Tetrabutylammoniumperiodat

Tetrabutylammonium Periodate

HCID 2724292

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Grundinformationen

CAS: 65201-77-6
Standard-SMILES: CCCC[N+](CCCC)(CCCC)CCCC.[O-][I+3]([O-])([O-])[O-]
InChIKey: PYVXLMQALOZKES-UHFFFAOYSA-M
Summenformel: C16H36INO4
Durchschnittliche Molmasse: 433,37 g/mol

Namen und Bezeichner

Bevorzugter Name: Tetrabutylammonium Periodate
IUPAC: tetrabutylazanium periodate
Lokaler Name: Tetrabutylammoniumperiodat
Englischer Name: Tetrabutylammonium periodate
Summenformel: C16H36INO4
Molmasse: 433.37

Namen und Synonyme

Tetrabutylammonium periodate65201-77-6EINECS 265-614-5RefChem:188414265-614-5tetrabutylazanium;periodateMFCD00011852tetrabutylazanium periodaten-tetrabutylammonium periodateN,N,N-Tributyl-1-butanaminium Periodate; N,N,N-Tributyl-1-butanaminium Salt With Periodic Acid (HIO4); N,N,N-Tributyl-1-butanaminium Periodate (IO41-); Tetrabutylammonium Metaperiodate; Tetrabutylammonium Periodatetetrabutylammonium;periodateTetra-n-butylammonium periodate

Weitere Namen anzeigen

etrabutylazanium,periodateTetra-n-butylammoniumperiodateTETRABUTYLAMMONIUM(META)PERIODATTetrabutylammonium periodate,99%TETRABUTYLAMMONIUM (META)PERIODATETetrabutylaminium·periodic acidanionTetra-n-butylaMMoniuM (Meta)periodate, 97%TETRABUTYLAMMONIUM (META)PERIODATE, MOIS T. W. ~10% WATER

C16H36INO4CHEMBL1078235Tetra-n-butylammonium (meta)periodateAKOS025243447CS-W011619AS-75489SY107079DB-054773

Datenbank-Bezeichner

CAS: 65201-77-6
PubChem CID: 2724292
ChEMBL: CHEMBL1078235
EC Number: 265-614-5

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA): 74,3 Å²
H-Brücken-Donoren: 0
H-Brücken-Akzeptoren: 4
Frei drehbare Bindungen: 12
Schwere Atome: 22
Formalladung: 0
Komplexität: 212

Physikochemische Eigenschaften

Schmelzpunkt: 175 °C · 175 °C (dec.) (lit.)
Dichte: 1.2302 · 1.2302 (estimate)
storage temp.: 2 · Storage temp. 2-8°C
Löslichkeit: Chloroform (Slightly), DMSO (Slightly)
Aggregatzustand: solid
BRN: 4621593 · 4621593
InChI: 1S/C16H36N.HIO4/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2-1(3,4)5/h5-16H2,1-4H3;(H,2,3,4,5)/q+1;/p-1
InChIKey: PYVXLMQALOZKES-UHFFFAOYSA-M
SMILES: [O-]I(=O)(=O)=O.CCCC[N+](CCCC)(CCCC)CCCC

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 4 Einträge

Danger

H272 (97.5%): May intensify fire; oxidizer [Danger Oxidizing liquids; Oxidizing solids]

P210, P220, P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 40 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Gefahrenhinweise

Hazard Classes and CategoriesOx. Sol. 2 (97.5%)

Sicherheitsdaten

F: 8
wgk: 3
ridadr: UN 1479 5.1/PG 2
hs_code: 29239000
risk_code: 8-36/37/38-20/22
hazard_code: O,Xi,Xn
safety_code: 17-26-36-37/39
hazard_class: 4.1
packing_group: II
Speicherklasse: 5.1B - Oxidizing hazardous materials
Hazard Classifications: Eye Irrit. 2Ox. Sol. 2Skin Irrit. 2STOT SE 3

Chemie und Industrie

Anwendungen

BeschreibungTetrabutylammonium periodate is useful reagent in oxidation of sulfides, phenacyl bromides, benzyl halides, phosphites; oxidative decarboxylation; co-oxidant in metal-catalyzed oxidation.

VerwendenTetrabutylammonium (meta)periodate (DCM) can be oxidated for the synthesis of aryl nitroso derivatives. It can also be used in the formation of an ionic liquid for the synthesis of aromatic carboxylic acids.