CAS 13462-88-9 Nickel(II) bromide (HCID 278492)

Überblick

See also: nickel (ii) bromide, anhydrous (annotation moved to); Nickel bromide (NiBr2), trihydrate (annotation moved to); Nickel(II) bromide hydrate (annotation moved to).

Namen und Bezeichner

Bevorzugter Name: Nickel(II) bromide
IUPAC: dibromonickel
Lokaler Name: Nickeldibromid
Englischer Name: NICKEL BROMATE
Summenformel: Br2Ni
Molmasse: 218.5

Namen und Synonyme

Nickel(II) bromideDibromonickelNickel dibromideNickelous bromideBr2NiNickel(2+) bromideNickel bromide (NiBr2)NiBr241SGH8A2S6NSC-128153Nickel bromide (NiBr2), hydrate (9CI)Nickel bromide (Br2Ni)

Weitere Namen anzeigen

Nickel(II)-bromidNickel-bromidNICKEL BROMATENickel(Ⅱ) bromideDibromonickel(II)Nickeleus bromidenickelbromide(nibr2)Nickel(II) dibromide

UNII-41SGH8A2S6nicke l bromideNickel dibromide; Nickel(2+) bromide; Nickel bromideNSC 128153; Nickel bromide (Br2Ni)EINECS 236-665-0NSC 128153Nickel (II) bromideNICKEL BROMIDE [MI]Nickel(II) bromide, 98%

Datenbank-Bezeichner

CAS: 13462-88-9
PubChem CID: 278492
UNII: 41SGH8A2S6
EC Number: 236-665-0

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA): 0 Å²
H-Brücken-Donoren: 0
H-Brücken-Akzeptoren: 0
Frei drehbare Bindungen: 0
Schwere Atome: 3
Formalladung: 0
Komplexität: 2,8

Experimentelle und physikochemische Eigenschaften

Chemical ClassesMetals -> Nickel Compounds, Inorganic

SpringerMaterials Propertiesdielectric constant

Density5.1 @25 °C

Melting Point963 °C

Physical DescriptionYellowish-green odorless solid; [CAMEO] Trihydrate: yellow-green and deliquescent; loses water at about 200 deg C; Anhydrous: yellow-gold; [Merck Index]

Physikochemische Eigenschaften

Schmelzpunkt: 963 °C · 963 °C (lit.)
Dichte: 5.098 g/mL · 5.098 g/mL at 25 °C (lit.)
storage temp.: Inert atmosphere,Room Temperature
Löslichkeit: 2 O: · H2O: slightly soluble(lit.)
Aggregatzustand: powder
Farbe: Brown
Wichte: 5.098 · 5.098
Wasserlöslichkeit: Soluble in water, alcohol and ether.
Merck: 14 · 14,6502
Stabilität: Stable. Incompatible with strong oxidizing agents.
Major Application: battery precursorscatalystsmaterial synthesis precursor
InChI: 1S/2BrH.Ni/h2*1H;/q;;+2/p-2
InChIKey: IPLJNQFXJUCRNH-UHFFFAOYSA-L
SMILES: Br[Ni]Br
CAS Datenbank: 13462 · 13462-88-9(CAS DataBase Reference)
EPA chemische Informationen: Nickel(II) bromide (13462-88-9)

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 6 Einträge

Danger

H317: May cause an allergic skin reaction [Warning Sensitization, Skin]

P203, P233, P260, P261, P264, P270, P271, P272, P273, P280, P284, P302+P352, P304+P340, P318, P319, P321, P333+P317, P342+P316, P362+P364, P391, P403, P405, and P501 (click each P-code to see the statement)

Danger

H317 (98.6%): May cause an allergic skin reaction [Warning Sensitization, Skin]

P203, P233, P260, P261, P264, P270, P271, P272, P273, P280, P284, P302+P352, P304+P340, P318, P319, P321, P333+P317, P342+P316, P362+P364, P391, P403, P405, and P501 (click each P-code to see the statement)

Gefahrenhinweise

Regulatory Information · 3 Einträge

Chemical: Nickel bromide (NiBr2)

Hazard Traits - Carcinogenicity; Reproductive Toxicity; Respiratory Toxicity

Restricted substance: Nickel dibromide

Other Safety InformationIMAP assessments - Water soluble nickel(2+) salts: Environment tier II assessment

Hazards SummaryIrritating to eyes, nose, and throat; [CAMEO] See Bromine. See Nickel and linked occupational diseases.

Hazard Classes and Categories · 3 Einträge

Skin Sens. 1 (98.6%)

Acute toxicity - category 4

Carc. 1A

Sicherheit und Schutzausrüstung

Threshold Limit Values (TLV)0.1 [mg/m3], inhalable fraction, as Ni

Permissible Exposure Limit (PEL)1.0 [mg/m3], as Ni

Protective Action Criteria (PAC) · 3 Einträge

1.1 [mg/m3]

12 [mg/m3]

74 [mg/m3]

Immediately Dangerous to Life or Health (IDLH)10.0 [mg/m3], as Ni

Toxikologische Informationen

Adverse EffectsSkin Sensitizer - An agent that can induce an allergic reaction in the skin.

Sicherheitsdaten

wgk: 3
tsca: TSCA listed
ridadr: UN 3077 9/PG 3
hs_code: 28275900
risk_code: 45-22-43-50/53-68-48/23-42/43-61-49
hazard_code: T,N,Xi
safety_code: 53-36/37-45-60-61
hazard_class: 6.1(b)
packing_group: III
Speicherklasse: 6.1C - Combustible acute toxic Cat.3toxic compounds or compounds which causing chronic effects
Hazard Classifications: Aquatic Acute 1Aquatic Chronic 1Carc. 1BMuta. 2Repr. 1BResp. Sens. 1Skin Sens. 1STOT RE 1 Inhalation

Chemie und Industrie

Verwendung und Herstellung

General Manufacturing InformationNickel bromide (NiBr2): ACTIVE

Anwendungen

VerwendenNickel(II) Bromide, is used as a source of bromide ion. It is also an important raw material used in various chemical synthesis and also as a catalyst in cross-coupling reactions.