Tritylhexafluorphosphat
Trityl hexafluorophosphate
Grundinformationen
- CAS
437-17-2- Standard-SMILES
F[P-](F)(F)(F)(F)F.c1ccc([C+](c2ccccc2)c2ccccc2)cc1- InChIKey
IBTFOFOFRZKIJU-UHFFFAOYSA-N- Summenformel
- C19H15F6P
- Durchschnittliche Molmasse
- 388,3 g/mol
- Monoisotopische Masse
- 388,08155645
Namen und Bezeichner
- Bevorzugter Name
- Trityl hexafluorophosphate
- IUPAC
- diphenylmethylbenzene hexafluorophosphate
- Lokaler Name
- Tritylhexafluorphosphat
- Englischer Name
- Triphenylcarbenium hexafluorophosphate
- Summenformel
- C19H15F6P
- Molmasse
- 388.29
Namen und Synonyme
Triphenylcarbenium hexafluorophosphate437-17-2Tritylium hexafluorophosphateTrityl hexafluorophosphateTriphenylcarbonium hexafluorophosphateTritylium, hexafluorophosphate(1-)Methylium, triphenyl-, hexafluorophosphate(1-)NSC 176018EINECS 207-112-0Methylium, triphenyl-, hexafluorophosphate(1-) (1:1)RefChem:900637Tritylium, hexafluorophosphate(1)
Weitere Namen anzeigen
Trityl cationhexafTRITYL HEXAFLUORO-PHOSPHATETrityl cation·hexafluorophosphateTriphenylmethylium·hexafluorophosphateiphenylmethylbenzene,hexafluorophosphate
Methylium, triphenyl, hexafluorophosphate(1)207-112-0Triphenylmethyl hexafluorophosphatediphenylmethylbenzene;hexafluorophosphateTRIPHENYLCARBENIUMHEXAFLUOROPHOSPHATEPh3CPF6MFCD00013121Tritylcarbonium hexafluorophosphate
Datenbank-Bezeichner
- CAS
437-17-2- PubChem CID
- 2723954
- DTXSID
DTXSID40883238- EC Number
- 207-112-0
Eigenschaften
Berechnete Struktureigenschaften
- Polarare Oberfläche (TPSA)
- 0 Ų
- H-Brücken-Donoren
- 0
- H-Brücken-Akzeptoren
- 7
- Frei drehbare Bindungen
- 3
- Schwere Atome
- 26
- Formalladung
- 0
- Komplexität
- 259
Experimentelle und physikochemische Eigenschaften
Chemical ClassesOther Classes -> Other Organic Compounds
Physical DescriptionDark yellow crystalline solid; [Sigma-Aldrich MSDS]
Physikochemische Eigenschaften
- Schmelzpunkt
- 150 °C · ~150 °C (dec.) (lit.)
- storage temp.
- 2 · 2-8°C
- Aggregatzustand
- solid
- Wasserlöslichkeit
- Soluble in water. (27 g/L) at 25°C.
- BRN
- 4344297 · 4344297
- InChI
- 1S/C19H15.F6P/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7(2,3,4,5)6/h1-15H;/q+1;-1
- InChIKey
- IBTFOFOFRZKIJU-UHFFFAOYSA-N
- SMILES
- F[P-](F)(F)(F)(F)F.c1ccc(cc1)[C+](c2ccccc2)c3ccccc3
- EPA chemische Informationen
- Methylium, triphenyl-, hexafluorophosphate(1-) (437-17-2)
Sicherheit und Regulatorisches
Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.
GHS-Klassifizierung
GHS Classification
Danger
H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]
P260, P264, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P363, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 44 reports by companies from 2 notifications to the ECHA C&L Inventory.
Gefahrenhinweise
Hazards SummaryCauses burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; [Sigma-Aldrich MSDS] See Triphenylcarbenium tetrafluoroborate.
Hazard Classes and CategoriesSkin Corr. 1B (100%)
Toxikologische Informationen
Adverse EffectsDermatotoxin - Skin burns.
Sicherheitsdaten
- F
- 8-10
- wgk
- 3
- tsca
- TSCA listed
- ridadr
- UN 3261 8/PG 2
- risk_code
- 34
- hazard_code
- C
- safety_code
- 26-36/37/39-45
- hazard_class
- 8
- packing_group
- II
- Speicherklasse
- 8A - Combustible corrosive hazardous materials
Chemie und Industrie
Verwendung und Herstellung
General Manufacturing InformationMethylium, triphenyl-, hexafluorophosphate(1-) (1:1): ACTIVE
Anwendungen
VerwendenTriphenylcarbenium hexafluorophosphate is a reagent involved in Si-H and Si-Si bond activation at Pt of neutral and cationic silyl Pt bisphosphine complexes. It is used in investigations of interactions with chromium acetylacetonate nitride mononuclear complexes. It is used in double ring-opening polyaddition of spiro orthoesters. It is used as reagent in Synthesis of "push-pull" tropylium-fused aminoporphyrazine, Preparation of cycloheptatrienyl and tropylium calix[4]arenes, Synthesis of palladacycles containing chiral rhenium half-sandwich complex for use as a catalyst.
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