HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
[2-(Dimethylamino)ethyl]triphenylphosphoniumbromid
2-DimethylaminoethyltriphenylphosphoniumBromide>(2-Dimethylaminoethyl)triphenylphosphonium bromide · 2-(dimethylamino)ethyl-triphenylphosphanium,bromide · (2-Dimethylaminoethyl)triphenylphosphonium bromide,97%
![Molekülstruktur von [2-(Dimethylamino)ethyl]triphenylphosphoniumbromid](/img/chemical/2724136.png)
Identifikatoren & physikalische Daten
| CAS No. | 21331-80-6 |
|---|---|
| Summenformel | C22H25BrNP |
| Durchschnittliche Molmasse | 414,3 g/mol |
| Monoisotopische Masse | 413,09079853 g/mol |
| SMILES | CN(C)CC[P+](c1ccccc1)(c1ccccc1)c1ccccc1.[Br-] |
| InChIKey | YIIHEMGEQQWSMA-UHFFFAOYSA-M |
| PubChem CID | 2724136 |
| EC No. | 244-335-2 |
| DTXSID | DTXSID30943890 |
| Lokaler Name | [2-(Dimethylamino)ethyl]triphenylphosphoniumbromid |
Chemische & physikalische Eigenschaften
| Polarare Oberfläche (TPSA) | 3,2 |
|---|---|
| H-Brücken-Donoren | 0 |
| H-Brücken-Akzeptoren | 2 |
| Frei drehbare Bindungen | 6 |
| Schwere Atome | 25 |
| Formalladung | 0 |
| Komplexität | 303 |
| Schmelzpunkt | 195-200 °C (dec.)(lit.) |
| Lagerbedingungen | Inert atmosphere,Room Temperature |
| Aggregatzustand | Powder |
| Farbe | Almost white to yellow-brown |
| BRN | 4072092 |
| CAS Datenbank | 21331-80-6(CAS DataBase Reference) |
Sicherheit & Vorschriften
| GHS-Einstufung | WarningH315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 43 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies. |
|---|---|
| Hazard Classes and Categories | Skin Irrit. 2 (100%) |
| F | 3 |
| Wassergefährdungsklasse (WGK) | 3 |
| Zollcode | 29310099 |
| R-Sätze (R) | 36/37/38 |
| Gefahrensymbole | Xi |
| Sicherheitshinweise (S) | 26-36 |
Anwendungen & Verwendung
Beschreibung
2-DiMethylaMinoethyltriphenylphosphoniuM BroMide is precursor to dimethylaminoethylidenetriphenylphosphorane, which condenses with aldehydes and ketones to give allylic amines.
Verwenden
[2-(Dimethylamino)ethyl]triphenylphosphonium Bromide, can be used as a polymerizable cationic surfactant for the intercalation of montmorillonite (MMT), used in the synthesis of polystyrene-clay nanocomposite materials. It can also be used for the synthesis of some analogs of morphine 6-glucuronide through Wittig reactions.