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Hexafluorsilicat(2-), Barium (1:1)

Barium hexafluorosilicate

HCID 28299
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Grundinformationen

CAS
17125-80-3
Standard-SMILES
F[Si-2](F)(F)(F)(F)F.[Ba+2]
InChIKey
RRLMRHFZRPYSNK-UHFFFAOYSA-N
Summenformel
Ba.F6Si
Durchschnittliche Molmasse
279,4 g/mol
Monoisotopische Masse
279,872593

Überblick

Barium silicofluoride is a chemical compound of barium. Barium is a metallic alkaline earth metal with the symbol Ba, and atomic number 56. It never occurs in nature in its pure form due to its reactivity with air, but combines with other chemicals such as sulfur or carbon and oxygen to form barium compounds that may be found as minerals. (L214, 408)

Namen und Bezeichner

Bevorzugter Name
Barium hexafluorosilicate
IUPAC
barium(2+);hexafluorosilicon(2-)
Lokaler Name
Hexafluorsilicat(2-), Barium (1:1)
Englischer Name
Barium hexafluorosilicate
Summenformel
BaF6Si
Molmasse
279.4

Namen und Synonyme

Barium hexafluorosilicate17125-80-3Barium silicofluorideBARIUM FLUOSILICATEBarium fluorosilicateCaswell No. 070BariumsilicofluoridBarium silicon fluorideSilicon fluoride barium saltBarium hexafluorosilicate(2-)Silicate(2-), hexafluoro-, bariumBariumsilicofluorid [German]
Weitere Namen anzeigen
Barium fiuosilicateBARIUMSILIOFLUORIDEBariumfluorosilicatebariumsiliconfluorideBarium fluorsilicatefluoro(trioxido)silaneBarium hexafluosilicate
W4A72RWE6QEPA Pesticide Chemical Code 075302EINECS 241-189-1Hexafluorosilicate(2-) barium (1:1)Silicate(2-), hexafluoro-, barium (1:1)DTXSID80884961BARIUM HEXAFLUOROSILICATE [MI]RefChem:560995

Datenbank-Bezeichner

CAS
17125-80-3
PubChem CID
28299

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA)
0 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
7
Frei drehbare Bindungen
0
Schwere Atome
8
Formalladung
0
Komplexität
62,7

Experimentelle und physikochemische Eigenschaften

Chemical ClassesMetals -> Metals, Inorganic Compounds
Pesticides · 2 Einträge

Insecticides

Active substance -> EU Pesticides database: Not approved

Physical DescriptionSolid; Insoluble in water (0.0235 g/100mL at 25 deg C); [Merck Index] Powder; [Sigma-Aldrich MSDS]

Physikochemische Eigenschaften

Schmelzpunkt
300 ℃ · decomposes at 300℃ [MER06]
Dichte
421 · d421 4.29
storage temp.
Refrigerator, under inert atmosphere
Löslichkeit
Aqueous Acid (Slightly, Heated, Sonicated)
Aggregatzustand
white orthorhombic needles
Farbe
White or colorless rhombohedral crystallinepowder
Wasserlöslichkeit
0.015 g/100mL · 0.015g/100mL H2O (0°C), 0.0235 (25°C), 0.091 (100°C) [MER06]
CAS Datenbank
17125 · 17125-80-3(CAS DataBase Reference)

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

GHS-Klassifizierung

GHS Classification · 6 Einträge

Warning

H302 (97.4%): Harmful if swallowed [Warning Acute toxicity, oral]

P261, P264, P270, P271, P301+P317, P304+P340, P317, P330, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 39 reports by companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

H301: Toxic if swallowed [Danger Acute toxicity, oral]

Gefahrenhinweise

Regulatory Information · 2 Einträge

Chemical: Silicate(2-), hexafluoro-, barium (1:1)

2002/2076

Hazards Summary · 1 Eintrag

Causes cyanosis, diarrhea, and musculoskeletal changes in oral lethal-dose studies of rats; [RTECS] Highly toxic; [Merck Index] Toxic by ingestion; Targets the kidney, heart, nerves, gastrointestinal tract, bone marrow, liver, and spleen; [Sigma-Aldrich MSDS] See Magnesium hexafluorosilicate and Potassium hexafluorosilicate.

Hazard Classes and Categories · 2 Einträge

Acute Tox. 4 (97.4%)

Acute toxicity (Oral) - Category 3

Sicherheit und Schutzausrüstung

Exposure Control and Personal Protection · 2 Einträge

Biological Exposure Indices (BEI) [ACGIH] - Fluorides in urine = 2 mg/L prior to shift or 3 mg/L at end of shift; (Repeated measurements recommended.)

1.0 [mg/m3], inhalable fraction, as F[German Research Foundation (DFG)]

Chemie und Industrie

Pharmakologische Informationen

Metabolism/Metabolites · 1 Eintrag

Barium compounds are absorbed via ingestion and inhalation, the extent of which depends on the individual compound. In the body, the majority of the barium is found in the bone, while small amounts exists in the muscle, adipose, skin, and connective tissue. Barium is not metabolized in the body, but it may be transported or incorporated into complexes or tissues. Barium is excreted in the urine and faeces. (L214)

Verwendung und Herstellung

Uses · 2 Einträge

Used in silicon tetrafluoride production and as a pesticide; [Merck Index]

No active pesticide product registrations in the US; [NPIRS]

General Manufacturing InformationSilicate(2-), hexafluoro-, barium (1:1): ACTIVE

Anwendungen

Verwendenpreparation of silicon tetrafluoride; as pesticide.

Vor- und nachgelagerte Produkte

Nachgelagerte Produkte

Siliciumtetrafluorid

Anbieter24 Anbieter

Hebei Chuanghai Biotechnology Co., Ltd+86-17732866630 · [email protected]
广州纳珑化工有限公司13192879270; 13192879270 · [email protected]
宁波化工原料有限公司13306607903;13306607903 · [email protected]

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Auf dieser SeiteGrundinformationenÜberblickNamen und BezeichnerEigenschaftenSicherheit und RegulatorischesChemie und IndustrieZugehörige ReaktionenNotizen zur Verbindung
DTXSID
DTXSID80884961
UNII
W4A72RWE6Q
EC Number
241-189-1
EPA chemische Informationen
Barium fluosilicate (17125-80-3)
Minimum Risk Level
Intermediate Oral: 0.2 mg/kg/day (L134) Chronic Oral: 0.2 mg/kg/day (L134)
Threshold Limit Values (TLV)2.5 [mg/m3], as F
Permissible Exposure Limit (PEL)2.5 [mg/m3], as F
Immediately Dangerous to Life or Health (IDLH)250.0 [mg/m3], as F

Toxikologische Informationen

TreatmentIntravenous infusion of potassium often relieves many of the symptoms of barium toxicity. (L214)
Health Effects · 1 Eintrag

The health effects of the different barium compounds depend on how well the compound dissolves in water or the stomach contents. At low doses, barium acts as a muscle stimulant, while higher doses affect the nervous system, causing cardiac irregularities, tremors, weakness, anxiety, dyspnea, paralysisand possibly death. Barium may also cause gastrointestinal disturbances, damage the kidneys and cause decreases in body weight. (L214)

Exposure RoutesOral (L214) ; inhalation (L214)
Toxicity Summary · 1 Eintrag

Barium is a competitive potassium channel antagonist that blocks the passive efflux of intracellular potassium, resulting in a shift of potassium from extracellular to intracellular compartments. The intracellular translocation of potassium results in a decreased resting membrane potential, making the muscle fibers electrically unexcitable and causing paralysis. Some of these barium's effects may also be due to barium induced neuromuscular blockade and membrane depolarization. (L214)

Signs and Symptoms · 1 Eintrag

Ingesting excess barium may cause vomiting, abdominal cramps, diarrhea, difficulties in breathing, increased or decreased blood pressure, numbness around the face, and muscle weakness. High levels may result in changes in heart rhythm or paralysis and possibly death. (L214)

Carcinogen ClassificationNo indication of carcinogenicity to humans (not listed by IARC).

Sicherheitsdaten

wgk
1
tsca
TSCA listed
ridadr
UN 1564 6.1/PG 3
hs_code
2805191000
RTECS-Nr.
CR0525000
risk_code
20/22
Toxizität
LD50 orl-rat: 175 mg/kg AFDOAQ 15,122,51
hazard_code
Xn,Xi
hazard_note
Irritant
safety_code
28
hazard_class
6.1(b)
packing_group
III
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启源(广东)医药化工有限公司18026564465 · [email protected]
西安宇特邦医药科技有限公司029-84536388 18717328141
Shaanxi Didu New Materials Co. Ltd+86-86-17392712779 +86-13289823923 · [email protected]
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