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Triethylphosphin
triethylphosphane · PEt3 · Triethylphosphine,99% · Et3P · tl409 · (C2H5)3P · Cytop? 320 · CYTOP(R) 320
Identifikatoren & physikalische Daten
| CAS No. | 554-70-1 |
|---|---|
| Summenformel | C6H15P |
| Durchschnittliche Molmasse | 118,16 g/mol |
| Monoisotopische Masse | 118,09113748 g/mol |
| SMILES | CCP(CC)CC |
| InChIKey | RXJKFRMDXUJTEX-UHFFFAOYSA-N |
| PubChem CID | 27365 |
| ChEBI | CHEBI:39971 |
| EC No. | 209-068-8 |
| DTXSID | DTXSID3060293 |
| Lokaler Name | Triethylphosphin |
Chemische & physikalische Eigenschaften
| XLogP | 1 |
|---|---|
| Polarare Oberfläche (TPSA) | 0 |
| H-Brücken-Donoren | 0 |
| H-Brücken-Akzeptoren | 0 |
| Frei drehbare Bindungen | 3 |
| Schwere Atome | 7 |
| Formalladung | 0 |
| Komplexität | 25 |
| Physical Description | Colorless liquid with an odor of hyacinths[Merck Index] Pungent odor[Alfa Aesar MSDS] |
| Schmelzpunkt | -88°C |
| Siedepunkt | 127-128 °C(lit.) |
| Dichte | 0.88 g/mL at 20 °C |
| Brechungsindex | n20/D 1.456(lit.) |
| Flammpunkt | 1 °F |
| Aggregatzustand | liquid |
| Farbe | colorless |
| Geruch | vile, nauseating odor.stench |
| Löslichkeit | Insoluble in water. |
| Merck | 14,9675 |
| BRN | 969170 |
| InChI | 1S/C6H15P/c1-4-7(5-2)6-3/h4-6H2,1-3H3 |
| InChIKey | RXJKFRMDXUJTEX-UHFFFAOYSA-N |
| SMILES | CCP(CC)CC |
| CAS Datenbank | 554-70-1(CAS DataBase Reference) |
| NIST chemische Informationen | Phosphine, triethyl-(554-70-1) |
| EPA chemische Informationen | Phosphine, triethyl- (554-70-1) |
Sicherheit & Vorschriften
| GHS-Einstufung | DangerH224 (17.5%): Extremely flammable liquid and vapor [Danger Flammable liquids]H225 (81.2%): Highly Flammable liquid and vapor [Danger Flammable liquids]H250 (100%): Catches fire spontaneously if exposed to air [Danger Pyrophoric liquids]H302 (17.5%): Harmful if swallowed [Warning Acute toxicity, oral]H314 (95%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]H318 (17.5%): Causes serious eye damage [Danger Serious eye damage/eye irritation]P210, P222, P231, P233, P240, P241, P242, P243, P260, P264, P264+P265, P270, P280, P301+P317, P301+P330+P331, P302+P335+P334, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P317, P321, P330, P363, P370+P378, P403+P235, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 80 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website. |
|---|---|
| Gefahrenübersicht | PyrophoricSelf-heating in large quantities and may catch fireAn irritantHarmful by inhalation[Alfa Aesar MSDS] See Tributylphosphine and tert-Butylphosphine. |
| Hazard Classes and Categories | Flam. Liq. 1 (17.5%)Flam. Liq. 2 (81.2%)Pyr. Liq. 1 (100%)Acute Tox. 4 (17.5%)Skin Corr. 1B (95%)Eye Dam. 1 (17.5%) |
| Toxicity Data | LC (mouse) > 1,000 mg/m3/10min |
| F | 10-13-23 |
| Wassergefährdungsklasse (WGK) | 3 |
| TSCA-Inventar-Status | TSCA listed |
| UN-Transportnummer | UN 2924 3/PG 2 |
| RTECS-Nr. | SZ3400000 |
| R-Sätze (R) | 11-34-67-17-40-37-19 |
| Gefahrensymbole | F,C |
| Sicherheitshinweise (S) | 26-36/37/39-45-7/9-33-16 |
| Gefahrenklasse | 4.2Acute Tox. 4 OralEye Dam. 1Flam. Liq. 2Pyr. Liq. 1Skin Corr. 1B |
| Verpackungsgruppe | I |
| Lagerklasse | 4.2 - Pyrophoric and self-heating hazardous materials |
Anwendungen & Verwendung
Verwenden
Triethylphosphine is used as a ligand for arylation. It is used in organic synthesis.