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Natriumhydroxymethansulfonat

Sodium Formaldehyde Bisulfite

HCID 2723822
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GrundinformationenNamen und BezeichnerEigenschaftenSicherheit und RegulatorischesChemie und IndustrieZugehörige ReaktionenNotizen zur Verbindung
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Grundinformationen

CAS
870-72-4
Standard-SMILES
O=S(=O)([O-])CO.[Na+]
InChIKey
UOULCEYHQNCFFH-UHFFFAOYSA-M
Summenformel
CH3NaO4S
Durchschnittliche Molmasse
134,09 g/mol
Monoisotopische Masse
133,96497386

Namen und Bezeichner

Bevorzugter Name
Sodium Formaldehyde Bisulfite
IUPAC
sodium hydroxymethanesulfonate
Lokaler Name
Natriumhydroxymethansulfonat
Englischer Name
Formaldehyde sodium bisulfite
Summenformel
CH5NaO4S
Molmasse
136.1

Namen und Synonyme

Sodium hydroxymethanesulfonate870-72-4SODIUM FORMALDEHYDE BISULFITEFormaldehyde sodium bisulfiteFormbisSodium hydroxymethanesulphonateHydroxymethanesulfonic acid monosodium saltSodium formaldehydebisulfiteDTXSID3027328HSDB 5766Sodium hydroxymethylsulfonateNSC 2441
Weitere Namen anzeigen
PNFormaldehyde Sodium BisulphiteFORMALDEHYDE SODIUMSodium hydroxy methyleneHVSL1FLJ13154
EINECS 212-800-9UNII-I566KHA05FFormaldehyde sulfite sodium saltI566KHA05FMonosodium hydroxymethanesulfonateAI3-23356Methanesulfonic acid, hydroxy-, sodium saltFormaldehyde-sodium bisulfite compound

Datenbank-Bezeichner

CAS
870-72-4
PubChem CID
2723822
DTXSID
DTXSID3027328
ChEMBL
CHEMBL3185494
UNII
I566KHA05F

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA)
85,8 Ų
H-Brücken-Donoren
1
H-Brücken-Akzeptoren
4
Frei drehbare Bindungen
1
Schwere Atome
7
Formalladung
0
Komplexität
108

Experimentelle und physikochemische Eigenschaften

Chemical ClassesMetals -> Organic Compounds, Metal Salts
CosmeticsReducing
Color/FormWhite solid
Solubility · 2 Einträge

Soluble in water

Soluble in methanol ... ethanol.

Boiling PointDecomposes
Physical Description · 2 Einträge

Liquid

White solid; [HSDB] White powder; [MSDSonline]

Dissociation ConstantspKa= 6.92
Other Experimental PropertiesNeedles from water /Monohydrate/

Physikochemische Eigenschaften

Schmelzpunkt
200 °C · 200 °C (dec.)(lit.)
Flammpunkt

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

GHS-Klassifizierung

GHS Classification · 3 Einträge

This chemical does not meet GHS hazard criteria for 95.8% (158 of 165) of all reports.

Not Classified

Aggregated GHS information provided per 165 reports by companies from 6 notifications to the ECHA C&L Inventory.

Gefahrenhinweise

Regulatory Information · 4 Einträge

Chemical: Methanesulfonic acid, 1-hydroxy-, sodium salt (1:1)

Methanesulfonic acid, 1-hydroxy-, sodium salt (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Methanesulfonic acid, 1-hydroxy-, sodium salt (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 03-11-2021 https://echa.europa.eu/registration-dossier/-/registered-dossier/27284

Sodium hydroxymethanesulfonate: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Hazards SummaryIf ingested, may form sulfuric acid in stomach; [HSDB] An irritant; [MSDSonline]
Hazard Classes and CategoriesNot Classified
Explosive Limits and PotentialA moderate explosion hazard when exposed to heat or flame. /Formaldehyde/
Skin, Eye, and Respiratory Irritations · 2 Einträge

A human skin and eye irritant. /Formaldehyde/

A human skin and eye irritant. /Formaldehyde/

Sicherheit und Schutzausrüstung

Chemie und Industrie

Verwendung und Herstellung

Uses · 6 Einträge

Used in photography (developer); [www.ci.tucson.az.us/arthazards/medium.html] Used as a textile stripping agent, fixing agent for keratin-containing fibers, flotation chemical in lead-zinc ores, cosmetic preservative, fungicide in mushroom cultivation, and to protect color pictures exposed to high humidity against fading and staining; [HSDB]

Textiles (Fiber & Fabric Manufacturing) [Category: Industry]

Textile stripping agent

One of several mixtures of sodium formaldehyde hydrosulfite and sodium formaldehyde bisulfite used as discharges and stripping or reducing agents in dyeing and other textile operations. In some cases the zinc derivatives are used. Derivation is by the action of formaldehyde on aqueous sodium hydrosulfide or from zinc formaldehyde, sodium dioxide, and sodium hydroxide. /Hydrosulfide-formaldehyde/

Fixing agent for keratin-containing fibers; flotation of lead-zinc ores; protecting color pictures exposed to high humidities against fading and staining

FUNGICIDE IN MUSHROOM CULTIVATION; PRESERVATIVE IN COSMETICS

U.S. Production · 2 Einträge

2023: 25,954 lb

This is a high volume chemical with production exceeding 1 million pounds annually in the U.S.

Industry UsesIntermediate
Methods of Manufacturing · 2 Einträge

Action of sodium bisulfite, formaldehyde, and water.

Skrabal, Skrabal, Monatsh 69, 17 (1936); Chhabria et al, German patent 1,173,059 (1964 to Schill and Seilacher).

Household ProductsInformation on 1 consumer products that contain Sodium hydroxymethane sulfonate in the following categories is provided:
Use ClassificationCosmetics -> Reducing
General Manufacturing Information · 2 Einträge

All Other Chemical Product and Preparation Manufacturing

Methanesulfonic acid, 1-hydroxy-, sodium salt (1:1): ACTIVE

Zugehörige Reaktionen

1
Reaktionsaufzeichnung erstellen
Reaktionsgleichung von HRID 704126
HRID 704126als Eduktuspto-grants-1991_01

Notizen zur Verbindung

Wird geladen…

Auf dieser SeiteGrundinformationenNamen und BezeichnerEigenschaftenSicherheit und RegulatorischesChemie und IndustrieZugehörige ReaktionenNotizen zur Verbindung
EC Number
212-800-9
Nikkaji
J57.764B
184 °C · 184 °C
storage temp.
Inert atmosphere,Room Temperature
Löslichkeit
Methanol (Slightly, Heated), Water (Slightly)
Aggregatzustand
Powder
Farbe
White to almost white
Biologische Quelle
goat
Wasserlöslichkeit
800 g/L · 800 g/L (20 ºC)
Merck
14 · 14,4236
Kosmetik-Inhaltsstoffe Funktionen
REDUCINGANTIMICROBIAL
InChI
InChI=1S/CH4O4S.Na.H/c2-1-6(3,4)5;;/h2H,1H2,(H,3,4,5);;
InChIKey
PIDRKEDSDCPMRU-UHFFFAOYSA-N
SMILES
S(O)(=O)(=O)CO.[NaH]
CAS Datenbank
870 · 870-72-4(CAS DataBase Reference)
EPA chemische Informationen
Methanesulfonic acid, hydroxy-, monosodium salt (870-72-4)
Disposal Methods · 1 Eintrag

SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

Preventive Measures · 1 Eintrag

SRP: The scientific literature for the use of contact lenses in industry is conflicting. The benefit or detrimental effects of wearing contact lenses depend not only upon the substance, but also on factors including the form of the substance, characteristics and duration of the exposure, the uses of other eye protection equipment, and the hygiene of the lenses. However, there may be individual substances whose irritating or corrosive properties are such that the wearing of contact lenses would be harmful to the eye. In those specific cases, contact lenses should not be worn. In any event, the usual eye protection equipment should be worn even when contact lenses are in place.

Toxikologische Informationen

Human Toxicity Excerpts... If swallowed they may cause irritation of the stomach by liberating sulfurous acid. /Sulfites/
Antidote and Emergency Treatment · 2 Einträge

/SRP:/ Basic treatment: Establish a patent airway. Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if needed. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for pulmonary edema and treat if necessary ... . Monitor for shock and treat if necessary ... . Anticipate seizures and treat if necessary ... . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with normal saline during transport ... . Do not use emetics. For ingestion, rinse mouth and administer 5 ml/kg up to 200 ml of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool ... . Cover skin burns with dry sterile dressings after decontamination ... . /Poison A and B/

/SRP:/ Advanced treatment: Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious, has severe pulmonary edema, or is in respiratory arrest. Positive pressure ventilation techniques with a bag valve mask device may be beneficial. Monitor cardiac rhythm and treat arrhythmias as necessary ... . Start an IV with D5W /SRP: "To keep open", minimal flow rate/. Use lactated Ringer's if signs of hypovolemia are present. Watch for signs of fluid overload. Consider drug therapy for pulmonary edema ... . For hypotension with signs of hypovolemia, administer fluid cautiously. Watch for signs of fluid overload ... . Treat seizures with diazepam (Valium) ... . Use proparacaine hydrochloride to assist eye irrigation ... . /Poison A and B/

Sicherheitsdaten

wgk
1
tsca
TSCA listed
hs_code
29055900
RTECS-Nr.
PB2200000
risk_code
36/37/38
safety_code
24/25
Speicherklasse
11 - Combustible Solids
Giftige Stoffe Daten
870-72-4(Hazardous Substances Data)
Anwendungen · 1 Eintrag

VerwendenFormaldehyde Sodium Bisulfite is used in the preparation of oil-soluble sulfonate additives used in improving anticorrosive, dispersant and antioxygenic properties of lubricant oils. Also used in chemical reactions in the preparation of chiral salen Mn(III) catalysts or lignosulfonates as dispersant for gypsum paste.

Vor- und nachgelagerte Produkte

Vorgelagerte Rohstoffe

FormaldehydNatriumhydrogensulfitNatriumanilinomethansulfonat

Nachgelagerte Produkte

friction reducer SAFsynthetic tanning agent DLT-9Dinatrium-3,3'-[carbonylbis[imino(3-methoxy-4,1-phenylen)azo]]dibenzoatAnilinomethansulfonsure

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