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Bismuttrichlorid
BiCl3 · BISMUTH(III) CHLORIDE · BISMUTH CHLORIDE · Trichlorobismuthane · Trichlorobismuth · Bismuth(III) chL · BISMUTH TRICHLORIDE · BISMUTH(+3)CHLORIDE
Identifikatoren & physikalische Daten
| CAS No. | 7787-60-2 |
|---|---|
| Summenformel | BiCl3 |
| Durchschnittliche Molmasse | 315,33 g/mol |
| Monoisotopische Masse | 313,88695674 g/mol |
| SMILES | [Cl][Bi]([Cl])[Cl] |
| InChIKey | JHXKRIRFYBPWGE-UHFFFAOYSA-K |
| PubChem CID | 24591 |
| EC No. | 232-123-2 |
| DTXSID | DTXSID3064851 |
| Lokaler Name | Bismuttrichlorid |
Chemische & physikalische Eigenschaften
| Polarare Oberfläche (TPSA) | 0 |
|---|---|
| H-Brücken-Donoren | 0 |
| H-Brücken-Akzeptoren | 0 |
| Frei drehbare Bindungen | 0 |
| Schwere Atome | 4 |
| Formalladung | 0 |
| Komplexität | 8 |
| Stoffklassen | Metals -> Metals, Inorganic Compounds |
| Physical Description | White to yellow deliquescent solid[Merck Index] Reacts with water to produce HCl[MSDSonline] |
| Schmelzpunkt | 230-232 °C(lit.) |
| Siedepunkt | 447 °C(lit.) |
| Dichte | 4.75 |
| Flammpunkt | 430°C |
| Lagerbedingungen | no restrictions. |
| Löslichkeit | Soluble in hydrochloric acid, nitric acid, diethyl ether, ethyl acetate and acetone. Insoluble in alcohol.decomposes |
| Aggregatzustand | powder |
| Farbe | White to beige or gray |
| Wichte | 4.75 |
| Geruch | Hydrochloric acid odor |
| Spezifische Wärmekapazität | Cp(crystal): 0.33 J/(g·K)Cp(gas): 0.25 J/(g·K), at 25℃ |
| Merck | 14,1262 |
| Stabilität | Stable, but reacts with water, moisture. |
| Hauptanwendungen | electroplatingmaterial synthesis precursorperovskite solar cells |
| InChI | 1S/Bi.3ClH/h3*1H/q+3/p-3 |
| InChIKey | JHXKRIRFYBPWGE-UHFFFAOYSA-K |
| SMILES | Cl[Bi](Cl)Cl |
| CAS Datenbank | 7787-60-2(CAS DataBase Reference) |
| NIST chemische Informationen | Bismuth trichloride(7787-60-2) |
| EPA chemische Informationen | Bismuthine, trichloro- (7787-60-2) |
Sicherheit & Vorschriften
| GHS-Einstufung | WarningH315 (96.2%): Causes skin irritation [Warning Skin corrosion/irritation]P264, P264+P265, P280, P302+P352, P305+P351+P338, P321, P332+P317, P337+P317, and P362+P364 (click each P-code to see the statement)Aggregated GHS information provided per 105 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies. |
|---|---|
| Regulatorische Informationen | Chemical: Bismuthine, trichloro-Bismuth trichloride: Does not have an individual approval but may be used under an appropriate group standard |
| Gefahrenübersicht | Corrosive[MSDSonline] See Bismuth. |
| Hazard Classes and Categories | Skin Irrit. 2 (96.2%) |
| Unerwünschte Wirkungen | Dermatotoxin - Skin burns. |
| Wassergefährdungsklasse (WGK) | 2 |
| TSCA-Inventar-Status | TSCA listed |
| UN-Transportnummer | 3260 |
| Zollcode | 2827 39 85 |
| RTECS-Nr. | EB2690000 |
| R-Sätze (R) | 36/38-36/37/38 |
| Toxizität | LD50 orally in Rabbit: 3334 mg/kg |
| Gefahrensymbole | Xi |
| Sicherheitshinweise (S) | 26-36-37/39 |
| Gefahrenklasse | 8Eye Irrit. 2Skin Irrit. 2 |
| Verpackungsgruppe | III |
| Lagerklasse | 11 - Combustible Solids |
Anwendungen & Verwendung
Verwenden
Bismuth trichloride used as catalyst for organic reactions.
Herstellung & Synthese
synthetische
Bismuth chloride may be synthesized directly by passing chlorine over bismuth. Alternatively, the chloride salt may be prepared by adding hydrochloric acid to basic bismuth chloride and evaporating the solution:Bi(OH)2Cl + 2HCl → BiCl3 + 2H2OAlso, the compound can be prepared by dissolving bismuth in concentrated nitric acid and then adding solid sodium chloride into this solution. Another method of preparation is treating the metal with concentrated hydrochloric acid:2Bi + 6HCl → 2BiCl3 + 3H2.