HRID 1298928als KatalysatorHigh-throughput exploration of 50,688 Pd-, Ni- and Cu-catalysed C–N coupling reactions
Trost Ligand
Grundinformationen
- CAS
138517-61-0- Standard-SMILES
O=C(N[C@@H]1CCCC[C@H]1NC(=O)c1ccccc1P(c1ccccc1)c1ccccc1)c1ccccc1P(c1ccccc1)c1ccccc1- InChIKey
AXMSEDAJMGFTLR-XRSDMRJBSA-N- Summenformel
- C44H40N2O2P2
- Durchschnittliche Molmasse
- 690,7 g/mol
- Monoisotopische Masse
- 690,25650252
Namen und Bezeichner
- Bevorzugter Name
- Trost Ligand
- IUPAC
- 2-diphenylphosphanyl-N-[(1R,2R)-2-[(2-diphenylphosphanylbenzoyl)amino]cyclohexyl]benzamide
- Englischer Name
- (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl)
- Summenformel
- C44H40N2O2P2
- Molmasse
- 690.75
Namen und Synonyme
138517-61-0Trost ligandDTXSID80894121RefChem:192277DTXCID301324240(R,R)-DACH-phenyl Trost ligandMFCD01631273Benzamide, N,N'-(1R,2R)-1,2-cyclohexanediylbis[2-(diphenylphosphino)-(R)-Trost ligand(R,R)-Trost ligand(R,R)-Dppba(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)
Weitere Namen anzeigen
(1R,2R)-Trost ligand(1R,2R)-(+)-1,2-TROST LIGAND1R,2R- DHAC-Phenyl Trost Ligand(R,R)-DACH-phenyl Trost ligand 95%(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-di-phenylphos...N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphino)benzamideN,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphi no)benzamide]
2-diphenylphosphanyl-N-[(1R,2R)-2-[(2-diphenylphosphanylbenzoyl)amino]cyclohexyl]benzamideTrost ligand, (R,R)-M4RRX95R5F(1R,2R)-N,N'-(Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)benzamide)(1R,2R)-1,2-Bis((2-(diphenylphosphino)benzoyl)amino)cyclohexane(1R,2R)-1,2-Bis((2-(diphenylphosphanyl)benzoyl)amino)cyclohexane(1R,2R)-N,N-Bis(O-(diphenylphosphino)benzoyl)cyclohexane-1,2-diamineN,N-(1R,2R)-1,2-Cyclohexanediylbis(2-(diphenylphosphino)benzamide)
Eigenschaften
Berechnete Struktureigenschaften
- XLogP
- 8,9
- Polarare Oberfläche (TPSA)
- 58,2 Ų
- H-Brücken-Donoren
- 2
- H-Brücken-Akzeptoren
- 2
- Frei drehbare Bindungen
- 10
- Schwere Atome
- 50
- Formalladung
- 0
- Komplexität
- 929
Physikochemische Eigenschaften
- Schmelzpunkt
- 134 · 134-136°C
- Siedepunkt
- 817 · 817.0±65.0 °C(Predicted)
- storage temp.
- 2 · under inert gas (nitrogen or Argon) at 2-8°C
- pka
- 13.35 · 13.35±0.40(Predicted)
- Aggregatzustand
- Powder
- Farbe
- white to off-white
- InChIKey
- AXMSEDAJMGFTLR-UHFFFAOYSA-N
- SMILES
- C1(NC(=O)C2=CC=CC=C2P(C2=CC=CC=C2)C2=CC=CC=C2)CCCCC1NC(=O)C1=CC=CC=C1P(C1=CC=CC=C1)C1=CC=CC=C1
Sicherheit und Regulatorisches
Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.
GHS-Klassifizierung
GHS Classification
Warning
H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]
P264, P280, P302+P352, P321, P332+P317, and P362+P364 (click each P-code to see the statement)
The GHS information provided by 1 company from 1 notification to the ECHA C&L Inventory.
Sicherheitsdaten
- wgk
- 3
- risk_code
- 36/37/38
- safety_code
- 26-36/37/39
- Speicherklasse
- 11 - Combustible Solids
Chemie und Industrie
Anwendungen
VerwendenTrost Ligands for Asymmetric Allylic Alkylation
Anbieter93 Anbieter
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
韶远科技(上海)有限公司4000665055 · [email protected]
上海铂之泉科技有限公司13681726990 13681726990 · [email protected]
武汉敬康恩生物医药科技有限公司13720134139 086-15871494362 13720134139 · [email protected]
毕佳索（上海毕得医药科技股份有限公司）400-6005915 · [email protected]
上海遐瑞医药科技有限公司+86-021-61551413 · [email protected]
Dayang Chem (Hangzhou) Co.,Ltd.+86-0571-88938639 17705817739 · [email protected]
郑州鸿晟医药科技有限公司0371-55695890 15637198702 · [email protected]
北京颖诺凯胜科技有限公司010-56541685 13070143590 · [email protected]
安耐吉化学&3A（安徽泽升科技股份有限公司）400-0056266 · [email protected]
北京绿百草科技发展有限公司010-61136123 · [email protected]
上海瀚鸿科技股份有限公司021-54306202 13764082696 · [email protected]
Zugehörige Reaktionen
192
HRID 1298929als KatalysatorHigh-throughput exploration of 50,688 Pd-, Ni- and Cu-catalysed C–N coupling reactions
HRID 1298930als KatalysatorHigh-throughput exploration of 50,688 Pd-, Ni- and Cu-catalysed C–N coupling reactions
HRID 1298931als KatalysatorHigh-throughput exploration of 50,688 Pd-, Ni- and Cu-catalysed C–N coupling reactions
HRID 1298932als KatalysatorHigh-throughput exploration of 50,688 Pd-, Ni- and Cu-catalysed C–N coupling reactions
HRID 1298933als KatalysatorHigh-throughput exploration of 50,688 Pd-, Ni- and Cu-catalysed C–N coupling reactions
HRID 1298934als KatalysatorHigh-throughput exploration of 50,688 Pd-, Ni- and Cu-catalysed C–N coupling reactions
HRID 1298935als KatalysatorHigh-throughput exploration of 50,688 Pd-, Ni- and Cu-catalysed C–N coupling reactions
Notizen zur Verbindung
Wird geladen…