Grundinformationen
- CAS
6921-34-2- Standard-SMILES
[CH2-]c1ccccc1.[Cl-].[Mg+2]- InChIKey
NRAFPLGJPPJUNB-UHFFFAOYSA-M- Summenformel
- C7.H7.Cl.Mg
- Durchschnittliche Molmasse
- 150,89 g/mol
- Monoisotopische Masse
- 150,0086696
Namen und Bezeichner
- Bevorzugter Name
- Magnesium, chloro(phenylmethyl)-
- IUPAC
- magnesium;methanidylbenzene;chloride
- Lokaler Name
- Benzylmagnesiumchlorid
- Englischer Name
- Benzylmagnesium chloride
- Summenformel
- C7H7ClMg
- Molmasse
- 150.89
Namen und Synonyme
Benzylmagnesium chloride6921-34-2Magnesium, chloro(phenylmethyl)-Chloro(phenylmethyl)magnesiumDTXSID00884302RefChem:800672Magnesium, chloro(phenylmethyl)DTXCID501023753230-039-0EC 230-039-0EINECS 230-039-0PhCH2MgCl
Weitere Namen anzeigen
Benzylmagnesium chloride solutionBENZYLMAGNESIUM CHLORIDE, 2.0M SOLUTION IN TETRAHYDROFURANENCL-004BenzylchloromagnesiumChlorobenzylmagnesiumBenzylmagnesiumchloridChloro(benzyl) magnesiumchloro(phenylmethyl)-magnesiu
BnMgClmagnesium;methanidylbenzene;chlorideBenzylchloridomagnesiumphenylmethyl magnesium chlorideBenzylmagnesium chloride 1.0 M in THFBENZYLMAGNESIUM CHLORIDE 2M in THFbenzylmagnesiumchloridebenzyl magnesium chloride
Datenbank-Bezeichner
- CAS
6921-34-2- PubChem CID
- 2733352
- DTXSID
DTXSID00884302- EC Number
- 230-039-0
Eigenschaften
Berechnete Struktureigenschaften
- Polarare Oberfläche (TPSA)
- 0 Ų
- H-Brücken-Donoren
- 0
- H-Brücken-Akzeptoren
- 2
- Frei drehbare Bindungen
- 0
- Schwere Atome
- 9
- Formalladung
- 0
- Komplexität
- 50,9
Experimentelle und physikochemische Eigenschaften
Chemical ClassesMetals -> Metals, Organic Compounds
Density0.794 @25 °C
Physical Description30-50% solution in tetrahydrofuran: Clear liquid; [Sigma-Aldrich MSDS]
Physikochemische Eigenschaften
- Siedepunkt
- 182 °C · 182 °C(Press: 16 Torr)
- Dichte
- 1.031 g/mL · 1.031 g/mL at 25 °C
- Flammpunkt
- 1 °F · 1 °F
- storage temp.
- water-free area
- Aggregatzustand
- Liquid
- Farbe
- Brown to purple
- Wasserlöslichkeit
- Severe reaction
- BRN
- 878506 · 878506
- InChI
- InChI=1S/C7H7.ClH.Mg/c1-7-5-3-2-4-6-7;;/h2-6H,1H2;1H;/q;;+1/p-1
- InChIKey
- NRAFPLGJPPJUNB-UHFFFAOYSA-M
- SMILES
- C1(C[Mg]Cl)=CC=CC=C1
- CAS Datenbank
- 6921 · 6921-34-2(CAS DataBase Reference)
- EPA chemische Informationen
- Magnesium, chloro(phenylmethyl)- (6921-34-2)
Sicherheit und Regulatorisches
Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.
GHS-Klassifizierung
GHS Classification
Danger
H225 (40.5%): Highly Flammable liquid and vapor [Danger Flammable liquids]
P210, P233, P240, P241, P242, P243, P260, P264, P280, P301+P330+P331, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P321, P363, P370+P378, P403+P235, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 74 reports by companies from 8 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Gefahrenhinweise
Regulatory Information
REACH registered substance: Benzylmagnesium chloride (EC: 230-039-0)
Magnesium, chloro(phenylmethyl)-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.
Hazards SummaryCauses burns; [Sigma-Aldrich MSDS] See Phenylmagnesium chloride.
Hazard Classes and CategoriesFlam. Liq. 2 (40.5%)
Sicherheit und Schutzausrüstung
Protective Action Criteria (PAC)
1.2 [mg/m3]
13 [mg/m3]
79 [mg/m3]
Toxikologische Informationen
Adverse EffectsDermatotoxin - Skin burns.
Sicherheitsdaten
- F
- 1-3-10
- wgk
- 1
- tsca
- TSCA listed
- ridadr
- UN 2924 3/PG 2
- hs_code
- 29319090
- risk_code
- 12-14-34-66-67-36/37-19-11-14/15-40-37-17-22
- hazard_code
- F+,C,Xi,F
- safety_code
- 16-29-33-7/8-45-43-36/37/39-26-6A-43B
- hazard_class
- 4.3
- packing_group
- II
- Speicherklasse
- 3 - Flammable liquids
- Hazard Classifications
- Acute Tox. 4 OralEye Dam. 1Flam. Liq. 2Skin Corr. 1B
Chemie und Industrie
Verwendung und Herstellung
UsesUsed to make fine chemicals; [ExPub: ECHA REACH Registrations]
General Manufacturing InformationMagnesium, chloro(phenylmethyl)-: ACTIVE
Anwendungen
VerwendenBenzylmagnesium chloride (Grignard reagent) can be used as an alkylating reagent:For alkylating quinolyl-functionalized Cpchromium(III) complexes which are used as precursors for the preparation of active olefin polymerization catalysts. In the synthesis of 2,3-disubstituted benzopyran-4-ones, 6-chloro-8-methylpurine derivative, and phenylalanine derivatives.
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