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Hydroxylammoniumsulfat

Hydroxylamine sulfate

HCID 24846
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Grundinformationen

CAS
10039-54-0
Standard-SMILES
O=S(=O)([O-])[O-].[NH3+]O.[NH3+]O
InChIKey
VGYYSIDKAKXZEE-UHFFFAOYSA-L
Summenformel
(NH2OH)2.H2SO4
Durchschnittliche Molmasse
164,14 g/mol
Monoisotopische Masse
164,01030715

Überblick

Hydroxylamine sulfate is a colorless crystalline solid. Contact may cause severe irritation to skin, eyes, and mucous membranes. May be toxic by ingestion.

Namen und Bezeichner

Bevorzugter Name
Hydroxylamine sulfate
IUPAC
hydroxyazanium;sulfate
Lokaler Name
Hydroxylammoniumsulfat
Englischer Name
Hydroxylamine sulfate
Summenformel
H2O4S.2H3NO
Molmasse
164.14

Namen und Synonyme

Hydroxylammonium sulfateOxammonium sulfateHydroxylamine sulfate (2:1)Bis(hydroxylamine) sulfateHydroxylamine sulphateHydroxylamine, sulfateHydroxylamine neutral sulfateBis(hydroxylammonium) sulphateHydroxylammoniumsulfatLANASANE LABDTXSID202542449KP498D4O
Weitere Namen anzeigen
HASHYDROXYLAMMONIUM SULPHATEHydroxyamine sulfateHydroxylammoniumHuHAS1amine suLHA synthase 1
hydroxyl ammonium sulfateBIS(HYDROXYLAMMONIUM) SULFATEEINECS 233-118-8UN2865UNII-49KP498D4ODTXCID505424HYDROXYLAMINE SULFATE [MI]EC 233-118-8

Datenbank-Bezeichner

CAS
10039-54-0
PubChem CID
24846
DTXSID
DTXSID2025424

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA)
184 Ų
H-Brücken-Donoren
4
H-Brücken-Akzeptoren
6
Frei drehbare Bindungen
0
Schwere Atome
9
Formalladung
0
Komplexität
64,2

Experimentelle und physikochemische Eigenschaften

Chemical Classes · 2 Einträge

Nitrogen Compounds -> Hydroxylamines

Corrosives

CosmeticsAntioxidant
LogP-3.6
Density · 2 Einträge

greater than 1 at 68 °F (USCG, 1999)

1.88 g/cm³

Solubility · 2 Einträge

greater than or equal to 100 mg/mL at 70 °F (NTP, 1992)

Solubility in water, g/100ml at 20 °C: 58.7

Decomposition120 °C
Melting Point · 2 Einträge

338 °F (decomposes) (NTP, 1992)

170 °C

Food Contact SubstancesFCS -> FDA Inventory of Food Contact Substances Listed in 21 CFR
Physical Description · 4 Einträge

Hydroxylamine sulfate is a colorless crystalline solid. Contact may cause severe irritation to skin, eyes, and mucous membranes. May be toxic by ingestion.

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

GHS-Klassifizierung

GHS Classification · 6 Einträge

Warning

H290: May be corrosive to metals [Warning Corrosive to Metals]

P203, P234, P260, P261, P264, P264+P265, P270, P272, P273, P280, P301+P317, P302+P352, P305+P351+P338, P317, P318, P319, P321, P330, P332+P317, P333+P317, P337+P317, P362+P364, P390, P391, P405, P406, and P501 (click each P-code to see the statement)

Warning

H290 (97.9%): May be corrosive to metals [Warning Corrosive to Metals]

P203, P234, P260, P261, P264, P264+P265, P270, P272, P273, P280, P301+P317, P302+P352, P305+P351+P338, P317, P318, P319, P321, P330, P332+P317, P333+P317, P337+P317, P362+P364, P390, P391, P405, P406, and P501 (click each P-code to see the statement)

Gefahrenhinweise

Regulatory Information · 5 Einträge

Chemical: Hydroxylamine, sulfate (2:1) (salt)

Hydroxylamine, sulfate (2:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Hydroxylamine, sulfate (2:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

REACH registered substance: Bis(hydroxylammonium) sulphate (EC: 233-118-8)

Hydroxylamine sulphate: Does not have an individual approval but may be used under an appropriate group standard

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

Other Safety InformationIMAP assessments - Hydroxylamine and its salts: Human health tier II assessment
DOT LabelCorrosive
Fire Hazards · 3 Einträge

Special Hazards of Combustion Products: Sulfuric acid fumes may form in fires. (USCG, 1999)

Chemie und Industrie

Verwendung und Herstellung

Uses · 2 Einträge

Used as a reducing agent in photography, an antioxidant for fatty acids and soaps, and a dehairing agent for hides; [Merck Index] Used mainly as an intermediate for cyclohexanone oxime or caprolactum; Also used as an intermediate (pharmaceuticals, insecticides, herbicides, and artificial sweeteners), photographic developer, vulcanizing accelerator, antioxidant for natural rubber, and inhibitor in plastic polymerizations; Other uses are surface treatment of steel, separation of uranium and plutonium, electroplating of metals and plastics, and fixing textile dyes; [EU Risk Assessment]

Steel Producing [Category: Industry]

U.S. Production2023: 500,000,000 - <1,000,000,000 lb
Consumer UsesNot Known or Reasonably Ascertainable
Industry UsesChelating agent
Use ClassificationCosmetics -> Antioxidant
General Manufacturing Information · 2 Einträge

All Other Chemical Product and Preparation Manufacturing

Hydroxylamine, sulfate (2:1): ACTIVE

Anwendungen

VerwendenHydroxylamine sulfate may be used to prepare highly sensitive cellulose tape, used for the detection of formaldehyde gas. It may be used in the quantitative determination of perchlorate in biological fluids by spectrophotometric methods .

Darstellung

synthetischeHydroxylamine sulfate may be prepared by mixing stoichiometric amountsof hydroxylamine and sulfuric acid. It also may be prepared by electrolytical-ly reducing an aqueous solution of ammonium sulfate.

Vor- und nachgelagerte Produkte

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UNII
49KP498D4O
EC Number
233-118-8

Liquid; Other Solid; Liquid; Dry Powder; Liquid; Large Crystals; Dry Powder

Solid; [Merck Index] White odorless solid; [CHRIS] Colorless crystals; [Sigma-Aldrich MSDS]

WHITE CRYSTALS OR POWDER.

Physikochemische Eigenschaften

Schmelzpunkt
170 °C · 170 °C (dec.)(lit.)
Siedepunkt
56.5 ℃ · 56.5℃
Dichte
1.86 · 1.86
Dampfdruck
0.001 Pa · 0.001Pa at 20℃
storage temp.
-20 °C · -20°C
Löslichkeit
water: soluble(lit.)
Aggregatzustand
Crystals
Farbe
White
PH
3.6 · 3.6 (10g/l, H2O, 20℃)
Biologische Quelle
mouse
Wasserlöslichkeit
329 g/L · 329 g/L (20 ºC)
Merck
14 · 14,4828
Stabilität
Stable, but may be an explosion hazard - do not heat. May decompose explosively in the presence of alkalies. Air sensitive. Hygroscopic. Incompatible with copper, copper alloys, strong oxidising agents, strong bases, nitrites.
Kosmetik-Inhaltsstoffe Funktionen
ANTIOXIDANT
InChI
1S/2H3NO.H2O4S/c2*1-2;1-5(2,3)4/h2*2H,1H2;(H2,1,2,3,4)
InChIKey
VRXOQUOGDYKXFA-UHFFFAOYSA-N
SMILES
NO.NO.OS(O)(=O)=O
LogP
-1.031 · -1.031 (est)
CAS Datenbank
10039 · 10039-54-0(CAS DataBase Reference)
EPA chemische Informationen
Hydroxylamine sulfate (2:1) (10039-54-0)

· Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.

Combustible. Gives off irritating or toxic fumes (or gases) in a fire.

Health Hazards · 2 Einträge

Inhalation of dust or ingestion may cause systemic poisoning characterized by cyanosis, methemoglobinemia, convulsions, and coma. Contact with eyes or skin causes irritation. (USCG, 1999)

· TOXIC and/or CORROSIVE; inhalation, ingestion or skin contact with material may cause severe injury or death.

Hazards Summary · 1 Eintrag

A skin irritant; May cause methemoglobinemia, cyanosis, convulsions, hypotension, and coma; [Merck Index] A strong reducing agent; A skin and eye irritant; May cause skin sensitization; May induce methemoglobinemia; Long term or repeated exposure may cause anemia; Can be absorbed through skin; [ICSC] May cause severe skin, eye, and mucous membrane irritation; [CAMEO] A skin and eye irritant; May cause cyanosis, methemoglobinemia, convulsions, and coma; [CHRIS] May explode by shock, friction, fire, or other source of ignition; Reports of occupational contact dermatitis; [ToxPlanet: EU Risk Assessment] Causes irritation or corrosive injuries to skin, eyes, and mucous membranes; [NTP] A skin and strong eye irritant; May cause skin sensitization; Harmful by ingestion; Targets the blood and CNS; [Sigma-Aldrich MSDS] See Hydroxylamine and Hydroxylamine hydrochloride.

DOT ID and Guide2865 154
Reactive GroupSalts, Acidic
EC ClassificationSymbol: Xn, N; R: 22-36/38-43-48/22-50; S: (2)-22-24-37-61
UN ClassificationUN Hazard Class: 8; UN Pack Group: III
Reactivity ProfileSulfuric acid fumes may form in fires (USCG, 1999). Solid hydroxylamine sulfate explodes when heated to 170 °C [Chem. Process 26:30(1963)]. Sodium ignites on contact with hydroxylamine. (Mellor, 1940, Vol. 8, 292.)
Chemical Dangers · 1 Eintrag

Decomposes on contact with hot surfaces or flames. This produces corrosive fumes of sulfur oxides. The solution in water is a medium strong acid. The substance is a strong reducing agent. It reacts violently with oxidants, powdered metals, nitrates, nitrites and heavy metal salts.

Sicherheit und Schutzausrüstung

Fire Fighting · 2 Einträge

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

Use water in large amounts, powder, alcohol-resistant foam, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.

First Aid Measures · 4 Einträge

Fresh air, rest. Refer for medical attention.

Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention .

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Rinse mouth. Give a slurry of activated charcoal in water to drink. Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Refer for medical attention .

Accidental Release Measures · 2 Einträge

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

First Aid · 2 Einträge

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

General First Aid:

Safe StorageSeparated from oxidants, nitrates, nitrites and combustible substances.
Exposure Control and Personal Protection· Wear positive pressure self-contained breathing apparatus (SCBA).
Nonfire Spill ResponseExcerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
Spillage Disposal · 1 Eintrag

Personal protection: P2 filter respirator for harmful particles. Sweep spilled substance into covered containers. Carefully collect remainder. Then store and dispose of according to local regulations. Do NOT let this chemical enter the environment.

Isolation and Evacuation · 2 Einträge

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

Immediate precautionary measure

Eye PreventionWear safety spectacles or eye protection in combination with breathing protection.
Fire PreventionNO open flames.
Inhalation RiskA harmful concentration of airborne particles can be reached quickly when dispersed.

Toxikologische Informationen

Adverse EffectsMethemoglobinemia - The presence of increased methemoglobin in the blood; the compound is classified as secondary toxic effect
Exposure RoutesThe substance can be absorbed into the body by inhalation of its aerosol, through the skin and by ingestion.
Signs and Symptoms · 4 Einträge

See Ingestion.

MAY BE ABSORBED! Redness.

Redness. Pain.

Blue lips, fingernails and skin. Confusion. Convulsions. Dizziness. Headache. Nausea. Unconsciousness.

ICSC Environmental DataThe substance is toxic to aquatic organisms.

Sicherheitsdaten

F
21
wgk
3
tsca
TSCA listed
ridadr
UN 2865
hs_code
28251000
RTECS-Nr.
NC5425000
risk_code
22-36/38-43-48/22-50-40-21/22-2
Toxizität
LD50 orally in Rabbit: 842 mg/kg LD50 dermal Rabbit 1500 - 2000 mg/kg
hazard_code
Xn,N,E
safety_code
22-24-37-61-36/37
hazard_class
8
packing_group
III
Speicherklasse
4.1A - Other explosive hazardous materials
Hazard Classifications
Acute Tox. 4 DermalAcute Tox. 4 OralAquatic Acute 1Carc. 2Eye Irrit. 2Met. Corr. 1Skin Irrit. 2Skin Sens. 1STOT RE 2 Oral

Vorgelagerte Rohstoffe

EthanolAmmoniumhydrogensulfitButanonoximSchwefeldioxidButanonAcetonoximAmmoniumsulfatSchwefelsure

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