Grundinformationen
- CAS
14481-29-9- Standard-SMILES
[C-]#N.[C-]#N.[C-]#N.[C-]#N.[C-]#N.[C-]#N.[Fe+2].[NH4+].[NH4+].[NH4+].[NH4+]- InChIKey
ZXQVPEBHZMCRMC-UHFFFAOYSA-R- Summenformel
- C6H16FeN10
- Durchschnittliche Molmasse
- 284,1 g/mol
- Monoisotopische Masse
- 284,09087801
Namen und Bezeichner
- Bevorzugter Name
- Ammonium ferrocyanide
- IUPAC
- tetraazanium;iron(2+);hexacyanide
- Lokaler Name
- Tetraammoniumhexacyanoferrat
- Englischer Name
- AMMONIUM FERROCYANIDE
- Summenformel
- C6H16FeN10
- Molmasse
- 284.1
Namen und Synonyme
AMMONIUM FERROCYANIDEtetraammonium ferrocyanideGHD63ZGL2LAmmonium hexacyanoferrate (II)DTXSID1051725AMMONIUM FERROCYANIDE [MI]Tetraammonium hexacyanoferrate(4-)(OC-6-11)-HEXAKIS(CYANO-.KAPPA.C)FERRATE(4-) AMMONIUM (1:4)RefChem:112158UNII-GHD63ZGL2LDTXCID1030280HSDB 2099
Weitere Namen anzeigen
FERROUS AMMONIUM CYANIDEAMMONIUM HEXACYANOFERRATE IItetraammoniumhexacyanoferrateammonium hexacyanoferrate(4-)IRON (II) AMMONIUM FERROCYANIDEtetraammoniumhexacyanoferrate(4-)hexacyano-ferrate(4-tetraammoniumAmmonium hexacyanoferrate hydrate
Tetraammonium hexacyanoferrate(4)EINECS 238-476-9Ferrate(4), hexacyano, tetraammoniumFerrate(4-), hexacyano-, tetraammoniumTriammonium hexakis-(cyano-C)ferrate(4-)AI3-28802Ammonium ferrocyanide ((NH4)4(Fe(CN)6))Ferrate(4-), hexakis(cyano-C)-, tetraammonium
Datenbank-Bezeichner
- CAS
14481-29-9- PubChem CID
- 26708
- DTXSID
DTXSID1051725- UNII
- GHD63ZGL2L
- EC Number
- 238-476-9
Eigenschaften
Berechnete Struktureigenschaften
- Polarare Oberfläche (TPSA)
- 147 Ų
- H-Brücken-Donoren
- 4
- H-Brücken-Akzeptoren
- 12
- Frei drehbare Bindungen
- 0
- Schwere Atome
- 17
- Formalladung
- 0
- Komplexität
- 10
Experimentelle und physikochemische Eigenschaften
Chemical ClassesNitrogen Compounds -> Ammonium Compounds
Color/Form
Yellow crystals
TURNS BLUE IN AIR
SolubilityFreely sol in water; practically insol in alcohol /Trihydrate/
Physical DescriptionYellow solid; Turns blue in air; [HSDB] Light green powder; [MSDSonline]
Stability/Shelf LifeLOSES NH3 ON EXPOSURE TO AIR & LIGHT; DECOMP ON HEATING /TRIHYDRATE/
Other Experimental PropertiesYellow crystalline powder /Trihydrate/
Physikochemische Eigenschaften
- Schmelzpunkt
- 300 °C · >300°C
- Löslichkeit
- 2 O; · soluble in H2O; insoluble in ethanol
- Aggregatzustand
- Powder
- Farbe
- yellow to green
- Wasserlöslichkeit
- 2 O · trihydrate soluble H2O [MER06]
- Merck
- 14 · 14,520
- CAS Datenbank
- 14481 · 14481-29-9(CAS DataBase Reference)
- EPA chemische Informationen
- Ferrate(4-), hexakis(cyano-.kappa.C)-, tetraammonium, (OC-6-11)- (14481-29-9)
Sicherheit und Regulatorisches
Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.
GHS-Klassifizierung
GHS Classification
This chemical does not meet GHS hazard criteria for 2.2% (1 of 45) of reports.
Warning
H302 (88.9%): Harmful if swallowed [Warning Acute toxicity, oral]
P261, P264, P270, P271, P280, P301+P317, P302+P352, P304+P340, P317, P321, P330, P362+P364, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 45 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Gefahrenhinweise
Regulatory InformationRestricted substance: Tetraammonium hexacyanoferrate
Hazards Summary
Emergency treatment: Irritants; [HSDB] Ferrocyanide complexes are stable and practically nontoxic because of the strong bonding between iron and cyanide. Cyanide ions may be formed slowly when the chemical is irradiated with UV light. [Ullmann] May cause irritation; [MSDSonline]
RCRA Requirements
/SRP:/ D003; A solid waste containing ammonium ferrocyanide may become characterized as a hazardous waste when subjected to testing for reactivity as stipulated in 40 CFR 261.23, and if so characterized, must be managed as a hazardous waste.
EPA Hazardous Waste NumberD003; /SRP:/ A waste containing ammonium ferrocyanide may (or may not) be characterized a hazardous waste following testing for the reactivity characteristics as prescribed by the Resource Conservation and Recovery Act (RCRA) regulations.
Clean Water Act RequirementsToxic pollutant designated pursuant to section 307(a)(1) of the Federal Water Pollution Control Act and is subject to effluent limitations. /Cyanides/
Hazard Classes and CategoriesAcute Tox. 4 (88.9%)
Hazardous Reactivities and IncompatibilitiesAt 220 °C interaction with ammonium hexacyanoferrate is explosive in wet mixtures, or in dry mixtures if the nitrate is in excess.
Sicherheit und Schutzausrüstung
Storage ConditionsPROTECT FROM LIGHT.
Disposal MethodsGenerators of waste (equal to or greater than 100 kg/mo) containing this contaminant, EPA hazardous waste number D003, must conform with USEPA regulations in storage, transportation, treatment and disposal of waste.
Toxikologische Informationen
Human Toxicity ExcerptsSUMMARY TOXICITY STATEMENT; ACUTE... FERROCYANIDES AS SUCH ARE OF LOW ORDER OF TOXICITY. LOW= CAUSES READILY REVERSIBLE TISSUE CHANGES WHICH DISAPPEAR AFTER EXPOSURE STOPS. CAUSES SOME DISCOMFORT. /FERROCYANIDES/
Regulatorische Informationen
RCRA Requirements
/SRP:/ D003; A solid waste containing ammonium ferrocyanide may become characterized as a hazardous waste when subjected to testing for reactivity as stipulated in 40 CFR 261.23, and if so characterized, must be managed as a hazardous waste.
Clean Water Act RequirementsToxic pollutant designated pursuant to section 307(a)(1) of the Federal Water Pollution Control Act and is subject to effluent limitations. /Cyanides/
Sicherheitsdaten
- F
- 8
- wgk
- 3
- tsca
- TSCA listed
- hs_code
- 28372000
- risk_code
- 20/21/22
- hazard_code
- Xn
- safety_code
- 26-36/37
- Giftige Stoffe Daten
- 14481-29-9(Hazardous Substances Data)
Chemie und Industrie
Verwendung und Herstellung
General Manufacturing InformationFerrate(4-), hexakis(cyano-.kappa.C)-, ammonium (1:4), (OC-6-11)-: ACTIVE
Vor- und nachgelagerte Produkte
Nachgelagerte Produkte
Anbieter40 Anbieter
湖北永阔科技有限公司027-59223108 15972152991 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
湖北万得化工有限公司15377098680 15377098680 · [email protected]
陕西缔都化学有限公司029-029-81123119 17391733320 · [email protected]
江苏艾康生物医药研发有限公司025-025-66113011 15955137747 · [email protected]
上海迈瑞尔生化科技有限公司4006356688 18621169109 · [email protected]
安耐吉化学&3A（安徽泽升科技股份有限公司）400-0056266 · [email protected]
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HBCChem, Inc.+1-510-219-6317 · [email protected]
杭州杰恒化工有限公司0571-87396432 · [email protected]
池州凯隆进出口贸易有限公司[email protected]
长沙晶康新材料科技有限公司0731-85118349 18874718518 · [email protected]
HANGZHOU LEAP CHEM CO., LTD.+86-571-87711850 +86-15355479329 · [email protected]
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厦门盈融达化工有限公司+86-0592-6210733 · [email protected]
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Aladdin Scientific[email protected]
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