[4,5'-Biisobenzofuran]-1,1',3,3'-tetrone
Grundinformationen
- CAS
36978-41-3- Standard-SMILES
O=C1OC(=O)c2cc(-c3cccc4c3C(=O)OC4=O)ccc21- InChIKey
FYYYKXFEKMGYLZ-UHFFFAOYSA-N- Summenformel
- C16H6O6
- Durchschnittliche Molmasse
- 294,21 g/mol
- Monoisotopische Masse
- 294,01643791
Namen und Bezeichner
- Bevorzugter Name
- [4,5'-Biisobenzofuran]-1,1',3,3'-tetrone
- IUPAC
- 4-(1,3-dioxo-2-benzofuran-5-yl)-2-benzofuran-1,3-dione
- Englischer Name
- 2,3,3,4-biphenyl tetracarboxylic dianhydride
- Summenformel
- C16H6O6
- Molmasse
- 294.22
Namen und Synonyme
[4,5'-Biisobenzofuran]-1,1',3,3'-tetrone3,4'-biphthalic anhydride(4,5'-Biisobenzofuran)-1,1',3,3'-tetroneDTXSID1068015RefChem:550983DTXCID5039274811-539-336978-41-3[4,5'-Biisobenzofuran]-1,1',3,3'-tetraone2,3,3,4-biphenyl tetracarboxylic dianhydride2,3,3',4'-Biphenyltetracarboxylic dianhydride4-(1,3-dioxo-2-benzofuran-5-yl)-2-benzofuran-1,3-dione
Weitere Namen anzeigen
α-BPDADF2DKJACS-36978-41-32,3,3',4'-BIPHENYL3,3',4',4'-BIPHENYL1,1'-Biphenyl-2,3,3',4'-
MFCD090306545-(1,3-dioxo-1,3-dihydro-2-benzofuran-4-yl)-1,3-dihydro-2-benzofuran-1,3-dioneDS-151352,3,3',4'-BiphenyLtetracarboxylic (|A-BPDA)[4,5 inverted exclamation mark -Biisobenzofuran]-1,1 inverted exclamation mark ,3,3 inverted exclamation mark -tetraone2,3,3',4'-biphenyl tetracarboxylic dianhydridea-BPDABCP32519
Datenbank-Bezeichner
- CAS
Eigenschaften
Berechnete Struktureigenschaften
- XLogP
- 2,3
- Polarare Oberfläche (TPSA)
- 86,7 Ų
- H-Brücken-Donoren
- 0
- H-Brücken-Akzeptoren
- 6
- Frei drehbare Bindungen
- 1
- Schwere Atome
- 22
- Formalladung
- 0
- Komplexität
- 567
Physikochemische Eigenschaften
- Schmelzpunkt
- 199 °C · 199 °C
- Siedepunkt
- 609.3 · 609.3±48.0 °C(Predicted)
- Dichte
- 1.625 · 1.625±0.06 g/cm3(Predicted)
- storage temp.
- Inert atmosphere,Room Temperature
- Aggregatzustand
- powder to crystal
- Farbe
- White to Almost white
- InChI
- InChI=1S/C16H6O6/c17-13-9-5-4-7(6-11(9)15(19)21-13)8-2-1-3-10-12(8)16(20)22-14(10)18/h1-6H
- InChIKey
- FYYYKXFEKMGYLZ-UHFFFAOYSA-N
- SMILES
- C1(=O)C2=C(C(C3C=CC4C(=O)OC(=O)C=4C=3)=CC=C2)C(=O)O1
- CAS Datenbank
- 36978 · 36978-41-3(CAS DataBase Reference)
- EPA chemische Informationen
- 4 · [4,5'-Biisobenzofuran]-1,1',3,3'-tetrone (36978-41-3)
Sicherheit und Regulatorisches
Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.
GHS-Klassifizierung
GHS Classification
Warning
H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]
P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 2 reports by companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Gefahrenhinweise
Hazard Classes and CategoriesSkin Irrit. 2 (100%)
Sicherheitsdaten
- tsca
- TSCA listed
- hs_code
- 2922498590
Chemie und Industrie
Verwendung und Herstellung
General Manufacturing Information[4,5'-Biisobenzofuran]-1,1',3,3'-tetrone: ACTIVE
Anwendungen
Beschreibung2,3,3,4-biphenyl tetracarboxylic dianhydride, also known as a-BPDA, is a high-performance polymer with excellent heat resistance, solvent resistance, radiation resistance, and impressive mechanical and dielectric properties. It holds great potential for applications across numerous industries and material fields.
Verwenden2,3,3',4'-Biphenyltetracarboxylic dianhydride be used for the preparation of a polyimide material.
Darstellung
synthetischeThe preparation of 2,3,3',4'-biphenyl tetracarboxylic dianhydride is as follows:In a 1000 ml three-necked flask, 18.3 g (0.1 mol) of 4-chlorophthalic anhydride and 18.3 g (0.1 mol) were added 3-chlorophthalic anhydride, 300 g of anisole as solvent, 0.13 g (0.001 mol) of nickel chloride as a catalyst, 0.198 g (0.001 mol) of C-1 as a catalyst ligand, and 0.03 g (0.0003 mol) of sodium bromide as a catalyst Auxiliary, 13 g (0.2 mol) of zinc powder was used as a reducing agent, and the reaction was stirred at 30 ° C for 8 hours under a nitrogen atmosphere. The reaction solution was filtered to remove insoluble solids in the reaction liquid. 300 g of methanol was added to the filtration mother liquor, and the product was precipitated, filtered, and dried to obtain 25.8 g of the product 2,3,3',4'-biphenyltetracarboxylic dianhydride, yield 87.7%.
Vor- und nachgelagerte Produkte
Vorgelagerte Rohstoffe
Zugehörige Reaktionen
2
Notizen zur Verbindung
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