Hydrazine hydrate (1:1)

HCID 24654CAS 10217-52-4

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Grundinformationen

Standard-SMILES: NN.O
InChIKey: IKDUDTNKRLTJSI-UHFFFAOYSA-N
Summenformel: H4N2.H2O
Durchschnittliche Molmasse: 50,061 g/mol
Monoisotopische Masse: 50,04801281

Überblick

Hydrazine hydrate is a hydrate. It contains a hydrazine.

Namen und Bezeichner

Bevorzugter Name: Hydrazine hydrate (1:1)
IUPAC: hydrazine;hydrate
Englischer Name: Hydrazine hydrate
Summenformel: H4N2.H2O
Molmasse: 50.06

Namen und Synonyme

Hydrazine hydrate7803-57-8Hydrazine hydroxideHYDRAZINE, MONOHYDRATEIdrazina idrataKYD297831PHydrazine hydrate (1:1)DTXSID9037240CHEBI:35511Hydrazine, hydrate (6CI,7CI)RefChem:5889DTXCID7017240

Weitere Namen anzeigen

Diamid hydrateHydrazine, hydrate (1:1)DiamideHydrateDiamineHydrateidrazinaidrataJACS-7803-57-8HYDRAZINE1-HYDRATEhydrazinehydroxide

DTXSID901014833Hydrazinium hydroxideHydrazine monohydrate10217-52-4hydrazine;hydrateHydrazine, hydratehydraziniumhydroxideMFCD00149931

Datenbank-Bezeichner

CAS: 10217-52-4、7803-57-8
PubChem CID: 24654
DTXSID: DTXSID9037240
ChEBI: CHEBI:35511
UNII: KYD297831P
EC Number: 600-285-7、616-584-0

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA): 53 Å²
H-Brücken-Donoren: 3
H-Brücken-Akzeptoren: 3
Frei drehbare Bindungen: 0
Schwere Atome: 3
Formalladung: 0
Komplexität: 0

Experimentelle und physikochemische Eigenschaften

Chemical Classes · 2 Einträge

Nitrogen Compounds -> Hydrazines

Corrosives

Density1.03 @ 21°C

Boiling Point119 °C @760 [mm Hg]

Melting Point-51.7 °C

Physical Description · 2 Einträge

Liquid; Other Solid; Liquid

A colorless fuming liquid with a faint ammonia-like odor; Corresponds to a 64% aqueous solution of hydrazine in water; [CAMEO]

Physikochemische Eigenschaften

Schmelzpunkt: 51.7 °C · −51.7 °C(lit.)
Siedepunkt: 120.1 °C · 120.1 °C(lit.)
Dichte: 1.03 g/mL · 1.03 g/mL at 20 °C
Dampfdichte: 1 · >1 (vs air)
Dampfdruck: 5 mm · 5 mm Hg ( 25 °C)
Brechungsindex: 20 · n20/D 1.428(lit.)
Flammpunkt: 204 °F · 204 °F
storage temp.: 0 · 0-6°C
Löslichkeit: Acetonitrile (Sparingly), DMSO (Sparingly), Methanol (Slightly), Water (Sparingly)
pka: 8.2 · 8.20
Aggregatzustand: fuming liquid
Wichte: 1.032 · 1.032
Farbe: fuming liquid
PH: 10 · 10-11 (10g/l, H2O, 20℃)
Explosionsgrenze: 3.4 · >3.4-99%(V)
Wasserlöslichkeit: Soluble in chloroform, DMSO, methanol. Slightly soluble in water.
Merck: 14 · 14,4771
BRN: 878137 · 878137
Stabilität: Stability Incompatible with a wide variety of materials, including oxidizing agents, heavy metal oxides, dehydrating agents, alkali metals, rust, silver salts. Combustible. Contact with many materials may cause fire or explosive decomposition. May react explosively with a variety of materials, including dehydrating agents, heavy metal ox
InChI: 1S/H4N2.H2O/c1-2;/h1-2H2;1H2
InChIKey: IKDUDTNKRLTJSI-UHFFFAOYSA-N
SMILES: O.NN
CAS Datenbank: 7803 · 7803-57-8(CAS DataBase Reference)
EPA chemische Informationen: Hydrazine monohydrate (7803-57-8)

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 6 Einträge

This chemical does not meet GHS hazard criteria for 0.5% (1 of 214) of reports.

Danger

H226 (95.3%): Flammable liquid and vapor [Warning Flammable liquids]

P203, P210, P233, P240, P241, P242, P243, P260, P261, P262, P264, P264+P265, P270, P271, P272, P273, P280, P284, P301+P316, P301+P330+P331, P302+P352, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P317, P318, P320, P321, P330, P333+P317, P361+P364, P362+P364, P363, P370+P378, P391, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 214 reports by companies from 14 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

This chemical does not meet GHS hazard criteria for 11.1% (1 of 9) of reports.

Gefahrenhinweise

Regulatory Information · 5 Einträge

Chemical: Hydrazine, monohydrate

Hydrazine, monohydrate is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Hydrazine, monohydrate are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Hydrazine, monohydrate: HSNO Approval: HSR007167 Approved with controls

Hydrazine, monohydrate: Does not have an individual approval but may be used under an appropriate group standard

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

Other Safety InformationIMAP assessments - Hydrazine: Human health tier II assessment

Hazards Summary · 1 Eintrag

Corrosive to skin; [Quick CPC] Highly toxic by inhalation, ingestion, or skin absorption; [CAMEO] A very strong reducing agent and violent poison; May cause delayed eye irritation; [Merck Index] Causes methemoglobinemia and liver injury in 28-day oral study of rats at 30 mg/kg/day; [JECDB] Causes excitement and muscle contraction or spasticity in oral lethal-dose studies of guinea pigs, mice, rabbits, and rats; [RTECS] Causes burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; May cause skin sensitization; Toxic by ingestion, inhalation, and skin absorption; [Alfa Aesar MSDS] See Hydrazine.

Hazard Classes and Categories · 6 Einträge

Flam. Liq. 3 (44.4%)

Flam. Liq. 3 (95.3%)

Acute toxicity - category 3

Flammable liquids - Category 4

Carcinogenicity - Category 1B

Flammable liquids - Category 4

Sicherheit und Schutzausrüstung

Protective Action Criteria (PAC) · 3 Einträge

0.10 [ppm]

13 [ppm]

35 [ppm]

Toxikologische Informationen

Adverse EffectsNeurotoxin - Other CNS neurotoxin

Sicherheitsdaten

F: 23
wgk: 3
tsca: Yes
ridadr: UN 2030 8/PG I/II/III (HYDRAZINE AQUEOUS SOLUTION with more than 37 % hydrazine, by mass)
hs_code: 28251000
RTECS-Nr.: MV8050000
risk_code: 45-20/21/22-34-43-51/53-50/53-23/24/25-10
Toxizität: LD50 orally in Rabbit: 169 mg/kg
hazard_code: T,N
safety_code: 53-45-60-61-36/37/39-26
hazard_class: 8
packing_group: II
Speicherklasse: 3 - Flammable liquids
Hazard Classifications: Acute Tox. 2 InhalationAcute Tox. 3 DermalAcute Tox. 3 OralAquatic Acute 1Aquatic Chronic 1Carc. 1BEye Dam. 1Flam. Liq. 3Skin Corr. 1BSkin Sens. 1
Selbstentzündungstemperatur: 280 °C

Chemie und Industrie

Pharmakologische Informationen

MeSH Pharmacological Classification · 2 Einträge

Substances that inhibit or prevent the proliferation of NEOPLASMS.

Substances that increase the risk of NEOPLASMS in humans or animals. Both genotoxic chemicals, which affect DNA directly, and nongenotoxic chemicals, which induce neoplasms by other mechanism, are included.

Verwendung und Herstellung

UsesUsed as a reducing agent and solvent for organic materials; Also used to make Helman catalyst (80% hydrazine hydrate that is used in V-2 type rockets) and mixed with methanol for rocket engine propulsion; [Merck Index]

U.S. Production2023: 75,000 - <500,000 lb

Consumer UsesIntermediate

Industry UsesIntermediate

General Manufacturing InformationPesticide, Fertilizer, and Other Agricultural Chemical Manufacturing

Anwendungen · 1 Eintrag

VerwendenHydrazine hydrate is used as a reducing agent in synthetic and analytical reactions and as a solvent for many inorganic compounds. It also is used with methanol as a propellant for rocket engines. Another application is catalytic decomposition of hydrogen peroxide.

Darstellung · 1 Eintrag

synthetischeHydrazine hydrate is prepared by treating hydrazine sulfate, N2H4•H2SO4 with sodium hydroxide. The product is collected by distillation under nitrogen. It also is obtained as a by-product in the Bayer Ketazine process for producing hydrazine in which hydrazine solution is hydrolysed under pressure in a ketazine column.