Grundinformationen
- Standard-SMILES
O=S(=O)([O-])[O-].[K+].[K+]- InChIKey
OTYBMLCTZGSZBG-UHFFFAOYSA-L- Summenformel
- K2SO4
- Durchschnittliche Molmasse
- 174,26 g/mol
- Monoisotopische Masse
- 173,87914284
Überblick
Potassium sulfate is an inorganic potassium salt and a potassium salt.
Namen und Bezeichner
- Bevorzugter Name
- Potassium Sulfate
- IUPAC
- dipotassium;sulfate
Namen und Synonyme
Weitere Namen anzeigen
Datenbank-Bezeichner
- CAS
7778-80-5、10233-01-9- PubChem CID
- 24507
- DTXSID
DTXSID6029701- ChEMBL
CHEMBL2021424- ChEBI
CHEBI:32036- UNII
- 1K573LC5TV
- EC Number
- 231-915-5
- Nikkaji
- J43.949E
Eigenschaften
Berechnete Struktureigenschaften
- Polarare Oberfläche (TPSA)
- 88,6 Ų
- H-Brücken-Donoren
- 0
- H-Brücken-Akzeptoren
- 4
- Frei drehbare Bindungen
- 0
- Schwere Atome
- 7
- Formalladung
- 0
- Komplexität
- 62,2
Experimentelle und physikochemische Eigenschaften
pH
Between 5,5 and 8,5 (5 % solution)
AQ SOLN IS NEUTRAL; PH ABOUT 7
Density
2.66
2.66 g/cm³
2.66 @25 °C
Color/Form
COLORLESS OR WHITE CRYSTALS, OR WHITE GRANULES OR POWDER
COLORLESS, RHOMBIC OR HEXAGONAL CRYSTALS
Solubility
Freely soluble in water, insoluble in ethanol
ITS SOLUBILITY IN WATER IS DECR BY KCL OR (NH4)2SO4
1 G DISSOLVES IN: 8.3 ML WATER, 4 ML BOILING WATER, 75 ML GLYCEROL; PRACTICALLY INSOL IN SATURATED SOLN OF AMMONIUM SULFATE; INSOL IN ALC
INSOL IN ACETATE, CARBON DISULFIDE
Solubility in water, g/100ml at 25 °C: 12
Human Drugs
FDA approved drugs -> Active ingredient
FDA approved drugs -> Active ingredient
Boiling Point
1689 °C
1689 °C
1689 °C @760 [mm Hg]
Sicherheit und Regulatorisches
GHS-Klassifizierung
GHS Classification
This chemical does not meet GHS hazard criteria for 89% (517 of 581) of all reports.
Danger
H318 (10.2%): Causes serious eye damage [Danger Serious eye damage/eye irritation]
P264+P265, P280, P305+P354+P338, and P317 (click each P-code to see the statement)
Aggregated GHS information provided per 581 reports by companies from 9 notifications to the ECHA C&L Inventory.
Gefahrenhinweise
Regulatory Information
Chemical: Sulfuric acid, dipotassium salt
Regulation (EC) No 1333/2008 (amended)
Sulfuric acid potassium salt (1:2) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Sulfuric acid potassium salt (1:2) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
Status: Active Update: 01-02-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/15527
Dipotassium sulphate: Non hazardous
State Drinking Water Standards
(AL) ALABAMA 500,000 ug/l /Sulfate ion/
(UT) UTAH 1,000,000 ug/l /Sulfate ion/
State Drinking Water Guidelines
(CA) CALIFORNIA 250 ug/l (Recommended); 500 ug/l (Upper); Short-term 600 ug/l /Sulfate ion/
(UT) UTAH 500,000 ug/l /Sulfate ion/
Sicherheit und Schutzausrüstung
First Aid Measures
Fresh air, rest.
Rinse and then wash skin with water and soap.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Give one or two glasses of water to drink.
Protective Action Criteria (PAC)
30 [mg/m3]
220 [mg/m3]
1300 [mg/m3]
Toxikologische Informationen
Signs and Symptoms
Cough. Sore throat.
Redness.
Redness. Pain.
Abdominal pain. Diarrhoea. Nausea. Vomiting.
Non-Human Toxicity Excerpts
CATTLE WHICH BROKE INTO FIELD WHICH HAD BEEN TREATED WITH POTASSIUM SULFATE DIED WITHIN 2 DAYS, SHOWING SYMPTOMS OF PROSTRATION, PARESIS, HYPOTHERMIA, CESSATION OF RUMINATION & CONSTIPATION. ONLY LESION SEEN @ POST MORTEM WAS CONGESTION OF MUCOUS MEMBRANE OF ABOMASUM & INTESTINES...
Regulatorische Informationen
State Drinking Water Standards
(AL) ALABAMA 500,000 ug/l /Sulfate ion/
(UT) UTAH 1,000,000 ug/l /Sulfate ion/
State Drinking Water Guidelines
(CA) CALIFORNIA 250 ug/l (Recommended); 500 ug/l (Upper); Short-term 600 ug/l /Sulfate ion/
(UT) UTAH 500,000 ug/l /Sulfate ion/
Chemie und Industrie
Pharmakologische Informationen
Mechanism of Action
Potassium is the major cation (positive ion) inside animal cells, while sodium is the major cation outside animal cells. The concentration differences of these charged particles causes a difference in electric potential between the inside and outside of cells, known as the membrane potential. The balance between potassium and sodium is maintained by ion pumps in the cell membrane. The cell membrane potential created by potassium and sodium ions allows the cell generate an action potential—a "spike" of electrical discharge. The ability of cells to produce electrical discharge is critical for body functions such as neurotransmission, muscle contraction, and heart function. Potassium is also an essential mineral needed to regulate water balance, blood pressure and levels of acidity.
FDA Pharmacological Classification
KALI SULPHURICUM
Increased Large Intestinal Motility [PE]; Potassium Salt [EPC]; Potassium Compounds [CS]; Osmotic Laxative [EPC]; Inhibition Large Intestine Fluid/Electrolyte Absorption [PE]; Osmotic Activity [MoA]
POTASSIUM SULFATE
Inhibition Large Intestine Fluid/Electrolyte Absorption [PE]; Osmotic Activity [MoA]; Potassium Compounds [CS]; Osmotic Laxative [EPC]; Increased Large Intestinal Motility [PE]; Potassium Salt [EPC]
KALI SULPH
Inhibition Large Intestine Fluid/Electrolyte Absorption [PE]; Osmotic Activity [MoA]; Increased Large Intestinal Motility [PE]; Potassium Salt [EPC]; Potassium Compounds [CS]; Osmotic Laxative [EPC]
Verwendung und Herstellung
Uses
Used in gypsum cements, to make alum and glass, as a food additive, in fertilizers, as an accelerator in wallboard, as an expansion control agent for dental materials, as a medical and veterinary cathartic, and as a veterinary sulfate source; [HSDB]
Cement Producing [Category: Industry]
REAGENT IN ANALYTICAL CHEMISTRY; MEDICINE; GYPSUM CEMENTS; ALUM MFR; FOOD ADDITIVE
(VET): CATHARTIC, SULFATE SOURCE
FERTILIZER FOR CHLORIDE-SENSITIVE CROPS (EG, TOBACCO); ACCELERATOR IN WALLBOARD (CONSTRUCTION INDUSTRY); AGENT IN MFR OF GLASS; CATHARTIC IN HUMAN MEDICINE; WATER-CORRECTIVE AGENT FOR FOODS (EG, BREWERY WATER); SETTING-EXPANSION CONTROL AGENT FOR DENTAL MATERIALS
U.S. Exports
(1978) 2.30X10+10 GRAMS
(1979) 2.24X10+10 GRAMS
(1985) 5.53x10+10 g
U.S. Imports
(1977) 6.90X10+10 GRAMS
(1979) 2.02X10+10 GRAMS
(1985) 4.88X10+10 g
U.S. Production
2023: 100,000,000 - <250,000,000 lb
(1977) 4.64X10+10 GRAMS (CONSUMPTION)
(1979) 4.11X10+10 GRAMS (CONSUMPTION)
(1985) 2.10X10+11 g
Consumption Patterns
Agriculture, 63%; exports, 36%; other, 1% (1984)
CHEMICAL PROFILE: Potassium Sulfates. Fertilizer (mainly for non-grain or specialty crops), 56%; exports, 41%; other, 3%. /Potassium sulfates/
CHEMICAL PROFILE: Potassium sulfates. Demand: 1987: 227,600 tons K2O; 1988: 235,000 tons K2O; 1992 /projected/: 280,000 tons K2O. (Does not include imports, which totaled 30,000 tons K2O in 1987.) /Potassium sulfates/
Methods of Manufacturing
REACTION OF POTASSIUM CHLORIDE WITH LANGBEINITE ORE, SCHOENITE OBTAINED FROM KAINITE ORE, OR SODIUM SULFATE (GLASERITE IS AN ISOLATED INTERMEDIATE); REACTION OF POTASSIUM CHLORIDE WITH SULFURIC ACID OR SULFUR DIOXIDE, WATER AND OXYGEN; RECOVERY FROM SUGAR WASTES
(A) BY TREATMENT OF POTASSIUM CHLORIDE EITHER WITH SULFURIC ACID OR WITH SULFUR DIOXIDE, AIR, & WATER (HARGREAVES PROCESS). (B) BY FRACTIONAL CRYSTALLIZATION OF NATURAL SULFATE ORE; (C) FROM SALT LAKE BRINES.
THE POTASSIUM SALT OF SULFURIC ACID. ...FIRST POTASH SALT PRODUCED COMMERCIALLY IN US FROM ANYTHING OTHER THAN WOOD ASHES. IT WAS PRODUCED FROM ALUNITE. SULFATE HAS ALSO BEEN MADE FROM CEMENT MILL DUST, LANGBEINITE, & FROM MURIATE BY TREATMENT WITH SODIUM OR MAGNESIUM SULFATE OR WITH SULFURIC ACID.
Formulations/Preparations
GRADES: HIGHEST PURITY MEDICINAL; COMMERCIAL; CRUDE; CP; AGRICULTURAL
Commercial potassium sulfate contains not less than 48% soluble potash (K2O) chiefly as sulfate, and not more than 2.5% chlorine
Use Classification
EPA Safer Chemical Functional Use Classes -> Processing Aids and Additives
Safer Chemical Classes -> Green circle - The chemical has been verified to be of low concern
Food additives
Food Additives -> FLAVOUR_ENHANCER; SALT_SUBSTITUTE -> JECFA Functional Classes
Cosmetics -> Viscosity controlling; Bulking
General Manufacturing Information
Not Known or Reasonably Ascertainable
Sulfuric acid potassium salt (1:2): ACTIVE
Sulfuric acid, potassium salt (1:?): ACTIVE
TECHNICAL GRADES ARE USED IN FERTILIZERS FOR MFR OF POTASSIUM ALUM, POTASSIUM CARBONATE & GLASS; THE REAGENT GRADE IS USED IN THE KJELDAHL DETERMINATION OF NITROGEN.
VET: RARE, AS LAXATIVE, AS IT IS MORE IRRITANT THAN SODIUM OR MAGNESIUM SULFATES. OCCASIONALLY USED IN WATER SOL TRACE MINERAL MIXES AS SOURCE OF POTASSIUM (44.8%) & AS AN ORAL SULFATE SOURCE IN RUMINANT EXPT.
VET: IT IS OF POTENTIAL VALUE AS SULFATE SOURCE, WHICH MAY REDUCE METHIONINE REQUIREMENTS OF POULTRY. A 0.1% LEVEL IN FEED OF LAYING HENS WAS ASSOCIATED WITH A 5% INCR IN EGG PRODUCTION.
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