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Cadmiumnitrat
ai3-51840 · Cadmiumnitrat · CADMIUM NITRATE · cadmiumdinitrate · CadMiniuM Nitrate · cadmium(ii)nitrate · cadmium(2+) dinitrate · Nitricacid,cadmiumsalt

Identifikatoren & physikalische Daten
| CAS No. | 10325-94-7 |
|---|---|
| Summenformel | Cd(NO3)2 |
| Durchschnittliche Molmasse | 236,42 g/mol |
| Monoisotopische Masse | 237,87899422 g/mol |
| SMILES | O=[N+]([O-])[O-].O=[N+]([O-])[O-].[Cd+2] |
| InChIKey | XIEPJMXMMWZAAV-UHFFFAOYSA-N |
| PubChem CID | 25154 |
| ChEBI | CHEBI:77732 |
| EC No. | 233-710-6 |
| DTXSID | DTXSID7044504 |
| Lokaler Name | Cadmiumnitrat |
Chemische & physikalische Eigenschaften
| Polarare Oberfläche (TPSA) | 126 |
|---|---|
| H-Brücken-Donoren | 0 |
| H-Brücken-Akzeptoren | 6 |
| Frei drehbare Bindungen | 0 |
| Schwere Atome | 9 |
| Formalladung | 0 |
| Komplexität | 18,8 |
| Stoffklassen | Metals -> Cadmium Compounds, InorganicCarcinogens |
| Dichte | 2.45 at 68 °F (USCG, 1999) - Denser than waterwill sink3.6 g/cu cm3.6 @25 °C2.455(17/4℃) |
| Color/Form | White cubic crystalsWhite, amorphous pieces or hygroscopic needlesWhite, prismatic needles |
| Löslichkeit | Soluble in ammonia, alcoholSol in ethanolSoluble in ether, acetoneIn water, 156 g/100 g water at 25 °Csoluble in ethanolg/100g solution H2O: 55.1 (0.6°C), 61.3 (25°C), 87.2 (100°C)solid phase, Cd(NO3)2 · 4H2O (0°C, 25°C), Cd(NO3)2 (100°C) [KRU93]soluble alcohol, ammonia [HAW93] |
| Endocrine Disruptors | Potential endocrine disrupting compound |
| Siedepunkt | 132 °C @760 [mm Hg]132℃ |
| Decomposition | When heated to decomp, emits very toxic fumes of /cadmium and nitrogen oxides/. |
| Schmelzpunkt | 138 °F (USCG, 1999)360 °C59.4℃ |
| Physical Description | Cadmium nitrate is an odorless white solid. Sinks in water. (USCG, 1999)[HSDB] White odorless crystals[MSDSonline] There are 3 hydrates that form at temperatures <56 deg C[Ullmann] |
| Stability/Shelf Life | Stable during transport. /Tetrahydrate/ |
| Other Experimental Properties | Strongly hygroscopicEnthalpy of Fusion: 18.3 kJ/mol at 360 °CSpecific gravity 2.455bp 132 °C /Tetrahydrate/... forms both a dihydrate and a tetrahydrateFor more Other Experimental Properties (Complete) data for CADMIUM NITRATE (9 total), please visit the HSDB record page. |
| Aggregatzustand | white cubic crystals |
| Farbe | white cubic crystals, crystallinehygroscopic |
| pH | ≥3 |
| Merck | 13,1622 |
| BRN | 8137359 |
| CAS Datenbank | 10325-94-7(CAS DataBase Reference) |
| EPA chemische Informationen | Cadmium nitrate (10325-94-7) |
Sicherheit & Vorschriften
| GHS-Einstufung | DangerH302: Harmful if swallowed [Warning Acute toxicity, oral]P203, P260, P261, P264, P270, P271, P273, P280, P301+P317, P302+P352, P304+P340, P317, P318, P319, P321, P330, P362+P364, P391, P405, and P501 (click each P-code to see the statement)H301 (90%): Toxic if swallowed [Danger Acute toxicity, oral]P203, P260, P261, P264, P270, P271, P273, P280, P284, P301+P316, P301+P317, P302+P352, P304+P340, P316, P317, P318, P319, P320, P321, P330, P362+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement) |
|---|---|
| Regulatorische Informationen | Chemical: Nitric acid, cadmium saltHazard Traits - CarcinogenicityGenotoxicityREACH registered substance: Cadmium nitrate (EC: 233-710-6)Restricted substance: Cadmium nitrateSubstance: Cadmium nitrateNitric acid, cadmium salt: HSNO Approval: HSR001316 Approved with controls |
| Weitere Sicherheitsinformationen | IMAP assessments - Water soluble cadmium(2+) salts: Environment tier II assessment |
| DOT-Kennzeichnung | Oxidizer Poison |
| Brandgefahren | Special Hazards of Combustion Products: Toxic oxides of nitrogen and cadmium oxide fume may form in fires. |
| Gesundheitsgefahren | Inhalation of fumes can produce coughing, chest constriction, headache, nausea, vomiting, pneumonitis. Chronic poisoning is characterized by emphysema and kidney injury. Ingestion causes gastrointestinal disturbance and severe toxic symptomsboth kidney and liver injuries may occur. Contact with eyes causes irritation. (USCG, 1999) |
| Gefahrenübersicht | See Cadmium and the linked diseases.The major hazards encountered in the use and handling of cadmium nitrate stem from its toxicologic properties. Toxic primarily by ingestion and inhalation, exposure to this odorless, colorless-to-white, crystalline substance may occur from its use in making other cadmium salts, in photographic emulsions, in coloring glass and procelain, and in the manufacture of nickel-cadmium batteries and turf fungicides. Effects from exposure may include headache, nausea, shortness of breath, chest pain, kidney damage, liver damage, emphysema, and intense pulmonary edema (possibly resulting in death). Processes and operations which may release cadmium fumes or dust should be enclosed and fitted with exhaust ventilation. In activities where overexposure is possible, workers should wear a high efficiency particulate filter respirator or self-contained breathing apparatus. Protective clothing also should be worn, including eye, face, and hand protection. All such clothing should be removed before leaving work. If contact should occur, immediately wash contaminated skin with large amounts of water. Do not eat, smoke, or drink in work areas. Cadmium nitrate presents only a moderate fire hazard (when in the form of dust) if exposed to heat, flame, or by chemical reaction with oxidizing agents, metals, hydrogen azide, zinc, selenium, or tellurium. Wear a self-contained breathing apparatus when fighting such fires. Cadmium nitrate should be stored in cool, well-ventilated areas, out of direct rays of sun, and away from combustibles and other fire hazards. Should hazardous concentrations of cadmium nitrate be released, first stop the discharge, then isolate and remove the discharged material. Before implementing land disposal of waste cadmium nitrate, consult environmental regulatory agencies for guidance. |
Anwendungen & Verwendung
Verwenden
Cadmium salts, photographic emulsions, col- oring glass and porcelain, laboratory reagent, cad- mium salts.
Herstellung & Synthese
synthetische
reparation Cadmium nitrate is prepared by dissolving cadmium metal or its oxide, hydroxide, or carbonate, in nitric acid followed by crystallization:CdO + 2HNO3 → Cd(NO3)2 + H2O.