO25WATER R PHEKaliumsulfat
Sulfuric acid potassium salt (1:2)1K573LC5TVPotassium (as sulfate)DTXSID6029701INS NO.515(I)INS-515(I)E-515(I)CHEBI:32036

Datenbank-Bezeichner

CAS
7778-80-5、10233-01-9
PubChem CID
24507
DTXSID
DTXSID6029701
ChEMBL
CHEMBL2021424
ChEBI
CHEBI:32036
UNII
1K573LC5TV
EC Number
231-915-5
Nikkaji
J43.949E

Eigenschaften

Berechnete StruktureigenschaftenWird ergänzt

Polarare Oberfläche (TPSA)
88,6 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
4
Frei drehbare Bindungen
0
Schwere Atome
7
Formalladung
0
Komplexität
62,2

Experimentelle und physikochemische Eigenschaften

Chemical ClassesMetals -> Metals, Inorganic Compounds
CosmeticsViscosity controlling; Bulking
pH · 2 Einträge

Between 5,5 and 8,5 (5 % solution)

AQ SOLN IS NEUTRAL; PH ABOUT 7

SpringerMaterials Propertiesdielectric constant
OdorODORLESS
TasteHARD, BITTER, SALINE TASTE
Food AdditivesFLAVOR ENHANCER, FLAVORING AGENT OR ADJUVANT, MALTING OR FERMENTING AID -> FDA Substance added to food
Density · 3 Einträge

2.66

2.66 g/cm³

2.66 @25 °C

Color/Form · 2 Einträge

COLORLESS OR WHITE CRYSTALS, OR WHITE GRANULES OR POWDER

COLORLESS, RHOMBIC OR HEXAGONAL CRYSTALS

Solubility · 5 Einträge

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

GHS-Klassifizierung

GHS Classification · 5 Einträge

This chemical does not meet GHS hazard criteria for 89% (517 of 581) of all reports.

Danger

H318 (10.2%): Causes serious eye damage [Danger Serious eye damage/eye irritation]

P264+P265, P280, P305+P354+P338, and P317 (click each P-code to see the statement)

Aggregated GHS information provided per 581 reports by companies from 9 notifications to the ECHA C&L Inventory.

Gefahrenhinweise

Regulatory Information · 5 Einträge

Chemical: Sulfuric acid, dipotassium salt

Regulation (EC) No 1333/2008 (amended)

Sulfuric acid potassium salt (1:2) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Sulfuric acid potassium salt (1:2) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 01-02-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/15527

Dipotassium sulphate: Non hazardous

Other Safety InformationIMAP assessments - Sulfuric acid, dipotassium salt: Human health tier I assessment
Fire HazardsNot combustible.
Hazards SummaryA mild skin, eye, and respiratory tract irritant; [ICSC] A mild skin irritant; [eChemPortal: ERMA] May cause irritation; [MSDSonline]
EPA Safer ChemicalChemical: Potassium sulfate
Chemical DangersDecomposes on heating. This produces sulfur oxides.

Chemie und Industrie

Pharmakologische Informationen

Mechanism of Action · 1 Eintrag

Potassium is the major cation (positive ion) inside animal cells, while sodium is the major cation outside animal cells. The concentration differences of these charged particles causes a difference in electric potential between the inside and outside of cells, known as the membrane potential. The balance between potassium and sodium is maintained by ion pumps in the cell membrane. The cell membrane potential created by potassium and sodium ions allows the cell generate an action potential—a "spike" of electrical discharge. The ability of cells to produce electrical discharge is critical for body functions such as neurotransmission, muscle contraction, and heart function. Potassium is also an essential mineral needed to regulate water balance, blood pressure and levels of acidity.

FDA Pharmacological Classification · 6 Einträge

KALI SULPHURICUM

Increased Large Intestinal Motility [PE]; Potassium Salt [EPC]; Potassium Compounds [CS]; Osmotic Laxative [EPC]; Inhibition Large Intestine Fluid/Electrolyte Absorption [PE]; Osmotic Activity [MoA]

POTASSIUM SULFATE

Inhibition Large Intestine Fluid/Electrolyte Absorption [PE]; Osmotic Activity [MoA]; Potassium Compounds [CS]; Osmotic Laxative [EPC]; Increased Large Intestinal Motility [PE]; Potassium Salt [EPC]

KALI SULPH

Inhibition Large Intestine Fluid/Electrolyte Absorption [PE]; Osmotic Activity [MoA]; Increased Large Intestinal Motility [PE]; Potassium Salt [EPC]; Potassium Compounds [CS]; Osmotic Laxative [EPC]

Absorption, Distribution and ExcretionMostly urine but also skin and feces.

Verwendung und Herstellung

Uses · 5 Einträge

Used in gypsum cements, to make alum and glass, as a food additive, in fertilizers, as an accelerator in wallboard, as an expansion control agent for dental materials, as a medical and veterinary cathartic, and as a veterinary sulfate source; [HSDB]

Cement Producing [Category: Industry]

REAGENT IN ANALYTICAL CHEMISTRY; MEDICINE; GYPSUM CEMENTS; ALUM MFR; FOOD ADDITIVE

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Freely soluble in water, insoluble in ethanol

ITS SOLUBILITY IN WATER IS DECR BY KCL OR (NH4)2SO4

1 G DISSOLVES IN: 8.3 ML WATER, 4 ML BOILING WATER, 75 ML GLYCEROL; PRACTICALLY INSOL IN SATURATED SOLN OF AMMONIUM SULFATE; INSOL IN ALC

INSOL IN ACETATE, CARBON DISULFIDE

Solubility in water, g/100ml at 25 °C: 12

Human Drugs · 2 Einträge

FDA approved drugs -> Active ingredient

FDA approved drugs -> Active ingredient

Boiling Point · 3 Einträge

1689 °C

1689 °C

1689 °C @760 [mm Hg]

Physikochemische Eigenschaften

Schmelzpunkt
1067 °C · 1067°C
Siedepunkt
1689 °C · 1689°C
Dichte
2.66 · 2.66
Flammpunkt
1689 °C · 1689°C
storage temp.
Inert atmosphere,Room Temperature
Löslichkeit
2 O: · H2O: 0.5 M at 20 °C, clear, colorless
Aggregatzustand
Very Fine Crystals or Powder
Farbe
White
Wichte
2.662 · 2.662
Geruch (Odor)
Odorless
PH
5.5 · 5.5-7.5 (25℃, 0.5M in H2O)
Biologische Quelle
synthetic
Wasserlöslichkeit
110 g/L · 110 g/L (20 ºC)
Spezifische Wärmekapazität
0.75 J/ · Cp(crystal): 0.75 J/(g·K), at 25℃
Merck
14 · 14,7674
Dielectric constant
5.9 · 5.9(0.0℃)
Stabilität
Stable.
Kosmetik-Inhaltsstoffe Funktionen
VISCOSITY CONTROLLING
InChI
1S/2K.H2O4S/c;;1-5(2,3)4/h;;(H2,1,2,3,4)/q2*+1;/p-2
InChIKey
OTYBMLCTZGSZBG-UHFFFAOYSA-L
SMILES
[K+].[K+].[O-]S([O-])(=O)=O
CAS Datenbank
7778 · 7778-80-5(CAS DataBase Reference)
NIST chemische Informationen
Potassium sulfate(7778-80-5)
EPA chemische Informationen
Potassium sulfate (7778-80-5)
Hazard Classes and Categories
Eye Dam. 1 (10.2%)
State Drinking Water Standards · 2 Einträge

(AL) ALABAMA 500,000 ug/l /Sulfate ion/

(UT) UTAH 1,000,000 ug/l /Sulfate ion/

State Drinking Water Guidelines · 2 Einträge

(CA) CALIFORNIA 250 ug/l (Recommended); 500 ug/l (Upper); Short-term 600 ug/l /Sulfate ion/

(UT) UTAH 500,000 ug/l /Sulfate ion/

Federal Drinking Water GuidelinesEPA 250,000 ug/l /Sulfate ion/

Sicherheit und Schutzausrüstung

Fire FightingIn case of fire in the surroundings, use appropriate extinguishing media.
First Aid Measures · 4 Einträge

Fresh air, rest.

Rinse and then wash skin with water and soap.

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Give one or two glasses of water to drink.

Spillage DisposalSweep spilled substance into covered containers. Personal protection: particulate filter respirator adapted to the airborne concentration of the substance.
Eye PreventionWear safety goggles.
Inhalation RiskEvaporation at 20 °C is negligible; a nuisance-causing concentration of airborne particles can, however, be reached quickly when dispersed, especially if powdered.
Skin PreventionProtective gloves.
Ingestion PreventionDo not eat, drink, or smoke during work.
Inhalation PreventionUse local exhaust.
Effects of Short Term ExposureThe substance is mildly irritating to the eyes, skin and respiratory tract.
Protective Action Criteria (PAC) · 3 Einträge

30 [mg/m3]

220 [mg/m3]

1300 [mg/m3]

Toxikologische Informationen

Signs and Symptoms · 4 Einträge

Cough. Sore throat.

Redness.

Redness. Pain.

Abdominal pain. Diarrhoea. Nausea. Vomiting.

Human Toxicity ExcerptsSWALLOWING LARGE DOSES CAUSES SEVERE GI IRRITATION.
Non-Human Toxicity Excerpts · 1 Eintrag

CATTLE WHICH BROKE INTO FIELD WHICH HAD BEEN TREATED WITH POTASSIUM SULFATE DIED WITHIN 2 DAYS, SHOWING SYMPTOMS OF PROSTRATION, PARESIS, HYPOTHERMIA, CESSATION OF RUMINATION & CONSTIPATION. ONLY LESION SEEN @ POST MORTEM WAS CONGESTION OF MUCOUS MEMBRANE OF ABOMASUM & INTESTINES...

Regulatorische Informationen

State Drinking Water Standards · 2 Einträge

(AL) ALABAMA 500,000 ug/l /Sulfate ion/

(UT) UTAH 1,000,000 ug/l /Sulfate ion/

State Drinking Water Guidelines · 2 Einträge

(CA) CALIFORNIA 250 ug/l (Recommended); 500 ug/l (Upper); Short-term 600 ug/l /Sulfate ion/

(UT) UTAH 500,000 ug/l /Sulfate ion/

Federal Drinking Water GuidelinesEPA 250,000 ug/l /Sulfate ion/

Sicherheitsdaten

wgk
1
tsca
TSCA listed
hs_code
31043000
RTECS-Nr.
TT5900000
Toxizität
LD50 orally in Rabbit: 6600 mg/kg
safety_code
22-24/25
Speicherklasse
13 - Non Combustible Solids
Giftige Stoffe Daten
7778-80-5(Hazardous Substances Data)

(VET): CATHARTIC, SULFATE SOURCE

FERTILIZER FOR CHLORIDE-SENSITIVE CROPS (EG, TOBACCO); ACCELERATOR IN WALLBOARD (CONSTRUCTION INDUSTRY); AGENT IN MFR OF GLASS; CATHARTIC IN HUMAN MEDICINE; WATER-CORRECTIVE AGENT FOR FOODS (EG, BREWERY WATER); SETTING-EXPANSION CONTROL AGENT FOR DENTAL MATERIALS

U.S. Exports · 3 Einträge

(1978) 2.30X10+10 GRAMS

(1979) 2.24X10+10 GRAMS

(1985) 5.53x10+10 g

U.S. Imports · 3 Einträge

(1977) 6.90X10+10 GRAMS

(1979) 2.02X10+10 GRAMS

(1985) 4.88X10+10 g

U.S. Production · 4 Einträge

2023: 100,000,000 - <250,000,000 lb

(1977) 4.64X10+10 GRAMS (CONSUMPTION)

(1979) 4.11X10+10 GRAMS (CONSUMPTION)

(1985) 2.10X10+11 g

Consumption Patterns · 3 Einträge

Agriculture, 63%; exports, 36%; other, 1% (1984)

CHEMICAL PROFILE: Potassium Sulfates. Fertilizer (mainly for non-grain or specialty crops), 56%; exports, 41%; other, 3%. /Potassium sulfates/

CHEMICAL PROFILE: Potassium sulfates. Demand: 1987: 227,600 tons K2O; 1988: 235,000 tons K2O; 1992 /projected/: 280,000 tons K2O. (Does not include imports, which totaled 30,000 tons K2O in 1987.) /Potassium sulfates/

Consumer UsesOther
Industry UsesSoil amendments (fertilizers)
Methods of Manufacturing · 3 Einträge

REACTION OF POTASSIUM CHLORIDE WITH LANGBEINITE ORE, SCHOENITE OBTAINED FROM KAINITE ORE, OR SODIUM SULFATE (GLASERITE IS AN ISOLATED INTERMEDIATE); REACTION OF POTASSIUM CHLORIDE WITH SULFURIC ACID OR SULFUR DIOXIDE, WATER AND OXYGEN; RECOVERY FROM SUGAR WASTES

(A) BY TREATMENT OF POTASSIUM CHLORIDE EITHER WITH SULFURIC ACID OR WITH SULFUR DIOXIDE, AIR, & WATER (HARGREAVES PROCESS). (B) BY FRACTIONAL CRYSTALLIZATION OF NATURAL SULFATE ORE; (C) FROM SALT LAKE BRINES.

THE POTASSIUM SALT OF SULFURIC ACID. ...FIRST POTASH SALT PRODUCED COMMERCIALLY IN US FROM ANYTHING OTHER THAN WOOD ASHES. IT WAS PRODUCED FROM ALUNITE. SULFATE HAS ALSO BEEN MADE FROM CEMENT MILL DUST, LANGBEINITE, & FROM MURIATE BY TREATMENT WITH SODIUM OR MAGNESIUM SULFATE OR WITH SULFURIC ACID.

Formulations/Preparations · 2 Einträge

GRADES: HIGHEST PURITY MEDICINAL; COMMERCIAL; CRUDE; CP; AGRICULTURAL

Commercial potassium sulfate contains not less than 48% soluble potash (K2O) chiefly as sulfate, and not more than 2.5% chlorine

Household ProductsInformation on 101 consumer products that contain Potassium sulfate in the following categories is provided:
Use Classification · 5 Einträge

EPA Safer Chemical Functional Use Classes -> Processing Aids and Additives

Safer Chemical Classes -> Green circle - The chemical has been verified to be of low concern

Food additives

Food Additives -> FLAVOUR_ENHANCER; SALT_SUBSTITUTE -> JECFA Functional Classes

Cosmetics -> Viscosity controlling; Bulking

General Manufacturing Information · 6 Einträge

Not Known or Reasonably Ascertainable

Sulfuric acid potassium salt (1:2): ACTIVE

Sulfuric acid, potassium salt (1:?): ACTIVE

TECHNICAL GRADES ARE USED IN FERTILIZERS FOR MFR OF POTASSIUM ALUM, POTASSIUM CARBONATE & GLASS; THE REAGENT GRADE IS USED IN THE KJELDAHL DETERMINATION OF NITROGEN.

VET: RARE, AS LAXATIVE, AS IT IS MORE IRRITANT THAN SODIUM OR MAGNESIUM SULFATES. OCCASIONALLY USED IN WATER SOL TRACE MINERAL MIXES AS SOURCE OF POTASSIUM (44.8%) & AS AN ORAL SULFATE SOURCE IN RUMINANT EXPT.

VET: IT IS OF POTENTIAL VALUE AS SULFATE SOURCE, WHICH MAY REDUCE METHIONINE REQUIREMENTS OF POULTRY. A 0.1% LEVEL IN FEED OF LAYING HENS WAS ASSOCIATED WITH A 5% INCR IN EGG PRODUCTION.

Anwendungen · 4 Einträge

BeschreibungPotassium sulfate (K2SO4) is a kind of chemical compounds that is commonly used in agriculture. The dominant application of potassium sulfate is as a fertilizer, which is commonly applied to offer both potassium and sulfur, thus improving the quality and yield of crops growing in soils that lack an adequate supply of this essential elements. Besides, the crude potassium sulfate is sometimes employed in the production of glass. It also has applications in other industries, which is used as a flash reducer in artillery propellant charges and as an alternative blast media similar to soda in the process of soda blasting. potassium sulfate powder

OccurrencePotassium and sodium sulfates and their double sulfates with calcium and magnesium occur naturally in various salt lakes. Potassium sulfate also occurs in certain volcanic lava. Its double salt with magnesium occurs in nature, as the mineral langbeinite.Potassium sulfate is used in fertilizers as a source of potassium and sulfur, both of which are essential elements for plant growth. Either in sim-ple form or as a double salt with magnesium sulfate, potassium sulfate is one of the most widely consumed potassium salts in agricultural applications. It is preferred over potassium chloride for certain types of crops; such as, tobac-co, citrus, and other chloride-sensitive crops. Some other applications include making gypsum cements; to make potassium alum; in the analysis of Kjeldahl nitrogen; and in medicine.

HistoryPotassium sulfate has been known since the early 14th century. It was studied by Glauber, Boyle, and Tachenius. In the 17th century, it was named arcanuni or sal duplicatum, as it was a combination of an acid salt with an alkaline salt. It was also known as vitriolic tartar and Glaser's salt or sal polychrestum Glaseri after the pharmaceutical chemist Christopher Glaser, who prepared and used it medicinally. From the early to mid-19th century, as understanding of plant nutritional requirements deepened and the fertilizer industry emerged, potassium sulphate began to be produced on a large scale as a vital potash fertiliser.

Verwendenpotassium sulfate is a reagent in cosmetics. Potassium sulfate is an inorganic salt with a primary function as a viscosity-increasing agent.

Vor- und nachgelagerte Produkte

Vorgelagerte Rohstoffe

KaliumhydroxidKaliumcarbonatHydrogenchloridaluniteMagnesiumsulfatKaliumchloridOctadecylaminAmmoniumsulfatMagnesium sulfate heptahydrateSchwefelsure

Nachgelagerte Produkte

Compound fertilizerAluminium potassium sulfate dodecahydrateethyl 3-ethylpyrazolyl-5-carboxylate4-HydroxybenzoesureAcenaphthylen2-Propenal4-[2-(Diethylamino)ethoxy]benzophenonNitrogen phosphorus potassium mixed fertilizerDikaliumdisulfatNitrogen-Phosphorus-Potassium compound fertilizer with sulphurCalcium phosphate monobasicNicosulfuronN-1,3-Dimethylbutyl-N'-phenyl-p-phenylendiaminKaliumhydrogencarbonatMixed and compound fertilizerPOTASSIUM METABISULFITEBrenztraubensureKaliumbromatCalciumhydrogenorthophosphatalpha-D-Glucopyranose 1-phosphate dipotassium salt hydrateDikaliumperoxodisulfatAmmoniumchromatCompound fertilizer of potassium sulfatepolyhaliteChrom (III) oxidCompound fertilizer,high concentrationL-MethioninWater flush fertilizer
Ergänzende Hinweise · 1 Eintrag

DefinitionPotassium sulfate is a potassium salt and an inorganic potassium salt. It is a white crystalline powder, K2SO4, soluble inwater and insoluble in ethanol;rhombic or hexagonal; r.d. 2.66; m.p.1069°C. It occurs naturally assch nite (Strassfurt deposits) and inlake brines, from which it is separatedby fractional crystallization. Ithas also been produced by the Hargreavesprocess, which involves theoxidation of potassium chloride withsulphuric acid. In the laboratory itmay be obtained by the reaction ofeither potassium hydroxide or potassiumcarbonate with sulphuric acid.Potassium sulphate is used in cements,in glass manufacture, as a food additive, and as a fertilizer(source of K+) for chloride-sensitiveplants, such as tobacco and citrus.