Magnesiumperchlorat

anhydrous magnesium · XKM 300 · KhKM 300 · ANHYDRONE · dehydrite · ANHYDRONE(R) · nesium perchL · Magnesium perchL

https://huagongshe.com/de/chemical/24840

Identifikatoren & physikalische Daten

CAS No.	10034-81-8
Summenformel	Mg(ClO4)2
Durchschnittliche Molmasse	223,2 g/mol
Monoisotopische Masse	221,88206402 g/mol
SMILES	[Mg+2].[O-][Cl+3]([O-])([O-])[O-].[O-][Cl+3]([O-])([O-])[O-]
InChIKey	MPCRDALPQLDDFX-UHFFFAOYSA-L
PubChem CID	24840
ChEBI	CHEBI:184579
EC No.	233-108-3
DTXSID	DTXSID70890617
Lokaler Name	Magnesiumperchlorat

Chemische & physikalische Eigenschaften

Polarare Oberfläche (TPSA)	149
H-Brücken-Donoren	0
H-Brücken-Akzeptoren	8
Frei drehbare Bindungen	0
Schwere Atome	11
Formalladung	0
Komplexität	95,8
Stoffklassen	Other Classes -> Perchlorates
Geruch	Odorless
Dichte	2.21 at 68 °F (USCG, 1999) - Denser than waterwill sinkDensity = 1.98decomposes at 185-190 °C /Hexahydrate/2.2 @25 °C2,21 g/cm3
Color/Form	White, granular, or flaky powder
Löslichkeit	99.3 G/100 CC OF H20 & 23.96 G/100 CC OF ALCOHOL, EACH AT 25 °CEthanol (Slightly), Water (Slightly)Magnesium perchlorate is soluble in water, ethanol.
Siedepunkt	Decomposes above 482.0 °F (USCG, 1999)
Decomposition	When heated to decomposition it emits toxic fumes of /magnesium oxide and hydrogen chloride/./Decomposes/ above 250 °C.
Schmelzpunkt	Decomposes at 250 °C251 °C
Physical Description	Magnesium perchlorate appears as a white crystalline solid. Strongly absorbs water from air and dissolves in it. Accordingly, used as a regenerable drying agent. May explode under prolonged exposure to heat or fire.White deliquescent solid[CAMEO] Odorless[HSDB] White odorless granules[Alfa Aesar MSDS]
Other Experimental Properties	Crystallizes from water with 6H2Overy hygroscopicdecomposes above 250 °Cdissolves in water with evolution of considerable amount of heatOxidizing agentHeat of solution: -260 Btu/lb= -140 cal/g= -6.0X10+5 J/kg
Dampfdruck	0Pa at 25℃
Lagerbedingungen	Hygroscopic, Room Temperature, Under inert atmosphere
Aggregatzustand	Solid
Wichte	2.21
Farbe	White
Merck	14,5678
Stabilität	Stable, but moisture sensitive. Oxidizer - contact with combustible material may lead to fire. Incompatible with reducing agents, organic materials, trimethyl phosphate, powdered metals, strong acids, phosphorus.
InChI	1S/2ClHO4.Mg/c22-1(3,4)5/h2(H,2,3,4,5)/q+2/p-2
InChIKey	MPCRDALPQLDDFX-UHFFFAOYSA-L
SMILES	[Mg++].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O
LogP (Verteilungskoeffizient)	-6.53 at 25℃
CAS Datenbank	10034-81-8(CAS DataBase Reference)
EPA chemische Informationen	Perchloric acid, magnesium salt (2:1) (10034-81-8)

Sicherheit & Vorschriften

GHS-Einstufung	DangerH271 (16.4%): May cause fire or explosionstrong Oxidizer [Danger Oxidizing liquidsOxidizing solids]P210, P220, P261, P264, P264+P265, P270, P271, P280, P283, P301+P317, P302+P352, P304+P340, P305+P351+P338, P306+P360, P319, P321, P330, P332+P317, P337+P317, P362+P364, P370+P378, P371+P380+P375, P403+P233, P405, P420, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 61 reports by companies from 10 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.H272: May intensify fireoxidizer [Danger Oxidizing liquids
Regulatorische Informationen	Chemical: Perchloric acid, magnesium saltStatus: Active Update: 11-08-2020 https://echa.europa.eu/registration-dossier/-/registered-dossier/29608Perchloric acid, magnesium salt: HSNO Approval: HSR001331 Approved with controls
Weitere Sicherheitsinformationen	IMAP assessments - Perchlorates: Human health tier II assessment
DOT-Kennzeichnung	Oxidizer
Brandgefahren	Behavior in Fire: Can form explosive mixture with combustible material or finely powdered metals. Increases the intensity of fires. (USCG, 1999)CAUTION: Ammonium nitrate products may explode if involved in fire or contaminated with hydrocarbons (fuels), organic matter, other contaminants or when hot molten and contained. Treat as an explosive (GUIDE 112).
Brandpotenzial	POWERFUL OXIDIZING MATERIALMIXTURES WITH COMBUSTIBLE ORG OR OTHER EASILY OXIDIZABLE MATERIALS...ARE IGNITED READILY BY FRICTION OR HEAT.It is noncombustible but it will accelerate the burning of combustible materials.
Gesundheitsgefahren	Inhalation of dust irritates mucous membranes. Ingestion of large amounts may be fatalimmediate symptoms include adominal pains, nausea and vomiting, diarrhea, pallor, blueness, shortness of breath, unconsciousness. Contact with eyes or skin causes irritation. (USCG, 1999)· Inhalation, ingestion or contact (skin, eyes) with vapors or substance may cause severe injury, burns or death.

Anwendungen & Verwendung

Beschreibung

Magnesium perchlorate is a powerful oxidizing agent, with the formula Mg(ClO4)2. Magnesium perchlorate decomposes at 250°C. The heat of formation is 568.90 kJ/mol. If water is added to magnesium perchlorate, the reaction is highly exothermic and may cause damage to the eyes. Thus, this salt should be added to a sufficient amount of water in order to form a dilute solution.Mg(ClO4)2·6H2O is composed of white, deliquescent crystals which are soluble in water and alcohol but explosive when in contact with reducing materials. This compound is used as a drying agent for gases. This salt is highly exothermic when added to water and releases steamy HCl gas. It can be dried to form the anhydrate by heating to 250°C under vacuum. The hexahydrate losses two molecules of water at 244°C in air and further decomposes to the dihydrate at 336°C and the anhydrate at 438°C. The anhydrate has been used as a desiccant to dry gas streams or air samples. However, it is no longer used since perchlorates tend to form explosive compounds with a variety of organic materials as well as other substances.

Verwenden

Magnesium perchlorate is commonly utilized as a potent oxidizing agent. It is used as dehydrating agent in organic synthesis. It is practiced in many domains like pharma industry, pyrotechnics industry,in rechargeable batteries and it is a versatile tool in organic synthesis. It possesses photoelectronic and optical properties. Thus it can be used in photo electronic and optoelectronic devices. It is applied as a strong drying agent for gases.

Herstellung & Synthese

synthetische

Magnesium perchlorate can be prepared by reacting magnesium carbonate with a solution of perchloric acid: MgCO3＋ HClO4→Mg(ClO4)2＋ CO2 This salt can also be prepared by an electrochemical method in water whereby magnesium perchlorate is formed from magnesium chlorate in which a platinum anode and a rotating stainless steel cathode are employed.