palladium(II) pivalate

HCID 24905427CAS 106224-36-6

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Grundinformationen

Standard-SMILES: CC(C)(C)C(=O)[O-].CC(C)(C)C(=O)[O-].[Pd+2]
InChIKey: PAGZTSLSNQZYEV-UHFFFAOYSA-L
Summenformel: C10H18O4Pd
Durchschnittliche Molmasse: 308,67 g/mol
Monoisotopische Masse: 308,02399506

Namen und Bezeichner

Bevorzugter Name: palladium(II) pivalate
IUPAC: bis(2,2-dimethylpropanoate);palladium(2+)
Englischer Name: Palladium pivalate 97%
Summenformel: Pd[O2C(CH3)3]2
Molmasse: 309

Namen und Synonyme

Palladium pivalatepalladium(II) pivalateRefChem:858336687-340-9936-555-9106224-36-6Palladium dipivalate2,2-dimethylpropanoate;palladium(2+)C10H18O4PdPalladium pivalate 97per centPalladium(II) trimethylacetatepalladium(II)pivalate

Weitere Namen anzeigen

2,2-DimethylpropanoiPalladium pivalate 97%Palladium pivalate 97%Palladium(II) trimethylacetate，97%PalladiuM(II)triMethylacetate,Min.98%Palladium(II) trimethylacetate, min. 98%

palladium(11) pivalate2,2-Dimethylpropanoic acid palladium(II) saltMFCD16038138SCHEMBL301033DTXSID606480082,2-dimethylpropanoate,palladium(2+)AKOS025294023SY069974

Datenbank-Bezeichner

CAS: 106224-36-6
PubChem CID: 24905427
DTXSID: DTXSID60648008
EC Number: 687-340-9、936-555-9
Nikkaji: J2.425.701K

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA): 80,3 Å²
H-Brücken-Donoren: 0
H-Brücken-Akzeptoren: 4
Frei drehbare Bindungen: 0
Schwere Atome: 15
Formalladung: 0
Komplexität: 73,1

Physikochemische Eigenschaften

Schmelzpunkt: 230 · 230-232 °C
storage temp.: Inert atmosphere,Room Temperature
Aggregatzustand: Solid
Farbe: Orange
Wasserlöslichkeit: 1 · Soluble in ethyl acetate, methanol, chloroform, tetrahydrofuran and 1,4-dioxane. Insoluble in water.
InChI: InChI=1S/2C5H10O2.Pd/c2*1-5(2,3)4(6)7;/h2*1-3H3,(H,6,7);/q;;+2/p-2
InChIKey: PAGZTSLSNQZYEV-UHFFFAOYSA-L
SMILES: [Pd+2].C([O-])(=O)C(C)(C)C.C([O-])(=O)C(C)(C)C

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 6 Einträge

Warning

H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]

P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 40 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

H301 (100%): Toxic if swallowed [Danger Acute toxicity, oral]

Gefahrenhinweise

Hazard Classes and Categories · 2 Einträge

Skin Irrit. 2 (100%)

Acute Tox. 3 (100%)

Sicherheitsdaten

wgk: 3
risk_code: 36/37/38
hazard_code: Xi
safety_code: 26
Speicherklasse: 11 - Combustible Solids
Hazard Classifications: Eye Irrit. 2Skin Irrit. 2STOT SE 3

Chemie und Industrie

Anwendungen · 1 Eintrag

VerwendenPalladium(II) trimethylacetate is used as a catalyst for aerobic cyclization of acrylic acid with alkenes. It is utilized in the benzylation of heterocycles with benzyl chloride and direct arylation reactions. Furthermore, it is used in regioselective oxidative arene cross-coupling.