Bis(diisopropylamino)chlorophosphine

HCID 2733425CAS 56183-63-2

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Grundinformationen

Standard-SMILES: CC(C)N(C(C)C)P(Cl)N(C(C)C)C(C)C
InChIKey: FEHUTHGOLLQBNW-UHFFFAOYSA-N
Summenformel: C12H28ClN2P
Durchschnittliche Molmasse: 266,79 g/mol
Monoisotopische Masse: 266,1678636

Namen und Bezeichner

Bevorzugter Name: Bis(diisopropylamino)chlorophosphine
IUPAC: N-[chloro-[di(propan-2-yl)amino]phosphanyl]-N-propan-2-ylpropan-2-amine
Englischer Name: BIS(DIISOPROPYLAMINO)CHLOROPHOSPHINE
Summenformel: C12H28ClN2P
Molmasse: 266.79

Namen und Synonyme

Bis(diisopropylamino)chlorophosphine56183-63-2DTXSID00369907RefChem:569062DTXCID10320943628-718-5MFCD00061482N-[chloro-[di(propan-2-yl)amino]phosphanyl]-N-propan-2-ylpropan-2-aminePhosphorodiamidous chloride, tetrakis(1-methylethyl)-C12H28ClN2PSCHEMBL1117784bisdiisopropylaminochlorophosphine

Weitere Namen anzeigen

Bis(diisopropyamino)chlorophosphineChlorobis(N,N-diisopropylamino)phosphineSKL629Bis(diisopropylaminodiisopropylaMino)phosphineChlorbis(diisopropylamino)phosphanChloro-di-N-(diisopropyl)-phosphiteBIS(DI-I-PROPYLAMINO)CHLOROPHOSPHINE

FEHUTHGOLLQBNW-UHFFFAOYSA-NGCA18363Bis(di-isopropylamino)chlorophosphineChloro(bis(diisopropylamino))phosphaneAKOS015910528bis(N,N-diisopropylamino)chlorophosphinebis-(N,N-diisopropylamino)chlorophosphineBP-14118

Datenbank-Bezeichner

CAS: 56183-63-2
PubChem CID: 2733425
DTXSID: DTXSID00369907
EC Number: 628-718-5
Nikkaji: J1.175.515A

Eigenschaften

Berechnete Struktureigenschaften

XLogP: 4,4
Polarare Oberfläche (TPSA): 6,5 Å²
H-Brücken-Donoren: 0
H-Brücken-Akzeptoren: 2
Frei drehbare Bindungen: 6
Schwere Atome: 16
Formalladung: 0
Komplexität: 159

Physikochemische Eigenschaften

Schmelzpunkt: 100 · 100-104 °C(lit.)
Siedepunkt: 291 ℃ · 291℃
Flammpunkt: 130 ℃ · 130℃
storage temp.: Store under inert gas
Aggregatzustand: Powder
pka: 4.5 · 4.50±0.70(Predicted)
Farbe: white to off-white
InChI: InChI=1S/C12H28ClN2P/c1-9(2)14(10(3)4)16(13)15(11(5)6)12(7)8/h9-12H,1-8H3
InChIKey: FEHUTHGOLLQBNW-UHFFFAOYSA-N
SMILES: P(N(C(C)C)C(C)C)(N(C(C)C)C(C)C)Cl
CAS Datenbank: 56183 · 56183-63-2(CAS DataBase Reference)

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 5 Einträge

Danger

H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]；H318 (97.6%): Causes serious eye damage [Danger Serious eye damage/eye irritation]

P260, P264, P264+P265, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P363, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 42 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

Gefahrenhinweise

Hazard Classes and CategoriesSkin Corr. 1B (100%)；Eye Dam. 1 (97.6%)

Sicherheitsdaten

wgk: 3
ridadr: UN 3261 8/PG 1
hs_code: 29310099
risk_code: 14-34
hazard_code: C
safety_code: 26-27-28-36/37/39-45
hazard_class: 8
packing_group: II
Speicherklasse: 8A - Combustible corrosive hazardous materials
Hazard Classifications: Eye Dam. 1Skin Corr. 1B

Chemie und Industrie

Anwendungen · 2 Einträge

BeschreibungBis(diisopropylamino)chlorophosphine is a white to off-white powder to crystalline organophosphorus compound, mainly used as an organic synthetic raw material or reaction reagent. It can be used in the synthesis of mixed phosphorothioate and methylenephosphine derivatives, etc. It is commonly used in chemical production and laboratory research.

VerwendenBis(diisopropylamino)chlorophosphine has been used in the synthesis of tert-butyl tetraisopropylphosphorodiamidite ligand for palladium-catalyzed Buchwald–Hartwig amination reaction.It is also can be used to synthesize:acyclic N-phosphonio imine catalyst for selective epoxidationsboryl-substituted methylenephosphonium derivatives